A semiconductor structure includes a gate structure over a substrate. The structure also includes a source/drain epitaxial structure formed on opposite sides of the gate structure. The structure also includes a contact structure formed over the gate structure. The structure also includes a metal layer formed over the contact structure. The structure also includes a cap layer formed over the metal layer. The structure also includes a first etch stop layer including a metal compound formed over the cap layer. The structure also includes a second etch stop layer including nitrogen formed over the first etch stop layer. The structure also includes a via structure that passes through the first etch stop layer and the second etch stop layer. The bottom surface of the cap layer is level with the bottom surface of the first etch stop layer

A semiconductor device structure and method for forming the same are provided. The semiconductor device structure includes a first metal layer formed over a substrate and a dielectric layer formed over the first metal layer. The semiconductor device structure further includes an adhesion layer formed in the dielectric layer and over the first metal layer and a second metal layer formed in the dielectric layer. The second metal layer is electrically connected to the first metal layer, and a portion of the adhesion layer is formed between the second metal layer and the dielectric layer. The adhesion layer includes a first portion lining with a top portion of the second metal layer, and the first portion has an extending portion along a vertical direction.

A semiconductor device includes a substrate, a first interlayer insulating layer on the substrate, a lower wiring pattern inside the first interlayer insulating layer, an etch stop layer on the first interlayer insulating layer, a second interlayer insulating layer on the etch stop layer, a via trench inside the second interlayer insulating layer and the etch stop layer and that extends to the lower wiring pattern, a via inside the via trench and that is in contact with the second interlayer insulating layer and is formed of a single film, an upper wiring trench formed inside the second interlayer insulating layer on the via, and an upper wiring pattern inside the upper wiring trench and that includes an upper wiring barrier layer and an upper wiring filling layer on the upper wiring barrier layer An upper surface of the via is in contact with the upper wiring filling layer.

A semiconductor device according to an embodiment includes: a semiconductor substrate; a conductor including tungsten (W) or molybdenum (Mo); a first film provided between the conductor and the semiconductor substrate and including titanium (Ti) and silicon (Si); an insulating layer surrounding the conductor; and a second film provided between the conductor and the insulating layer, surrounding the conductor, and including titanium (Ti) and nitrogen (N). A first distance between the semiconductor substrate and an end portion of the second film on a side opposite to the semiconductor substrate is smaller than a second distance between the semiconductor substrate and an end portion of the conductor on a side opposite to the semiconductor substrate.

A semiconductor structure and a method for fabricating a semiconductor structure are provided. In the semiconductor structure, a side of a film layer structure facing away from a substrate is provided with a wiring layer, a side of the substrate facing away from the film layer structure is provided with a connecting hole extending to the wiring layer, and an insulating layer is arranged on a hole wall of the connecting hole. A barrier ring is arranged on the insulating layer, a center line of the barrier ring is arranged collinearly with a center line of the connecting hole, and diffusibility of the barrier ring is less than diffusibility of the wiring layer. A connecting post joined to the wiring layer is arranged in the connecting hole.

Methods of depositing a metal film are discussed. A metal film is formed on the bottom of feature having a metal bottom and dielectric sidewalls. Formation of the metal film comprises exposure to a metal precursor and an alkyl halide catalyst while the substrate is maintained at a deposition temperature. The metal precursor has a decomposition temperature above the deposition temperature. The alkyl halide comprises carbon and halogen, and the halogen comprises bromine or iodine.

Exemplary methods of semiconductor processing may include delivering a carbon-containing precursor and a hydrogen-containing precursor to a processing region of a semiconductor processing chamber. The methods may include generating a plasma of the carbon-containing precursor and the hydrogen-containing precursor within the processing region of the semiconductor processing chamber. The methods may include forming a layer of graphene on a substrate positioned within the processing region of the semiconductor processing chamber. The substrate may be maintained at a temperature below or about 600° C. The methods may include halting flow of the carbon-containing precursor while maintaining the plasma with the hydrogen-containing precursor.

A method includes providing a semiconductor structure having a metal gate structure (MG), gate spacers disposed on sidewalls of the MG, and a source/drain (S/D) feature disposed adjacent to the gate spacers; forming a first metal layer over the S/D feature and between the gate spacers; recessing the first metal layer to form a trench; forming a dielectric layer on sidewalls of the trench; forming a second metal layer over the first metal layer in the trench, wherein sidewalls of the second metal layer are defined by the dielectric layer; and forming a contact feature over the MG to contact the MG.

A method includes forming an insulating layer over a conductive feature; etching the insulating layer to expose a first surface of the conductive feature; covering the first surface of the conductive feature with a sacrificial material, wherein the sidewalls of the insulating layer are free of the sacrificial material; covering the sidewalls of the insulating layer with a barrier material, wherein the first surface of the conductive feature is free of the barrier material, wherein the barrier material includes tantalum nitride (TaN) doped with a transition metal; removing the sacrificial material; and covering the barrier material and the first surface of the conductive feature with a conductive material.

A hybrid via interconnect structure includes a first metal filling at least partially surrounded by a first barrier metal layer, a second metal filling at least partially surrounded by a second barrier metal layer, and a hybrid via formed between the first metal filling and the second metal filling. The hybrid via provides an electrical connection between the first metal filling and the second metal filling and is formed of a different material than the first metal filling, the second metal filling, the first barrier metal layer, and the second barrier metal layer. The hybrid via interconnect structure can be formed during the back end of line (BEOL) portion of an integrated circuit (IC) fabrication process to provide reduced interconnect resistance and improved ease of fabrication.