In an embodiment, a device includes: a channel region; a gate dielectric layer on the channel region; a first work function tuning layer on the gate dielectric layer, the first work function tuning layer including a n-type work function metal; a barrier layer on the first work function tuning layer; a second work function tuning layer on the barrier layer, the second work function tuning layer including a p-type work function metal, the p-type work function metal different from the n-type work function metal; and a fill layer on the second work function tuning layer.

Methods and precursors for selectively depositing a metal film on a silicon nitride surface relative to a silicon oxide surface are described. The substrate comprising both surfaces is exposed to a blocking compound to selectively block the silicon oxide surface. A metal film is then selectively deposited on the silicon nitride surface.

According to the invention there is provided a method of filling one or more gaps created during manufacturing of a feature on a substrate by providing a deposition method comprising; introducing a first reactant to the substrate with a first dose, thereby forming no more than about one monolayer by the first reactant; introducing a second reactant to the substrate with a second dose. The first reactant is introduced with a subsaturating first dose reaching only a top area of the surface of the one or more gaps and the second reactant is introduced with a saturating second dose reaching a bottom area of the surface of the one or more gaps. A third reactant may be provided to the substrate in the reaction chamber with a third dose, the third reactant reacting with at least one of the first and second reactant.

A vertical metal-insulator-metal (MIM) capacitor is formed within multiple layers of a multi-level metal interconnect system of a chip. The vertical MIM capacitor has a first electrode, a second electrode, and a high-k capacitor dielectric material disposed therebetween. The dielectric constant of the capacitor dielectric material is greater than the dielectric constant of interlayer dielectric (ILD) material. After ILD is removed from between the vertically-oriented, interdigitated portions of the first and second electrodes, a capacitor dielectric material having a dielectric constant greater than the ILD dielectric material is disposed therebetween.

A substrate processing method includes applying a solution of a compound containing a metal oxide to a surface of a wafer to form a liquid film of the solution on the surface of the wafer, heating the liquid film at a first temperature lower than a crosslinking temperature of the compound, and irradiating the liquid film with energy rays to form a coating film containing the metal oxide on the surface, after heating the liquid film at the first temperature.

A highly reliable semiconductor device suitable for miniaturization and high integration is provided. The semiconductor device includes a first insulator; a transistor over the first insulator; a second insulator over the transistor; a first conductor embedded in an opening in the second insulator; a barrier layer over the first conductor; a third insulator over the second insulator and over the barrier layer; and a second conductor over the third insulator. The first insulator, the third insulator, and the barrier layer have a barrier property against oxygen and hydrogen. The second insulator includes an excess-oxygen region. The transistor includes an oxide semiconductor. The barrier layer, the third insulator, and the second conductor function as a capacitor.

Transistors and method of forming he same include forming a fin on a bottom source/drain region having a channel region and a sacrificial region on the channel region. A gate stack is formed on sidewalls of the channel region. A gate conductor is formed in contact with the gate stack that has a top surface that meets a middle point of sidewalls of the sacrificial region. The sacrificial region is trimmed to create gaps above the gate stack. A top spacer is formed on the gate conductor having airgaps above the gate stack.

Embodiments of the disclosure generally provide methods of forming a capacitor layer or a gate insulating layer with high dielectric constant as well as film qualities for display applications. In one embodiment, a thin film transistor structure includes source and drain electrodes formed on a substrate, a gate insulating layer formed on a substrate covering the source and drain electrodes, wherein the gate insulating layer is a high-k material having a dielectric constant greater than 10, and a gate electrode formed above or below the gate insulating layer.

In a method for fabricating a fine structure, a metal oxide layer is formed by using an atomic layer deposition over a substrate, and the metal oxide layer is removed. An interfacial oxide layer is formed between the metal oxide layer and the substrate. The interfacial oxide layer is an oxide of an element constituting the substrate, and the interfacial oxide layer is removed.

An object is to provide a semiconductor device including a semiconductor element which has favorable characteristics. A manufacturing method of the present invention includes the steps of: forming a first conductive layer which functions as a gate electrode over a substrate; forming a first insulating layer to cover the first conductive layer; forming a semiconductor layer over the first insulating layer so that part of the semiconductor layer overlaps with the first conductive layer; forming a second conductive layer to be electrically connected to the semiconductor layer; forming a second insulating layer to cover the semiconductor layer and the second conductive layer; forming a third conductive layer to be electrically connected to the second conductive layer; performing first heat treatment after forming the semiconductor layer and before forming the second insulating layer; and performing second heat treatment after forming the second insulating layer.