The present invention provides a system and method to mineralize CO.sub.2 into peridotite rocks in a controlled and efficient manner removing carbon permanently from the atmosphere. Carbon dioxide sequestration into peridotite rocks happens naturally by means of natural weathering. However, this process is so slow and might take thousands of years to transform considerable amount of CO.sub.2 into carbonate rocks. The present invention, however, shortens the time of mineralization considerably in a controlled and quantifiable manner. This is typically done by injecting CO.sub.2 into peridotite rock formation and creating an efficient reaction pathways and conditions for the mineralization reaction to happen and therefore store CO.sub.2 by conversion into magnesite (MgCO.sub.3) and calcite (CaCO.sub.3).

An air purification apparatus includes an adsorption unit, a purification passage, and a regeneration passage. The adsorption unit adsorbs carbon dioxide and water vapor in air. The purification passage introduces air in a passenger compartment into the adsorption unit, and returns air, from which the carbon dioxide and the water vapor are adsorbed and removed by the adsorption unit, into the passenger compartment. The regeneration passage introduces air for regeneration into the adsorption unit, and discharges used air for regeneration obtained by regenerating the adsorption unit to an outside of the vehicle. An upstream side of the adsorption unit of the regeneration passage and the purification passage is constituted by an internal air introduction pipeline configured to introduce air from the passenger compartment.

Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock, and the Wobbe Index of said fuel is increased by a step of carbon dioxide removal or methanation.

The invention relates to a process for the combined production of hydrogen and carbon dioxide from a hydrocarbon mixture, in which the residual gas of a PSA H.sub.2 (12) is separated by permeation in order to reduce the hydrocarbon content thereof and the hydrocarbon-purified gas is separated at a low temperature to produce a carbon dioxide-rich liquid (22).

One or more embodiments relate to a method for removing CO.sub.2 from a gaseous stream containing CO.sub.2 having the steps of contacting the gaseous stream containing CO.sub.2 with a solvent at a first temperature and a first pressure to dissolve said CO.sub.2 in said solvent, where the solvent is made up of at least one ester, and where said at least one ester has two or more alkyl-ester functional groups on a central hydrocarbon chain.

Novel chemical sensors that improve detection and quantification of CO.sub.2 are critical to ensuring safe and cost-effective monitoring of carbon storage sites. Fiber optic (FO) based chemical sensor systems are promising field-deployable systems for real-time monitoring of CO.sub.2 in geological formations for long-range distributed sensing. In this work, a mixed-matrix composite integrated FO sensor system was developed that reliably operates as a detector for gas-phase and dissolved CO.sub.2. A mixed-matrix composite sensor coating on the FO sensor comprising plasmonic nanocrystals and zeolite embedded in a polymer matrix. The mixed-matrix composite FO sensor showed excellent reversibility/stability in a high humidity environment and sensitivity to gas-phase CO.sub.2 over a large concentration range. The sensor exhibited the ability to sense CO.sub.2 in the presence of other geologically relevant gases, which is of importance for applications in geological formations. A prototype FO sensor configuration which possesses a robust sensing capability for monitoring dissolved CO.sub.2 in natural water was demonstrated. Reproducibility was confirmed over many cycles, both in a laboratory setting and in the field.

The present disclosure relates to an absorber column apparatus for removing a selected component of a gas. The apparatus may have a first zone, a second zone and a third zone, wherein the first and third zones form a first domain through which a first fluid laden with a select gaseous component to be removed therefrom flows along concurrently with a second fluid. The second fluid at least substantially removes the select gaseous component from the first fluid to create a third fluid. The first fluid leaves the absorber column as a fourth fluid with the select gaseous component at least substantially removed therefrom. The second zone forms an active packing zone including a structure which forms an independent second domain in thermal communication with the first domain. The second receives a quantity of the third fluid and channels it through the second zone to help cool at least one of the first and second fluids.

Methods and systems to achieve clean fuel processing systems in which carbon dioxide emissions (1) from sources (2) may be processed in at least one processing reactor (4) containing a plurality of chemoautotrophic bacteria (5) which can convert the carbon dioxide emissions into biomass (6) which may then be used for various products (21) such as biofuels, fertilizer, feedstock, or the like. Sulfate reducing bacteria (13) may be used to supply sulfur containing compounds to the chemoautotrophic bacteria (5).

A process for production of ammonia includes: providing a reaction stream including carbon monoxide and hydrogen; passing the reaction stream and steam over a water gas shift catalyst in a catalytic shift reactor, forming a shifted gas mixture depleted in carbon monoxide and enriched in hydrogen; passing the shifted gas mixture with an oxygen-containing gas over a selective oxidation catalyst at ≧175° C., forming a selectively oxidized gas stream with a portion of the carbon monoxide converted to carbon dioxide; removing some of the carbon dioxide from the selectively oxidized gas stream in a carbon dioxide removal unit; passing the carbon dioxide depleted stream over a methanation catalyst in a methanator to form a methanated gas stream, optionally adjusting its hydrogen:nitrogen molar ratio to form an ammonia synthesis gas; and passing the ammonia synthesis gas over an ammonia synthesis catalyst in an ammonia converter to form ammonia.

Structured adsorbent beds comprising a high cell density substrate, such as greater than about 1040 cpsi, and a coating comprising adsorbent particles, such as DDR and a binder, such as SiO.sub.2 are provided herein. Methods of preparing the structured adsorbent bed and gas separation processes using the structured adsorbent bed are also provided herein.