Solid-state supercapacitors and microsupercapacitors comprising printed graphene electrodes and related methods of preparation.

A method for the preparation of an electrode comprising a substrate made of an aluminium based material, vertically aligned carbon nanotubes and an electrically conductive polymer matrix, the method comprising the following successive steps: (a) synthesising, on a substrate made of an aluminium based material, a carpet of vertically aligned carbon nanotubes according to the technique of CVD (Chemical Vapour Deposition) at a temperature less than or equal to 650° C.; (b) electrochemically depositing the polymer matrix on the carbon nanotubes from an electrolyte solution including at least one precursor monomer of the matrix, at least one ionic liquid and at least one protic or aprotic solvent. Further disclosed is the prepared electrode and a device for storing and returning electricity such as a supercapacitor comprising the electrode.

A boron-sulfur-codoped porous carbon material and a preparation method is disclosed. The boron-sulfur-codoped porous carbon material includes a porous carbon, and B and S doped in the surface and pores of the porous carbon; where B has a doping content of 5.56 wt.% to 7.85 wt.%, and S has a doping content of 0.90 wt.% to 1.55 wt.%. Test results of examples show that the boron-sulfur-codoped porous carbon material has high doping contents of B and S, and abundant pores; in a three-electrode system, the material shows a maximum specific capacitance of 168 F.Math.g.sup.- .sup.1 to 290.7 F.Math.g.sup.-1 at 0.5 A.Math.g.sup.-1; after the material is assembled into a symmetrical supercapacitor, the supercapacitor has an ultra-high energy density of 11.3 Wh.Math.kg.sup.-1 to 16.65 Wh.Math.kg.sup.-1 in a neutral electrolyte system, and has a capacitance retention rate of 97.09% to 100.67% after 10,000 life tests.

The invention provides electrolyte compositions including a metal cation, an ionic liquid, and a chelator that coordinates the metal cation. The electrolyte compositions are advantageous as they exhibit increased ion transference, and thus increased total conductivity, relative to a pure ionic liquid electrolyte that coordinates the metal cation. The invention provides a general strategy to control the cation-anion dynamics that govern ionic liquid performance. Electrolytes of the invention may be useful for any suitable purpose, e.g., in primary and secondary batteries, supercapacitors, and solar cells.

Disclosed is a hybrid electrochemical cell with a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode. The hybrid electrochemical cell further includes a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode. An electrolyte is in contact with both the first conductor and the second conductor. In some embodiments, the hybrid electrochemical cell further includes a separator between the first conductor and the second conductor to prevent physical contact between the first conductor and the second conductor, while facilitating ion transport between the first conductor and the second conductor.

A porous silicon composite including: a porous silicon composite cluster comprising a porous silicon composite secondary particle and a second carbon flake on at least one surface of the porous silicon composite secondary particle; and a carbonaceous layer on the porous silicon composite cluster, the carbonaceous layer comprising amorphous carbon, wherein the porous silicon composite secondary particle comprises an aggregate of two or more silicon primary particles, the two or more silicon primary particles comprise silicon, a silicon suboxide of the formula SiO.sub.x, wherein 0<x<2 on a surface of the silicon, and a first carbon flake on at least one surface of the silicon suboxide, the silicon suboxide is in a form of a film, a matrix, or a combination thereof, and the first carbon flake and the second carbon flake are each independently present in a form of a film, particles, a matrix, or a combination thereof. Also a method of preparing the porous silicon composite, a carbon composite, an electrode, and a device, each including the porous silicon composite, and a lithium battery including the electrode.

A capacitor and a method for manufacturing the capacitor are provided. The capacitor comprises (1) a capacitor main body including an outer package case, an opening sealing member attached to an inside of an open portion of the outer package case and a terminal lead penetrating through the opening sealing member; (2) a base attached to an outside of the open portion of the outer package case, the base including an insertion through hole through which the terminal lead passes to be disposed on an outer side of the base; and (3) a resin layer between the base and the opening sealing member.

Disclosed here is a method for producing a graphene macro-assembly (GMA)-fullerene composite, comprising providing a mixture of graphene oxide and water, adding a hydroxylated fullerene to the mixture, and forming a gel of the hydroxylated fullerene and the mixture. Also described are a GMA-fullerene composite produced, an electrode comprising the GMA-fullerene composite, and a supercapacitor comprising the electrode.

A data center rack is disclosed. The data center rack comprises a plurality of chamber openings including computing devices; and at least one chamber opening including a mounted ultracapacitor module comprising a plurality of ultracapacitors. A data center comprising a data center rack is also disclosed.

An ultracapacitor that is capable of exhibiting good properties even after being subjected to high temperatures, such as experienced during solder reflow, is provided. The ultracapacitor contains a housing having sidewalls that extend in a direction generally perpendicular to a base. An interior cavity is defined between an inner surface of the base and the sidewalls within which an electrode assembly can be positioned. To attach the electrode assembly, first and second conductive members are disposed on the inner surface of the base. The electrode assembly likewise contains first and second leads that extend outwardly therefrom and are electrically connected to the first and second conductive members, respectively. The first and second conductive members are, in turn, electrically connected to first and second external terminations, respectively, which are provided on an outer surface of the base.