A continuous pyrolysis system including a pyrolysis chamber, a heating chamber, a feeding chamber having a pressure input, an output coupled to the pyrolysis chamber, and a feeding opening opened to ambient atmosphere, a flame injector injecting ambient air and combustible material into the heating chamber, a pumping device with an input coupled to the heating chamber, and an output coupled to the pressure input of the feeding chamber, a O.sub.2 sensor within the heating chamber, and/or a pressure transducer within the feeding chamber, and a controller coupled to the O.sub.2 sensor, the pressure transducer, the flame injector, and the pumping device, for controlling the flame injector to inject ambient air and/or combustible material to maintain within the heating chamber O.sub.2 concentration between 8% and 10%, and/or for controlling the pumping device to maintain pressure in the feeding chamber above ambient pressure.

Asphalt binders are modified using fractional products from waste tire pyrolysis, using an initial step of i) at least partially pyrolyzing, separately from such asphaltic binder, whole rubber articles or size-reduced rubber particles to provide one or more pyrolyzed rubber fractions including a pyrolyzed oil fraction having a selected minimum initial boiling point or flash point, and ii) removing some or all polycyclic aromatic hydrocarbon (PAH) compounds from such pyrolyzed oil fraction to provide a reduced-PAH and preferably translucent pyrolyzed oil fraction that may be combined with an asphaltic binder to provide a modified asphalt composition.

Mechanical stirred bed reactors that incorporate a screen are described. Methods of using such reactors to process perfluoropolymers to form perfluorinated olefin monomers are also described. The reactors and methods may be used to upcycle filled perfluorinated materials.

A fluidized bed reactor for biomass treatment comprising a vessel extending in a first direction from a first end to a second end, an inlet at the first end of the vessel for feeding biomass particles into the vessel, an outlet at the second end of the vessel for outputting processed biomass, a first fluid inlet independently activatable to deliver a first volume of a gas in a second direction into a first region of the vessel, and a second fluid inlet spaced apart from the first fluid inlet in the first direction and independently activatable to deliver a second volume of the gas in the second direction into a second region of the vessel, the second region adjacent the first region.

A thermoplastic polyolefin composition which is capable of being shaped and repeatedly recycled, comprises propylene-based polymers, said composition being modified with 0.01-5 wt % of organic oligomeric silanes selected from partially hydrolyzed alkoxy substituted vinyl, allyl or methacryl silanes, and blends thereof, and 0.0005-0.5 wt % of a compound capable of generating free radicals.

A process and system for liquefying and plasticizing a waste plastic in a pyrolysis film reactor are provided. More particularly, a liquefied waste plastic, which may include halogen-depleted molten waste plastics, may be pyrolyzed in a pyrolysis film reactor to form a pyrolysis oil and a pyrolysis gas. The pyrolysis film reactors may include a falling film reactor and/or an upflow film reactor.

A hydrogen composition having a recycle content value is obtained by processing a recycle content feedstock to make a recycle content hydrogen or by deducting from a recycle inventory a recycle content value applied to a hydrogen composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by a hydrogen manufacturer has its origin in recycled waste plastics.

The present invention relates to a process for purifying a crude nitrogen-containing, sulfur-containing, halogen-containing pyrolysis oil originating from the pyrolysis of plastic waste, comprising (i) subjecting the crude pyrolysis oil to a treatment with a trapping agent selected from (a) an elemental metal of group 1, 2, 6, 7, 8, 9, 10, 11, 12, 13 of the IUPAC periodic table, a mixture or an alloy thereof; (b) an oxide of metals of group 1, 2, 6, 7, 8, 9, 10, 11, 12, 13 of the IUPAC periodic table or a mixture thereof; (c) an alkoxide of metals of group 1, 2 of the IUPAC periodic table or a mixture thereof; (d) a solid sorption agent as defined in the claims; or a combination of at least two trapping agents (a), (b), (c) or (d); (ii) separating the product obtained into a purified pyrolysis oil fraction having a reduced nitrogen, sulfur and halogen content in relation to the crude pyrolysis oil and a fraction comprising the trapping agent which has bound at least a part of the sulfur, nitrogen, halogen present in the crude pyrolysis oil

A method for thermally decomposing a carbonaceous waste material including: filling a reactor defined by a reactor wall with the waste material and an auxiliary material, resulting in a reactor content, the auxiliary material including abrasive particles; heating the reactor contents in the absence of oxygen, such that gaseous products are formed by pyrolysis of the waste material and the abrasive particles do not melt or thermally decompose; moving the reactor contents during the pyrolysis, the moving being adapted to mix the reactor contents and to cause the abrasive particles to scrape over at least parts of the reactor wall. The auxiliary material has a composition to include a component adapted to bind halogens present in the gaseous products and/or so that the brittleness of the auxiliary material is greater than the brittleness of the reactor wall.

The present disclosure provides for articles formed of a filled polymeric resin material. More specifically, the present disclosure relates to polymeric resin materials that include a filler that includes of a mixture of cured rubber granules, foam granules, and/or textile fibers. The filler can be suspended in and/or encapsulated by the polymeric resin material. The polymeric resin material, the filler, or both can include waste or scrap material from manufacturing or from ground post-consumer waste.