Processes for producing ethylene-based polymers and oligomers from ethanol include the steps of contacting the ethanol and a catalyst to produce a reaction mixture containing ethylene, wherein a first portion of the ethanol is derived from a biomass and a second portion of the ethanol is derived from a plastic, a mixed solid waste stream, or a combination thereof, separating at least a portion of the ethylene from the reaction mixture, and contacting ethylene with a suitable polymerization or oligomerization catalyst composition to produce the ethylene polymer or ethylene oligomers. A related process for producing ethylene-based polymers and oligomers uses a first ethylene feed derived from ethanol and a second ethylene feed derived from a plastic, a mixed solid waste stream, or a combination thereof.

A furnace, and a method of firing it, wherein part of the fuel supplied to the furnace is produced from waste plastics by a depolymerisation process, waste heat from the furnace being used to promote the depolymerisation process. The furnace is equipped with regenerators for waste heat recovery and is fired alternately in first and second opposed directions, with the direction of firing periodically reversing between the first direction and the second direction. The supply of fuel to the furnace is temporarily interrupted while the direction of firing is reversing, means being provided to accommodate the fuel produced during the temporary interruption. The furnace may be used for producing glass.

A method of recycling a PET-containing material comprises: (1) providing an MRS extruder having an MRS section comprising a plurality of satellite screws and an outlet; (2) providing a vacuum pump in communication with the MRS section; (3) providing a spinning machine comprising an inlet, wherein the inlet is directly coupled to the outlet of the MRS extruder; (4) heating a plurality of PET-containing flakes in the MRS extruder to form a PET-containing melt; (5) increasing a surface area of the PET-containing melt by distributing the PET-containing melt across the plurality of satellite screws in the MRS extruder; (6) drawing off vapors from the PET-containing melt by reducing the pressure in the MRS section with the vacuum pump; (7) collating the PET-containing melt in the MRS extruder; and (8) extruding the PET-containing melt through the outlet of the MRS extruder into the inlet of the spinning machine.

A method of recycling a PET-containing material comprises: (1) providing a polymer crystallizer comprising at least one heating element, and at least one blower; (2) providing an MRS extruder having an MRS section comprising a plurality of satellite screws; (3) providing a vacuum pump in fluid communication with the MRS section; (4) grinding and washing the PET-containing material; (5) heating the PET-containing material in the crystallizer to at least partially dry the PET-containing material; (6) shearing the PET-containing material in the MRS extruder to produce a PET-containing melt; (7) increasing a surface area of the PET-containing melt by distributing the PET-containing melt across a plurality of satellite screws in the MRS extruder; (8) drawing off vapors from the PET-containing melt by reducing the pressure in the MRS section with the vacuum pump; (9) collating the PET-containing melt in the MRS extruder; and (10) extruding a recycled PET-containing material.

The present disclosure pertains to coatings with self-repairing capabilities. In some embodiments, the coatings may include a polymer blend, made up of at least two polymers. The coatings may further contain compatibilizers that are nanocontainer particles. The nanocontainers may be filled with self-healing agents. The self-healing agents may be agents that heal cracks formed in the coating or they may be anti-corrosion agents that reduce the corrosion of the underlying metal substrate.

There are provided herein polymeric films and sheet structures comprising treated latex paint and one or more water-insoluble polymer component, methods for producing such films using a continuous film-making process, and articles thereof. Methods provided herein allow recycling of waste latex paint into thin films and sheets using continuous film-making processes and/or while controlling levels of toxic or volatile contaminants.

The present invention relates to a composition comprising a polymeric network having at least one unit of formula (I), (II), and/or (III); (I) (II) (III) wherein said composition is obtained by contacting at least one compound A comprising at least two functions selected from the group of function of formula X—C(═O)—CHR.sup.1—C(═O)—R.sup.2, —C(═O)—C—R.sup.2; or —C(═O)—CR.sup.1═CR.sup.2—NR.sup.4R.sup.5; wherein at least 25% by weight of compounds A have a functionality ≦5, with % by weight relative to the total weight of compounds A; with at least one compound B comprising at least one NH.sub.2, or NH.sub.3.sup.+ groups; wherein X, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, L.sup.1 and L.sup.2 have the same meaning as that defined in the claims. The present invention also relates to a compound comprising at least two units and at most 5 units of formula (I), (II), and/or (III); wherein R.sup.1, R.sup.2, R.sup.3, X, L.sup.1 and L.sup.2 have the same meaning as that defined in the claims. The present invention also relates to processes for preparing said composition and said compounds, to material, articles, and polymers comprising or using said compositions and compounds, and the use thereof.

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A process and an apparatus for pyrolysis of mixed plastic feedstock producing petroleum products are described. In one example, a process for producing petroleum products includes charging feedstock of mixed polymer materials into a reactor apparatus. Heat energy is applied to the feedstock while advancing the feedstock through the reactor apparatus in an anaerobic operation. The energy input to the reactor apparatus is controlled by controlling a temperature gradient within the reactor vessel to produce petroleum gas product. The process involves in situ chemical reactions comprising cracking and recombination reactions that that are controlled to convert solid hydrocarbonaceous portion of the feedstock to molten fluids and gases inside the reactor vessel and to produce gaseous petroleum products which exit the reactor vessel. The separated solid residue from the pyrolysis process is also removed from the reactions vessel.

A pyrolysis device and process to convert a carbonaceous feedstock to a carbon solid and pyrolysis gas, and processes for refining the resulting carbon solid and pyrolysis gases. The pyrolysis process may include introducing a carbonaceous feedstock into a pyrolysis processor having a vertical rotary tray processor, heating the feedstock to a temperature above about 790° F., removing a carbon material from a bottom of the pyrolysis processor, and removing a pyrolysis gas from a top of the pyrolysis processor.

A catalyst is illustrated, which has 70-90 parts by weight of mica, 1-10 parts by weight of zeolite, 5-15 parts by weight of titanium dioxide, 1-10 parts by weight of aluminum oxide, 1-5 parts by weight of sodium oxide and 1-5 parts by weight of potassium oxide. The present disclosure also illustrates a pyrolysis device using the catalyst, and further illustrates a pyrolysis method using the catalyst and/or the pyrolysis device for thermally cracking an organic polymer.