There is described a low number average molecular weight (M.sub.N<10 kD) and high glass transition temperature (>75 C.) copolymer (optionally a solid grade oligomer (SGO)) that comprises (a) at least 20 wt-% of itaconate functional monomer(s), (b) not more than 40% of a hydrophilic monomer, preferably an acid functional monomer(s) in an amount sufficient to achieve an acid value from 65 to 325 mg KOH per g of solid polymer; (c) optionally not more than 70% of other monomers not being either (a) or (b), having a max content of vinyl aromatic monomer(s) of 40 wt-% and/or max content of methacrylate(s) of 40 wt-%; where the weight percentages of monomers (a), (b) and (c) are calculated as a proportion of the total amount of monomers in the copolymer being 100%.

An optical film including an acrylic resin having a lactone ring structure in a main chain thereof and an acrylonitrile-styrene resin, wherein a tensile elastic modulus in a machine direction, which are abbreviated as EMD, and a tensile elastic modulus in a direction perpendicular to the machine direction, which is abbreviated as ETD, satisfy the relationship of Equation (1): Equation (1) EMD/ETD<0.8.

Water resistant, acrylic emulsion pressure sensitive adhesive polymers containing particles having a mean volume-average particle diameter of greater than about 210 nm for use in label and tape application are provided. The emulsion polymers exhibit an increase in opacity of less than about 10%.

A method of producing a polarizing plate according to an embodiment includes: applying an application liquid containing a polyvinyl alcohol-based resin and a surfactant onto a resin substrate to produce a laminate in which a polyvinyl alcohol-based resin layer is formed on the resin substrate; stretching and dyeing the polyvinyl alcohol-based resin layer formed on the resin substrate to produce a polarizing film; laminating an optical functional film on a polarizing film side of the laminate to produce an optical functional film laminate; and peeling the resin substrate from the optical functional film laminate. A content of the surfactant in the application liquid is less than 1 part by weight with respect to 100 parts by weight of the polyvinyl alcohol-based resin.

An acrylic adhesive composition is provided comprising a free-radical polymerizable monomer, an initiation system and a co-accelerator that enhances the reactivity of the initiation system by increasing the reaction rate between the oxidizing agent and the reducing agent. The free radical-polymerizable monomer preferably comprises methyl methacrylate (MMA), the initiator system preferably comprises N,N-diisopropanol-p-toluidine (DIIPT) and benzoyl peroxide (BPO), and the co-accelerator preferably comprises 1,4-diazabicyclo[2.2.2]octane (or triethylene diamine (TDA)).

The invention describes a double-sided, carrierless self-adhesive tape which can be used in particular for achieving very durable adhesive bonding of a variety of articles. This double-sided, carrierless self-adhesive tape is composed of a homogeneously crosslinked pressure-sensitive acrylate hotmelt composition of single-layer construction, which may have been lined with release materials such as siliconized release papers or release films. The double-sided, carrierless pressure-sensitive adhesive tape is characterized in that it is composed of a photoinitiator-free, thermally homogeneously crosslinked acrylate hotmelt which is crosslinked predominantly by way of urethane units. It is notable in particular for the fact that it is homogeneously chemically crosslinked through the layer and, in contrast to acrylate layers crosslinked by radiation (UV/EBC), does not exhibit any profile of crosslinking through the layer. It can be used in particular as an adhesive transfer tape for the permanent attachment of articles to a variety of substrates.

A method, and an article made therefrom, of: contacting a substrate with a first solution of a first polyelectrolyte polymer to form a layer of the first polyelectrolyte polymer on the substrate; and contacting the layer of the first polyelectrolyte polymer with a second solution of a second polyelectrolyte polymer to form a layer of the second polyelectrolyte polymer on the layer of the first polyelectrolyte polymer. The first polyelectrolyte is a polyanion or polycation polymer. The second polyelectrolyte is a polyanion or polycation polymer of a charge opposite to that of the first polyelectrolyte polymer. At least one of the first solution or the second solution is an aggregate-forming solution comprising an ionic species having at least two discrete sites of a charge opposite to that of the polyelectrolyte polymer in the aggregate-forming solution. The ionic species forms, via bridging interactions, aggregates of the polyelectrolyte polymer that remain intact in the aggregate-forming solution during the contact and layer formation.

A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.

Provided is a decorative sheet which can impart, to molded resin articles, excellent design attractiveness and an excellent touch both due to a rugged shape. The decorative sheet comprises, superposed in the following order, a base layer, a surface layer which is constituted of a cured object obtained from a curable resin composition and has the rugged shape, and a removable thermoplastic resin film.

Provided is a film for blister packs having barrier capability that is excellent in terms of impact resistance and thermal stability. Also provided is a vinylidene chloride polymer-containing latex that is ideal for producing the film. The coating layer of the film for a blister pack, and the latex, comprise a vinylidene chloride copolymer having a weight-average molecular weight, Mw, between 120,000 and 300,000 that is obtainable by emulsion polymerizing 70 to 95 parts by mass of vinylidene chloride and 30 to 5 parts by mass of one or more other monomer(s) copolymerizable with the vinylidene chloride, with the proviso that the total amount of vinylidene chloride and the other monomer(s) is 100 parts by mass).