A Reflux Rinsing method for purifying crystals using solvent vapor through dynamic equilibrium recrystallization. Feed material having tetrahydrocannabinol acid (THCA) is inserted into a reaction vessel having walls, and upper portion, and a lower portion with a bottom surface. The feed material is exposed to a hydrocarbon liquid in the reaction vessel in a quantity sufficient to keep liquid present in equilibrium with gas in the reaction vessel through the recrystallization process, forming a raw extract having THCA. The walls and bottom surface of the reaction vessel are coated with raw extract. The reaction vessel is heated and then the heating is discontinued. Vapor/thin-film DER is promoted in the reaction vessel for a predetermined length of time with no solvent reflux, resulting in formation of purified crystals of THCA under pressure. The hydrocarbon solvent is reclaimed from the reaction vessel, leaving the purified crystals and impurities. When the reaction vessel is opened, the purified crystals and impurities are removed.

Compositions and methods are provided for producing crystalline forms of organic acids or salts or lactones thereof from an aqueous solution. More specifically, methods are provided for producing a crystalline form of a salt of mevalonic acid (also referred to as X-MVA) from an aqueous solution, comprising subjecting the aqueous solution comprising said X-MVA to a purification step to produce a purified solution and crystallizing said X-MVA from said purified solution by water solvent crystallization. Methods are also provided for producing mevalonolactone from an aqueous solution comprising X-MVA, comprising subjecting the aqueous solution comprising said X-MVA to cation exchange thereby converting said aqueous solution comprising X-MVA to an aqueous solution comprising mevalonolactone (MVL). Methods are also provided for producing mevalonolactone monohydrate crystals.

A sample cell including a sample space, restricted on its first side by a first inner side of a first membrane and on its second side by a second inner side of a second membrane. A spacer is arranged between the first and the second inner sides to establish a distance between the membranes. A first retaining element is arranged on a first outer side, facing away from the sample space, of the first membrane and a second retaining element is arranged on a second outer side, which faces away from the sample space, of the second membrane, the first and second retaining elements together form a retaining structure. The first and second retaining elements each have a plurality of apertures aligned with each other in a direction transverse to the flat sides, to form a plurality of examination windows, in which the outer sides of the membranes are exposed.

A method for crystallization of β-ammonium tetramolybdate includes: performing a stepwise pH-adjusting treatment of an ammonium molybdate solution via zoning to obtain the β-ammonium tetramolybdate. When feeding the ammonium molybdate solution into a reaction system from a first zone and then into second to sixth zones successively, pH.sup.1 of a resultant solution in the first zone is 7.0-6.0; pH.sup.2 of a resultant solution in the second zone is less than 6 and greater than or equal to 4; pH.sup.3 of a resultant solution in the third zone is less than 4 and greater than or equal to 2.5; pH.sup.4 of a crystallized slurry in the fourth zone is less than 2.5 and greater than or equal to 1; pH.sup.5 of a crystallized slurry in the fifth zone is 2.5-4.0; and pH.sup.6 of a crystallized slurry in the sixth zone is less than 2.5 and greater than or equal to 2.0.

A method includes supplying a supersaturated brine stream having a plurality of minerals and anti-scalant from a water treatment system to a gypsum removal system disposed within a mineral removal system. The gypsum removal system includes a gypsum reactor that may receive the supersaturated brine, may deactivate the anti-scalant such that gypsum precipitates from the supersaturated brine, and may generate a gypsum slurry having a mixture of desupersaturated brine, precipitated gypsum, and the anti-scalant in solution with the desupersaturated brine. The method also includes supplying gypsum seed crystals to the gypsum reactor. The gypsum seed crystals may precipitate the gypsum from the supersaturated brine to generate the gypsum slurry. The method also includes directing a first portion of the gypsum slurry from the gypsum reactor to a gypsum settler. The gypsum settler may reactivate the anti-scalant such that the anti-scalant absorbs onto the precipitated gypsum to remove the anti-scalant from the desupersaturated brine and may generate anti-scalant-gypsum crystals and a desupersaturated overflow having at least a portion of the plurality of minerals. The method further includes generating the gypsum seed crystals supplied to the gypsum reactor using the anti-scalant-gypsum crystals.

A method of activating and dewatering sludge through application of acoustic pressure shock waves to wastewater.

Techniques for growing crystalline calcium carbonate solids such that the crystalline calcium carbonate solids include a volume of 0.0005 mm.sup.3 to 5 mm.sup.3, include a slaker to react quicklime (CaO) and a low carbonate content fluid to yield a slurry of primarily slaked lime (Ca(OH).sub.2); a fluidized-bed reactive crystallizer that encloses a solid bed mass and includes an input for a slurry of primarily slaked lime, an input for an alkaline solution and carbonate, and an output for crystalline calcium carbonate solids that include particles and an alkaline carbonate solution; a dewatering apparatus that includes an input coupled to the crystallizer and an output to discharge a plurality of separate streams that each include a portion of the crystalline calcium carbonate solids and alkaline carbonate solution; and a seed transfer apparatus to deliver seed material into the crystallizer to maintain a consistent mass of seed material.

A method for producing high purity D-psicose crystals having a purity of 98% (w/w) or more and a grain size of MA200 or more. The method includes: removing impurities from a D-psicose solution to obtain a purified D-psicose solution; concentrating the purified D-psicose solution; cooling the concentrated D-psicose solution to 30° C. to 40° C. through a heat exchanger; seed crystallizing the D-psicose solution at 30° C. to 40° C. to obtain a seed crystallized massecuite; and full-scale crystallizing the seed crystallized massecuite. The method can produce pure D-psicose crystals in a suitable form for industrial application through an economical crystallization process from the D-psicose solution without using organic solvents.

A method of crystallizing α-lactose monohydrate from an aqueous solution comprising dissolved α-lactose and β-lactose, said method comprising: circulating a first volume of said aqueous solution in a mutarotation loop in a mutarotation loop system (100); said mutarotation loop system comprising a crystallization tank (110) and a mutarotation tank (130).

The invention generally relates to systems with anti-fouling control and methods for controlling fouling within a channel of a plug flow crystallizer. In certain aspects, the invention provides a system that includes a plug flow crystallizer having a channel, one or more heating/cooling elements, each operably associated with a different segment of the channel, and a controller. The controller is operably coupled to the one or more heating/cooling elements and configured to implement a temperature profile within the channel of the plug flow crystallizer that grows crystals in a plug of fluid that flows through a first segment of the channel and dissolves encrust in a second segment of the channel while having minimal impact on crystal growth in the plug of fluid in the second segment of the channel. In certain embodiments, these segments may be cyclically alternated, in that the segment in which crystal grows in one cycle becomes the segment in which crystal dissolves in the next cycle and vice versa, to realize a fully continuous crystallization process.