Various embodiments disclosed relate to extraction of target materials using a CZTS sorbent. A method of extracting a target material from a medium includes contacting a copper zinc tin sulfur (CZTS) sorbent with the target material in the medium including the target material to form a used CZTS sorbent that includes the target material.

Systems and methods for operating a water recovery system are disclosed and include activating a condenser of the water recovery system. The method includes measuring a temperature associated with the condenser based on data obtained from a condenser temperature sensor. The method includes comparing the temperature associated with the condenser to a maximum threshold temperature. The method includes activating an auxiliary condenser of the water recovery system in response to the temperature associated with the condenser being greater than the maximum threshold temperature.

The removal of acid gases (e.g., non-carbon dioxide acid gases) using sorbents that include salts in molten form, and related systems and methods, are generally described.

Various illustrative embodiments of a system and process for recovering high-quality biomethane and carbon dioxide product streams from biogas sources and utilizing or sequestering the product streams are provided. The system and process synergistically yield a biomethane product which meets gas pipeline quality specifications and a carbon dioxide product of a quality and form that allows for its transport and sequestration or utilization and reduction in greenhouse gas emissions. The system and process result in improved access to gas pipelines for products, an improvement in the carbon intensity rating of the methane fuel, and improvements in generation of credits related to reductions in emissions of greenhouse gases.

An improvement in a wet scrubbing process for treating gaseous industrial process streams which contain one or more of SO.sub.2, SO.sub.3, H.sub.2SO.sub.4 which comprises contacting the stream of gas with a countercurrent flow of liquid derived from a circulating liquid stream which includes (i) a purge stream configured to remove a portion of the circulating liquid having a concentration of H.sub.2SO.sub.4 from the process, and (ii) a liquid make-up stream configured to replace the portion of the circulating liquid that is removed from the circulating liquid stream, the improvement comprising controlling the flow of liquid make-up whereby the concentration of H.sub.2SO.sub.4 in the purge stream is increased to a useful value; and filtering the purge stream to remove unwanted contaminants to yield a clarified purge stream.

A process is presented where a feed stream containing a hydrogen sulfide and another feed component is introduced into an absorber that the feed stream flows upward from the bottom of the absorber and contacts a liquid treatment solution, where the liquid treatment solution contains a sulfur dye catalyst. The hydrogen sulfide is absorbed into the liquid treatment solution and converted into sulfide ions. The other feed component is removed from the absorber vessel substantially free of the hydrogen sulfide and a spent treatment solution is also removed from the absorber vessel and fed to an oxidation vessel where it is contacted with an oxygen containing gas causing the sulfide ions to oxidize to thiosulfate and converting the spent sulfur dye catalyst to regenerated sulfur dye catalyst. The thiosulfate is recovered, and the regenerated sulfur dye catalyst can be recycled as part of the liquid treatment solution.

An embodiment of the present invention relates to an aqueous solvent solution for absorbing carbon dioxide, and a process using an aqueous solvent solution for absorbing carbon dioxide. The aqueous solvent solution having a catalytic compound dissolved in the water that is an alkali salt of an N-substituted amino acid and at least one base that is dissolved in water. The catalytic compound assisting in forming a bicarbonate.

Methods for enzyme-enhanced CO.sub.2 capture include contacting a CO.sub.2-containing gas with an aqueous absorption solution at process conditionssuch as high temperature, high pH, and/or using carbonate-based solutionsin the presence of Thermovibrio ammonificans carbonic anhydrase (TACA) or functional derivative thereof for catalyzing the hydration reaction of CO.sub.2 into bicarbonate and hydrogen ions and/or catalyzing the desorption reaction to produce a CO.sub.2 gas. The TACA may be provided to flow with the solution to cycle through a CO.sub.2 capture system that includes an absorber and a stripper.

A method and a plant for capturing CO2 from an incoming flue gas. The flue gas can be exhaust gas from coal and gas fired power plants, cement factories or refineries. The incoming exhaust gas is cooled, mixed with air and compressed, and thereafter introduced into a combustion chamber together with gas and/or liquid fuel. Part of the combustion is achieved by separate burners with cooling/combustion air feed with a volume equal to the volume of CO2 captured. Said burners will elevate the temperature in the combustion chamber allowing combustion of exhaust gas with low oxygen content. CO2 is captured at high partial pressure before expansion by the gas turbine to produce power and generate steam in the heat recovery unit. The gas turbine will operate with high efficiency close to design parameters with respect to inlet temperature, pressure and flow.

The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises subjecting ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) to condensation under acidic conditions so as to form an acidic condensate, and using at least part of the acidic condensate as an acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.