Devices, systems and methods for using photosynthetic biomass to purify water, reduce indoor air pollution, remove greenhouse gases including CO.sub.2 from outdoor atmospheric air, and produce biofuel, food products, and fertilizer are provided herein. Also provided herein are systems and methods for enhancing growth of a photosynthetic biomass in a greenhouse.

The disclosure generally relates to CCS sorbents, particularly for CO.sub.2/H.sub.2O displacement desorption process. The sorbent includes an aluminum oxide support and an alkali metal salt impregnated on the support, and a silicon modification of the sorbent to reduce water uptake by the sorbent and make it more hydrophobic. The silicon modification can be an organosilyl moiety added after the initial sorbent is complete, or a silica source added to the aluminum oxide structure, typically via impregnation. The sorbents demonstrate better H.sub.2O/CO.sub.2 ratios. Compositions and methods of making are disclosed.

A system and method for enhancement of CO.sub.2 concentration in closed or semi closed spaces, wherein said system comprises a unit (3) for capturing CO.sub.2 from ambient air, said unit further comprises two process units (134, 172) capable of 5 adsorbing and desorbing CO.sub.2 on an adsorbent, and working alternately in adsorbing and desorbing mode.

Disclosed are embodiments of a filter unit containing a water adsorbent material in the form of water adsorbent particles in a packed bed and a gas adsorbent material in the form of gas adsorbent particles in a packed bed. In embodiments, the gas adsorbent material is downstream from the water adsorbent material in a direction of operation. Further disclosed are methods of preparing and using the filter units.

The present invention relates to methods of preferentially sorbing, from a target mixture, one or more target substance(s) over one or more non-target substance(s). In particular, porous organic cages (POCs) may be deployed in the quantum sieving of mixtures of hydrogen isotopes to selectively sorb heavy hydrogen isotopes (e.g. diatomic deuterium) over lighter isotopes (diatomic protium).

The present invention relates to an organic-inorganic hybrid nanoporous material, maintaining a nanoporous skeleton structure formed by coordination of an organic ligand containing an aromatic compound to a trivalent central metal ion, and further having an intramolecular acid anhydride functional group modified on the aromatic compound of the nanoporous skeleton structure, and thereby exhibits selectivity for olefins, and an adsorbent comprising the same. Specifically, the organic-inorganic hybrid nanoporous material of the present invention exhibits an excellent olefin-selective adsorption capacity through differences in adsorption equilibrium and adsorption rate, and thus can be usefully employed in the separation of C2-C4 hydrocarbons. Further, the olefins adsorbed to the organic-inorganic hybrid nanoporous material can be desorbed by purging of an inert gas which is not liquefied by way of mild vacuum conditions or compression, and thus, the organic-inorganic hybrid nanoporous material can be used to prepare olefins by separating C2-C4 hydrocarbon mixtures.

A gas separation unit for the separation of a first gas, carbon dioxide, from a mixture, by using an adsorption/desorption process using a loose particulate sorbent material arranged in at least two stacked layers. The primary heat exchange piping is arranged on the two outer edges of the layer within the cavity extending along a longitudinal direction. Further, an essentially parallel array of secondary heat exchange pipes is provided, the secondary heat exchange pipes extending along a transverse direction. The first diameter of the secondary heat exchange pipes is at least twice as large as the second outer diameter of the secondary heat exchange pipes and the secondary heat exchange pipes are in thermal contact with sheets of metal which extend oscillating between pairwise adjacent secondary heat exchange pipes.

Regeneration of a fluid medium can be accomplished using a continuously regenerable scrubber, which, in its various embodiments, combines valve functions and sorbent material, such as amine beds, into one component, dramatically reducing size and mass of scrubber. Sorbent material beds rotate continuously past breathing gas vent loop ports for scrubbing CO.sub.2/H.sub.2O and then past vacuum ports for regenerating the sorbent material. Typically, a first fluid output is connected to a lower header fluid output and a second, sweeping fluid source connected to a lower header fluid input. A motor spins the substantially circular bed assembly at a predetermined speed which allows adsorption or absorption as well as desorption of materials flowing through the sorbent material.

Disclosed herein is a method for obtaining compounds and compositions from plant and fungus materials by thermal treatment, affinity capture, filtration, and release through multi-phasic transitions between gas, solid, and liquid states. The compounds of interest are obtained by manipulating the temperature and pressure of the heating chamber. The compounds in gas phase are passed through an affinity medium which captures the compounds of interest in either solid or liquid phase by exposing the compound of interest to the localized micro-affinity environment of the medium. The compounds are separated from the medium using direct competition with solvent or buffers optimized for the specific chemical properties of compounds.

A carbon dioxide separation recovery method includes: bringing a particulate carbon dioxide adsorbent and a treatment target gas containing carbon dioxide into contact with each other to make the carbon dioxide adsorbent adsorb the carbon dioxide contained in the treatment target gas; and bringing the carbon dioxide adsorbent which has adsorbed the carbon dioxide and desorption steam into contact with each other to desorb the carbon dioxide from the carbon dioxide adsorbent, and thereby, regenerate the carbon dioxide adsorbent and recover the desorbed carbon dioxide. The step of recovering the carbon dioxide includes utilizing a recovery gas as a heat source of a heat exchanger, the recovery gas containing the desorption steam which has contacted the carbon dioxide adsorbent and the carbon dioxide which has been desorbed from the carbon dioxide adsorbent.