Described are bulk process gas purification systems and related methods, including systems that are adapted to use a volume of gas at an exterior surface of a vessel, e.g., a flow of the gas, to control a temperature of the vessel interior during a recharging step, during a cooling step that follows a recharging step, or both.

In a method for separating argon by cryogenic distillation, in which a flow containing argon, oxygen and nitrogen and being more rich in argon than the air is sent to a distillation column, and an argon-rich gas flow is withdrawn at the top of the column, a portion of the argon-rich gas flow is mixed with beads to form a gas mixture containing beads, the beads being capable of adsorbing oxygen in the presence of argon at the column operating temperatures; the portion of the argon-rich gas flow mixed with the beads is condensed and then sent to the top of the column; and a bottom liquid containing beads is withdrawn from the column and treated to remove the beads, the beads removed being regenerated to remove the adsorbed oxygen and being again mixed with the argon-rich gas flow.

In a helium purification process, a stream containing at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane is separated to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane and a second stream enriched in nitrogen and in methane, the helium-enriched stream is treated to produce a helium-rich product and a residual gas containing water, the residual gas is treated by adsorption (TSA) to remove the water and the regeneration gas from the adsorption is sent to a combustion unit (O).

The invention provides a method and system for separating xenon-krypton mixed gas by hydrate formation process. The system is mainly composed of a gas hydrate generating unit, a heat exchanging unit and a gas-water separating unit: pre-cooled xenon-krypton mixed gas is injected from a bottom of a reaction tower, xenon gas in the mixed gas and water attached to a porous tray generate a xenon gas hydrate; and water is injected from a top of the tower to wet the porous tray, a generated hydrate particle is washed and collected to the bottom of the tower simultaneously to form a hydrate slurry, after passing through the heat exchanging unit, the xenon gas hydrate in the slurry is decomposed to form a gas phase flow and a water phase flow, and then enters the gas-water separating unit, and the xenon gas is separated from decomposed water.

The present invention relates to a gas separation membrane including: a supporting membrane; and a separation functional layer which is provided on the supporting membrane and includes a crosslinked polyamide obtained by polycondensation of a polyfunctional amine and a polyfunctional acid halide, in which, in the crosslinked polyamide, the number A of terminal amino groups, the number B of terminal carboxy groups, and the number C of amide groups satisfy (A+B)/C≤0.66.

What is disclosed is a mass selective fluid bandpass filter. This filter provides for selecting gas molecules of a specific mass from a gas sample containing molecules of two or more mass species. This filter provides a means of operation of a selecting a predetermined gas from a group of gases or an atmosphere. The mass selective fluid bandpass filter consists of quartz glass, of either natural or manmade origin. This provides method of removing a predetermined gas from the group consisting of: .sup.1H.sub.2, .sup.1H.sup.2H, .sup.2H.sub.2, .sup.1H.sup.3H, .sup.2H.sup.3H, .sup.3H.sub.2, .sup.1H.sub.2O, .sup.1H.sup.2HO, .sup.2H.sub.2O, .sup.1H.sup.3HO, .sup.2H.sup.3HO, .sup.3H.sub.2O, .sup.3He, .sup.4He, O.sub.2, O.sub.3, .sup.12CO.sub.2, .sup.13CO.sub.2, .sup.14CO.sub.2, CO, N.sub.2, NO, NO.sub.2, NO.sub.x, SiO.sub.2, FeO, Fe.sub.2O.sub.3, SiF.sub.4, HF, NH.sub.3, SO.sub.2, SO.sub.3, H.sub.2SO.sub.4, H.sub.2S, .sup.35Cl.sub.2, .sup.37Cl.sub.2, F.sub.2, Al.sub.2O.sub.3, CaO, MnO, P.sub.2O.sub.5, phenols, volatile organic compounds, and peroxyacyl nitrates.

A piece of equipment commonly used in many petrochemical and refinery processes is a pressure swing adsorption (PSA) unit. A PSA unit may be used to recover and purify hydrogen process streams, such as from hydrocracking and hydrotreating process streams. Aspects of the present disclosure are directed to monitoring PSA unit processes for potential and existing issues, providing alerts, and/or adjusting operating conditions to optimize PSA unit life. There are many process performance indicators that may be monitored including, but not limited to, flow rates, chemical analyzers, temperature, and/or pressure. In addition, valve operation may be monitored, including opening speed, closing speed, and performance. The system may adjust one or more operating characteristics to decrease the difference between the actual operating performance in the recent and the optimal operating performance.

Embodiments of the present disclosure provide for an ortho (o)-hydroxy-functionalized diamine, a method of making an o-hydroxy-functionalized diamine, an o-hydroxy-functionalized diamine-based polyimide, a method of making an o-hydroxy-functionalized diamine imide, methods of gas separation, and the like.

The invention relates to a method (200-400) for extracting pure helium using a first membrane separation stage (1), a second membrane separation stage (2), and a third membrane separation stage (3), in which a first helium-containing feed mixture is supplied to the first membrane separation stage (1), a second helium-containing feed mixture is supplied to the second membrane separation stage (2), and a third helium-containing feed mixture is supplied to the third membrane separation stage (3), and in which a first permeate and a first retentate are formed in the first membrane separation stage (1), a second permeate and a second retentate are formed in the second membrane separation stage (2), and a third permeate and a third retentate are formed in the third membrane separation stage (3). According to the invention, the first feed mixture is formed using at least one portion of a helium-containing starting mixture, the second feed mixture is formed using at least one portion of the first permeate, the third feed mixture is formed using at least one portion of the second retentate, the second permeate is at least partially processed by pressure-swing adsorption in order to obtain the pure helium and a remaining mixture, and at least one portion of the third permeate and/or at least one portion of the third retentate is guided back into the method (200). The invention also relates to a corresponding system.

A helium-containing stream is recovered from a natural gas feed using a membrane followed by multiple distillation steps. Refrigeration is provided by expanding a bottoms liquid with a higher nitrogen content than the feed, achieving a lower temperature in the process. The helium-enriched vapor is then purified and the helium-containing waste stream is recycled to maximize recovery and reduce the number of compressors needed. The helium-depleted natural gas stream can be returned at pressure for utilization or transportation.