Treatment of radioactive waste comprising organic compounds and sulfur-containing compounds and/or halogen-containing compounds. An apparatus comprises a reaction vessel comprising a filter for carrying out thermal treatment of the waste and a thermal oxidizer. Utilizing co-reactants to reduce gas phase sulfur and halogen from treatment of wastes.

An apparatus and method for purifying a raw hydrogen gas stream of chloramines and chlorine is provided. The explosive chloramines compounds can be effectively captured by the carbon adsorbent without accumulating on the carbon surface. Rather, the chloramines are converted via decomposition, into non-explosive products with catalytic effect of the carbon material. Chlorine reacts with impregnated reducing agent on the carbon surface to form the solid products, which can be adsorbed on the carbon surface. The purified hydrogen gas contains little to no trace of chloramines and chlorine impurities, thereby making the hydrogen gas suitable for liquid hydrogen production.

Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO.sub.2 off-gas by heating the feed gas, optionally removing siloxanes and silanols from the heated feed gas, optionally removing part of the sulfur-containing compounds in the heated feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic conversion of any or all of the volatile organic compounds (VOCs) present in the gas, including sulfur-containing compounds, chlorine-containing compounds and any of the reactants injected, in at least one suitable reactor, and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H.sub.2, CO, ammonia, urea, methanol, ethanol and dimethyl ether (DME).

Treatment of radioactive waste comprising organic compounds, and sulfur-containing compounds and/or halogen-containing compounds. An apparatus comprises a reaction vessel comprising a filter for carrying out thermal treatment of the waste and a thermal oxidizer. Utilizing co-reactants to reduce gas phase sulfur and halogen from treatment of wastes.

A waste gas purification system according to an embodiment includes an adsorption-catalysis-oxidation unit, an enhanced absorption unit, an air inducing unit, and a flue gas discharge and heat exchange unit that are sequentially connected. The waste gas enters a heat exchange device of the flue gas discharge and heat exchange unit through a first waste gas delivery pipeline to perform heat exchange, then is converged with waste gas in a second waste gas delivery pipeline, and enters a third waste gas delivery pipeline. Waste gas in the third waste gas delivery pipeline is purified after sequentially passing through the adsorption-catalysis-oxidation unit and the enhanced absorption unit. Purified flue gas is introduced into the flue gas discharge and heat exchange unit by the air inducing unit, and the purified flue gas is discharged after performing heat exchange with the heat exchange device. In some embodiments, the waste gas purification system and method may implement deep treatment of complex waste gas containing organic and inorganic components.

A halogen gas removing agent for removing halogen gas from a gas flow, which reduces the risk of leakage of the halogen gas exhausted from a semiconductor production process by treating the gas flow with the removing agent and a process for producing the removing agent. Also provided are an apparatus for removing the halogen gas using the removing agent, and a method for monitoring the state of consumption of the halogen gas. The halogen gas removing agent includes an inorganic compound base material, a sulfur-containing reducing compound and a color indicator, preferably using a pseudoboehmite as the base material, adding a pH indicator having a transition range in a pH range of 3 to 8 as the color indicator, and adding a basic metal compound such as zinc oxide.

Described herein is a graphene and polyvinyl alcohol based multilayer composite membrane that provides selective resistance for solutes to pass through the membrane while providing water permeability. A selectively permeable membrane comprising a crosslinked graphene with a polyvinyl alcohol and an additive that can provide enhanced salt separation from water, methods for making such membranes, and methods of using the membranes for dehydrating or removing solutes from water are also described.

A method and system for the generation of a medium-Btu, clean and renewable fuel gas to replace fossil fuels in existing lime kilns with minimal retrofitting without significantly compromising the kiln capacity. A steam-blown dual fluidized bed gasifier produces renewable fuel gas from a carbonaceous feedstock such as woody biomass. A gas cleanup process purifies the raw fuel gas, resulting in a clean fuel gas for mitigation of lime contamination and environmental issues. The adiabatic flame temperature and flue gas volume/GJ for the combustion of the renewable fuel gas are similar to values for natural gas, making retrofitting of fossil fuel-fired lime kilns relatively straightforward.

This invention relates to metal organic framework (MOF) compositions, methods of preparing them and methods of using them. The MOF compositions are characterized in that at least a portion of the linker molecule is an amino containing organic linker. The MOF also has a crystal size of greater than 1 ?m and has been treated with an acid wash to provide a MOF in which at least 55% of the amino groups are activated amino groups of the form NH.sub.2. The MOF compositions are useful in adsorbing various contaminants from various gas stream. One specific example is adsorbing NO.sub.2 from an air stream.

This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.