Treatment of radioactive waste comprising organic compounds, and sulfur-containing compounds and/or halogen-containing compounds. An apparatus comprises a reaction vessel comprising a filter for carrying out thermal treatment of the waste and a thermal oxidizer. Utilizing co-reactants to reduce gas phase sulfur and halogen from treatment of wastes.

Herein are disclosed compositions of matter, processes of manufacture and processes of use of solid state admixtures that include an inorganic base and a sulfide selected from the group consisting of an ammonium sulfide, an alkali metal sulfide, an alkali-earth metal sulfide, transition metal sulfide, and a mixture thereof. The composition can include solid state inorganic bases (e.g., calcium hydroxide and sodium sesquicarbonate) and/or gaseous bases (e.g., ammonia) and, optionally, a support material for one or more of the inorganic base and sulfide. The compositions are useful for capturing environmental contaminants, for example, from the flue gas of a coal fired power plant.

A gas treatment device uses a gas to be treated which contains an acid compound that dissolves into water to produce acid and a treatment liquid which absorbs the acid compound to phase-separate, to separate an acid compound from the gas to be treated. The gas treatment device includes an absorber which brings the gas to be treated into contact with the treatment liquid; a regenerator 14 which heats the treatment liquid contacting the gas to be treated to separate an acid compound; and a liquid feeding portion which feeds the treatment liquid contacting the gas to be treated in the absorber to the regenerator. In the absorber, the treatment liquid contacting the gas to be treated phase-separates into a first phase portion having a high acid compound content and a second phase portion having a low acid compound content. The liquid feeding portion is configured to introduce, into the regenerator, the treatment liquid with the phase-separated first phase portion and second phase portion mixed.

The present invention relates to an apparatus and method for recovering carbon dioxide (hereinafter also referred to as CO.sub.2) contained in a combustion exhaust gas, and more specifically relates to: an apparatus and method for reactively absorbing CO.sub.2 contained in a combustion exhaust gas into an amine compound-containing absorption liquid; an apparatus and method for desorbing CO.sub.2 contained in an amine compound-containing absorption liquid from the amine compound-containing absorption liquid; an apparatus and method for evaporating and separating impurities from the amine compound-containing absorption liquid containing the impurities; an apparatus and method for performing a pretreatment such as desulfurization, dust removal, and cooling on a combustion exhaust gas; and a carbon dioxide-recovering apparatus and method utilizing the above apparatuses and methods.

Various embodiments disclosed relate to extraction of target materials using a CZTS sorbent. A method of extracting a target material from a medium includes contacting a copper zinc tin sulfur (CZTS) sorbent with the target material in the medium including the target material to form a used CZTS sorbent that includes the target material. The method also includes separating the used CZTS sorbent from the medium.

As an improvement to processes for desulfurization of natural gas and synthetic natural gas streams that employ conventional zeolitic materials (absorbents), including copper-containing zeolites, pre-treatment methods and post-treatment methods are provided that lower the level of leachable benzene following desulfurization with the absorbents to <0.5 mg benzene/L leachate, while retaining within the absorbents a majority of sulfur adsorbed from a gas stream.

The present invention relates to a fuel cell system (100a, 100b, 100c) comprising a fuel cell stack (5) having an anode portion (5a) and a cathode portion (5b), a reformer (3) for reforming fuel for use in the anode portion (5a) of the fuel cell stack (5), and a fuel tank (1) for providing the fuel to the reformer (3), wherein downstream of the fuel tank (1) and upstream of the reformer (3) there is located a desulphurization unit (2) with an adsorber (2a) for the adsorptive desulphurization of fuel, which is conducted from the fuel tank (1) via the desulphurization unit (2) to the reformer (3), wherein the adsorber (2a) is provided with anodes (5a) and cathode portions (5b) and/or an internal combustion engine (11) of the fuel cell system (100a; 100b; 100c) is in fluid communication by means of a regeneration fluid line (12), wherein fluid heated by the regeneration fluid line (12) can be conveyed from the anode portion (5a) and cathode portion (5b) and/or from the internal combustion engine (11) to the adsorber (2a). The invention also concerns a method for the thermal regeneration of desulphurization adsorbates and a motor vehicle equipped with the fuel cell system (100a, 100b, 100c) in accordance with the invention.

A solvent system comprising a diluent and a nitrogenous base for the removal of CO.sub.2 from mixed gas streams is provided. Also provided is a process for removing CO.sub.2 from mixed gas streams using the disclosed solvent system. The solvent system may be utilized within a gas processing system.

The system and method spatially predict the condensation of water and acid from the flue gas in the condensing heat exchanger installed in fossil power plant flue gas treatment system or similar environment. By modifying the operational conditions, the heat exchanger can control rates and areas of condensations. The system and method adjust either the cooling water temperature or the flowrate ratio of flue gas to cooling water to control the condensation rates of water or acids. The system and method also estimate actual coverage areas to apply for anti-corrosive coating onto the tube or duct surfaces to resist corrosion due to acid condensation. The system and method also optimize or customize condensation rates of water and acids in boiler flue gas under operating conditions given at a power plant.

Disclosed is a process for regenerating a hybrid solvent used to remove contaminants from a fluid stream and to provide an improved yield of purified fluid. Said process comprises at least one purification unit (12) and at least one regeneration unit (40) wherein condensed water (72) from the regeneration unit is combined with the regenerated lean hybrid solvent (55) prior to reuse in the purification unit and none of the condensed water is recycled into the regeneration unit.