This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.

Disclosed is an apparatus for preparing phosphoric acid from a fume exiting the kiln in a kiln phosphoric acid process, the apparatus comprises a hydration tower and an acid solution cyclical spraying system, a fume inlet of the fume exiting the kiln is disposed at a lower portion of the hydration tower, a fume outlet after hydration and absorption is disposed at the top, a spraying device is disposed in a cavity of the hydration tower above the fume inlet, a liquid inlet of the acid solution cyclical spraying system is disposed on a bottom of the hydration tower, a liquid outlet of the acid solution cyclical spraying system is connected to a liquid intake pipe of the spraying device. The present invention has the advantages of simple structure, reasonable layout, strong adaptability, high raw material utilization rate, reduced contaminant emissions, and high recovery rate of phosphoric acid etc.

A biogas combustion system that obtains a stable output and saves energy is realized. A combustion system comprises a separation portion 14 that removes carbon dioxide from a treatment target gas containing a mixture gas containing methane as a main component and containing carbon dioxide to obtain methane gas of a high purity in which at least a content of carbon dioxide has been reduced, and a combustion portion 15 that combusts the methane gas. The separation portion 14 includes a first treatment chamber 11 and a second treatment chamber 12 separated from each other by a separation membrane 13 therebetween. The separation membrane 13 selectively allows the carbon dioxide in the treatment target gas supplied to the first treatment chamber 11 to pass therethrough to the second treatment chamber 12 to obtain a first separation gas having a higher methane purity than the treatment target gas in the first treatment chamber 11 and a second separation gas containing the carbon dioxide in the treatment target gas in the second treatment chamber 12.

Embodiments of the present disclosure are directed towards methods for preparing mixed-metal oxide particles by heating adamantane-intercalated layered double-hydroxide (LDH) particles at a reaction temperature of from 400° C. to 800° C. to form mixed-metal oxide particles. The adamantane-intercalated LDH particles have a general formula [M.sub.1-xAl.sub.x(OH).sub.2](A).sub.x.mH.sub.2O, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate, and an aspect ratio greater than 100. The aspect ratio is defined by the width of an adamantane-intercalated LDH particle divided by the thickness of the adamantane-intercalated LDH particle. The mixed-metal oxide particles comprise a mixed-metal oxide phase containing M, Al or Fe, and carbon.

A detoxifying device 100 having an inner wall 104 that forms a flow passage 103 through which treatment gas flows includes a first piping 130 that forms a part of the flow passage 103, a replaceable piping section 170 that forms a part of the flow passage 103 at the position downstream of the first piping 130, and is connected thereto for sprinkling the cleaning water to remove the solid product adhering to the inner wall 104, and a second piping 150 that forms a part of the flow passage 103 at the position downstream of the piping section 170, and is connected thereto.

Through the procedures of pretreatment, temperature swing adsorption (TSA) coarse desorption, pressure swing adsorption (PSA) purification and hydrogen purification, the hydrogenous waste gas from various procedures in the manufacturing process of semiconductor (especially silicon wafer), including the off-gas from chemical vapor deposition (CVD), doping (diffusion and ion implantation), photolithography and cleaning, the combusted and washed discharged gas of the off-gas in other procedures after field treatment and centralized treatment, or the hydrogenous waste gas entering the hydrogen discharge system are purified to meet the standard for the electronic grade hydrogen required for the manufacturing process of semiconductor, the recycling of hydrogen resources is realized, and the yield of hydrogen is greater than or equal to 70-85%. The present invention solves the technical difficulty the normal-pressure waste hydrogen recovered in the manufacturing process of semiconductor can't be returned to the manufacturing process of semiconductor for reuse.

A method for generating Renewable Natural Gas (RNG) from raw biogas is disclosed, in which carbon dioxide is removed from biogas to generate pipeline specification RNG by a combination of absorption and membrane processes. The absorption process provides for the initial bulk carbon dioxide removal. The membrane process provides for the simultaneous removal of carbon dioxide and water vapors to pipeline specification. The method is characterized by a reduced separation energy consumption as compared to stand-alone membrane and absorption unit separations for biogas upgrading.

Adsorbent materials are disclosed, along with filter elements containing the adsorbent materials methods of using adsorbents to remove siloxane contaminants from a gas stream. The method includes providing an adsorbent material that has been washed with an acid and passing a gas through the adsorbent material so as to reduce siloxane levels in the gas. A filter element for reducing siloxane levels in a gas includes a first adsorbent material, the first adsorbent material comprising an acid-washed adsorbent; and a second adsorbent material, the second adsorbent material comprising an acid-impregnated adsorbent.

An absorbent composition having a bismuth material on a support containing at least one of a metal oxide, a metalloid oxide or an activated carbon and methods of making and using the same. The adsorbent composition is usful for adsorbing arsine from a fluid stream.

An apparatus for treatment of gaseous pollutants, the apparatus comprising a reaction portion and a passage. The reaction portion comprises a gas inlet unit, a reaction unit, a combustion unit and a cooling unit. The passage comprises a transverse section, a connection section and a straight section, the transverse section is provided with a top gas inlet in communication with the reaction portion and a lateral gas inlet, the connection section is connected between the transverse section and the straight section, the top gas inlet receives an effluent passing through the reaction portion and then flowing downwards, the lateral gas inlet receives a transverse air flow, and the effluent is driven by the transverse gas flow to form a cyclone and is discharged from an outlet of the straight section by means of the connection section.