The present invention relates to a polymer layered hollow fiber membrane based on poly(2,5-benzimidazole) (ABPBI), ABPBI copolymers and substituted polybenzimidazole (PBI) and a process for preparation thereof.

The present disclosure provides a process for producing a modified microporous membrane, comprising (i) Providing a first solution comprising at least one first polymer and at least one epoxy functional compound; (ii) Providing a second solution comprising at least one diamine compound; (iii) Bringing the first solution and the second solution into contact, thereby obtaining a modified microporous membrane comprising at least one first polymer and the crosslinked reaction product of the at least one epoxy functional compound and the at least one diamine compound; wherein the modified microporous membrane is a hollow-fiber membrane; and wherein the first solution is a dope solution, the second solution is a bore solution, and bringing the first and second solutions into contact takes place in a spinneret.

Chinese ink is applied on various materials and stabilized by atomic layer deposition to fabricate solar steam generation devices. The encapsulated ink has excellent photothermal properties and evaporation efficiency under simulated sunlight, holding great promise in solar evaporation device applications.

A thermo-electrochemical reactive capture apparatus includes an anode and a cathode, wherein the anode includes a first catalyst, wherein the cathode includes a second catalyst, a porous ceramic support positioned between the anode and the cathode, an electrolyte mixture in pores of the ceramic support, and a steam flow system on an outer side of the cathode. The outer side of the cathode is opposite an inner side of the cathode and the inner side of the cathode is adjacent to the ceramic support. In addition, the electrolyte mixture is configured to be molten at a temperature below about 600° C.

An electrochemical compressor utilizes an anion conducting layer disposed between an anode and a cathode for transporting a working fluid. The working fluid may include carbon dioxide that is dissolved in water and is partially converted to carbonic acid that is equilibrium with bicarbonate anion. An electrical potential across the anode and cathode creates a pH gradient that drives the bicarbonate anion across the anion conducting layer to the cathode, wherein it is reformed into carbon dioxide. Therefore, carbon dioxide is pumped across the anion conducting layer. The compressor may be part of a refrigeration system that pumps the working fluid in a closed loop through a condenser and an evaporator.

The present inventive concept relates to a chemically modified anion exchange membrane and a method of preparing the same and, more particularly, an anion exchange membrane in which sulfonic acid groups in a perfluorinated sulfonic acid electrolyte membrane are substituted with anion conductive groups such as ammonium group, phosphonium group, imidazolium group, pyridinium group and sulfonium group, and a method of preparing an anion exchange membrane by chemically modifying sulfonic acid groups in a perfluorinated sulfonic acid electrolyte membrane.

Chemically inert, mechanically tough, cationic metallo-polyelectrolytes designed as durable anion-exchange membranes (AEMs) via ring-opening metathesis polymerization (ROMP) of cobaltocenium-containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation to provide a new class of AEMs with a polyethylene-like framework and alkaline-stable cobaltocenium cation for ion transport, which exhibit excellent thermal, chemical and mechanical stability, as well as high ion conductivity.

Polymer-based membranes and methods for fabricating membranes are described. The methods include forming a casting solution featuring a plurality of titanium dioxide (TiO2) nanoparticles, a polyvinylidene fluoride (PVDF)-based solvent, and a polyvinylpyrrolidone (PVP)-based modifying agent, dispersing the casting solution to form a first element, generating a plurality of active sites on a surface of the first element, and forming a polymer-based membrane by exposing the surface of the first element to a fluorosilane composition to form a fluorosilane layer on the surface, where the fluorosilane composition includes a silane compound having at least one alkyl substituent that includes between 9 and 21 fluorine atoms.

Provided is a nanofiltration composite membrane, comprising: a supporting layer comprising a polyethylene terephthalate, a polymeric porous layer formed on the supporting layer, the polymeric porous layer comprising a polysulfone and an amphiphilic polymer represented by the formula below:

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and an interfacial polymerization layer formed on the polymeric porous layer and the interfacial polymerization layer comprising polyamide which is synthesized by polymerizing piperazine with 1,3,5-benzenetricarbonyl trichloride; wherein, n1, n2, n3, x, and y are integers greater than 0, the molecular weight of the amphiphilic polymer ranges from 90,000 to 200,000, and a weight ratio of the polysulfone to the amphiphilic polymer ranges from 2 to 20. The nanofiltration composite membrane can increase the removal rate of divalent ions and separate substances of specific molecular weights in solutions.

A process for preparing a hollow fiber includes the steps of providing a dope solution including polyamide imide (PAI), providing an aqueous bore solution including polyethylene imine (PEI), extruding the dope solution in an cross-sectional annular shape and ejecting the bore solution in the center of the annular shape, allowing the PAI and the PEI to react, thereby forming an internal surface layer including the cross-linked reaction product, and forming a polyamide Thin Film Composite (TFC) layer by interfacial reaction of aqueous di- or triamine compound and organic di- or triacylhalide compound on the internal surface layer including the cross-linked reaction product.