Provided by the present invention is a method for preparing a porous polymer semipermeable membrane, wherein a hydrophobic polynorbornene polymer and a hydrophilic small-molecule crosslinking agent containing a thiol functional group are mixed and dissolved in a solvent capable of dissolving both of them to obtain a coating solution; the coating solution is applied onto the surface of a biosensor electrode and dried such that the hydrophobic component and the hydrophilic component undergo phase separation; then, a membrane is formed and crosslinking is carried out, the unreacted hydrophilic small-molecule crosslinking agent is removed, and re-drying is carried out to obtain a porous polymer semipermeable membrane; also disclosed is a product. For the product obtained by the preparation method of the present invention, the hydrophobicity of the polymer enables good adhesion of the porous polymer semipermeable membrane to the surface of the biosensor, and the porous structure ensures the diffusion of biological substances to the surface of the biosensor, and regulates the diffusion rate of the biological substances in the semipermeable membrane without changing the thickness of the polymer membrane significantly.

The present invention is directed to surface-treated membranes comprising: (a) a porous substrate; and (b) a coating layer applied to the substrate. The coating layer is formed from a surface treatment composition comprising: (i) a first component comprising an organic solvent; and (ii) a second component comprising a fluorine-containing polymer and a solvent containing at least one C—F bond. The present invention is further drawn to a method of preparing a surface-treated filtration membrane, comprising: (a) contacting a porous substrate with a first component of a surface treatment composition, wherein the first component comprises an organic solvent; (b) subsequently contacting the porous substrate with a second component of the surface treatment composition, wherein the second component comprises a fluorine-containing polymer and a solvent containing at least one C—F bond; and (c) subjecting the porous substrate to a temperature of 25 to 90° C. for 1 to 180 minutes.

The present invention relates to a chemically modified anion exchange membrane and a method of preparing the same and, more particularly, an anion exchange membrane in which sulfonic acid groups in a perfluorinated sulfonic acid electrolyte membrane are substituted with anion conductive groups such as ammonium group, phosphonium group, imidazolium group, pyridinium group and sulfonium group, and a method of preparing an anion exchange membrane by chemically modifying sulfonic acid groups in a perfluorinated sulfonic acid electrolyte membrane.

A single piece-type bipolar film roll with a mesh cloth support and a manufacturing method therefor. The single piece-type bipolar film roll is supported by a high-strength ultra-high molecular weight polyethylene mesh cloth, one side of the single piece-type bipolar film roll is a cation exchange layer containing a benzenesulfonic acid group, the other side of the single piece-type bipolar roll is an anion exchange layer containing a benzyl dimethyl butyl ammonium quaternary amino group, and the middle is a water dissociation catalyst layer containing a benzyl methyl butyl amine tertiary amino group, and the three layers form the single piece-type bipolar film roll. By providing a wider protective film and a narrower spacing film, a dipping and absorbing film roll is polymerized to prepare a composite base film roll which is then subjected to continuous sulfonation to prepare a single-sided sulfonated composite positive film roll, and then the unreacted blank side is sequentially subjected to three-step chemical reactions such as complete chloromethylation, complete tertiary amination and incomplete methylation, so as to prepare a single piece-type bipolar film roll having a compact structure, a clear middle interface, a high mechanical strength and a stable quaternary amino group, and the product qualification rate is high; and the single piece-type bipolar film roll is suitable for a bipolar film electrodialysis engineering application of an organic material-containing system.

A rare earth coated membrane is beneficial to aid in the separation of contaminants, such as anions containing phosphorous, anions containing arsenic, PFAS, and mixtures thereof. Membranes with the rare earth coating or treatment can have larger pore sizes than would be expected to remove these contaminants. Disclosed herein are methods for treating or coating the membrane to provide the rare earth coated membrane. The coated membranes can be used to remove contaminants, such as anions containing phosphorous, anions containing arsenic, and PFAS, from liquid feeds, such as water or water-based feeds.

M(SiF.sub.6)(pyz).sub.3 (M=Cu, Zn, Co, or Ni) has a pore size between a size of H.sub.2 and a size of CO.sub.2, and thus exhibits prominent screening performance for H.sub.2/CO.sub.2. A strong interaction between Cu(SiF.sub.6)(bpy).sub.2 and a CO.sub.2 molecule can hinder the transport of the CO.sub.2 molecule. The above two MOFs both can achieve the H.sub.2/CO.sub.2 separation. By preparing a dense MSiF.sub.6/polymer layer, MSiF.sub.6 is uniformly dispersed in the polymer and is fixed, and subsequently, MSiF.sub.6 is converted into M(SiF.sub.6)(pyz).sub.3 or Cu(SiF.sub.6)(bpy).sub.2 by interacting with an organic ligand. Through vapor-induced in-situ conversion, MOF particles can be well dispersed without interface defects between the MOF particles and the polymer. Even at a doping amount of 80%, the mechanical flexibility and stability of the MMM can still be retained.

The present disclosure provides surface functionalized affinity membranes. The surface functionalized affinity membranes can provide increased binding capacity through improved coupling chemistries, ligand densities, spacer arm types, and spacer arm lengths. Methods of preparing the surface functionalized affinity membranes and methods of using the surface functionalized affinity membranes to isolate targets of interest, including nucleic acid molecules and proteins, from a sample are also provided.

An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, and etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer. A method of: depositing a hexaiodo-substituted macrocycle onto a substrate having a Ag(111) surface; coupling the macrocycle to form a nanoporous graphene sheet; layering the graphene sheet and substrate onto a nanoporous membrane with the graphene sheet in contact with the nanoporous membrane; and etching away the substrate.

The present invention relates to a polyamide reverse osmosis membrane including a porous support; a polyamide layer which is formed on at least one surface of the porous support; a fouling resistant layer which is formed on the polyamide layer; and a protective coating layer which is formed on the fouling resistant layer and linked by cross-linking with the fouling resistant layer, and more specifically to a polyamide reverse osmosis membrane having excellent durability and antifouling properties in which antifouling properties are improved, but there is no decrease in flow rate and salt removal rate, and there is little decrease in physical properties due to fouling and little change over time due to a preservation solution, and chlorine durability is also excellent.

The invention relates to porous polymeric cellulose prepared via cellulose crosslinking. The porous polymeric cellulose can be incorporated into membranes and/or hydrogels. In preferred embodiments, the membranes and/or hydrogels can provide high dynamic binding capacity at high flow rates. Membranes and/or hydrogels comprising the porous polymeric cellulose are particularly suitable for filtration, separation, and/or functionalization media.