A method for controlling fiber cross-alignment in a nanofiber membrane, comprising: providing a multiple segment collector in an electrospinning device including a first and second segment electrically isolated from an intermediate segment positioned between the first and second segment, collectively presenting a cylindrical structure, rotating the cylindrical structure around a longitudinal axis proximate to an electrically charged fiber emitter; electrically grounding or charging edge conductors circumferentially resident on the first and second segment, maintaining intermediate collector electrically neutral; dispensing electrospun fiber toward the collector, the fiber attaching to edge conductors and spanning the separation space between edge conductors; attracting electrospun fiber attached to the edge conductors to the surface of the cylindrical structure, forming a first fiber layer; increasing or decreasing rotation speed of the cylindrical structure to alter the angular cross-alignment relationship between aligned nanofibers in adjacent layers, the rotation speed being altered to achieve a target relational angle.

Novel electrospun nanofibers and nanofibrous membranes, methods of manufacturing the same, and methods of using the same are provided. The nanofibers include a cactus mucilage, such as mucilage from Opuntia ficus-indica. An organic polymer can be added to the cactus mucilage before electrospinning. The nanofibrous membranes can be used in water filtration.

The invention concerns a method for producing a superhydrophobic membrane or surface coating of a substrate from an aqueous phase comprising the following steps: a) Preparing an aqueous dispersion by dispersing particles of hydrophobic polymer(s) in an aqueous solution of protic polymer(s), wherein the protic polymer(s) and the hydrophobic polymer(s) are present in a weight ratio of protic polymer(s):hydrophobic polymer(s) in a range of 5:95 to 22:78, b) electrospinning the dispersion of step a) onto a carrier for producing the membrane or onto the surface for producing the surface coating thereby producing at least one fiber and a nonwoven fabric from the fiber, c) subjecting the nonwoven fabric to a sol-gel process, wherein a precursor/precursors of the sol-gel comprise(s) an alkoxysilane, and d) curing the nonwoven fabric obtained by step c) at a temperature in a range of 50 C. to 150 C.

Disclosed are a light-driven filtration antibacterial composite membrane and a preparation method and use thereof. The method for preparing the light-driven filtration antibacterial composite membrane includes: mixing dichloromethane and N,N-dimethylformamide to obtain a first solution; adding PCL particles to the first solution, and stirring until being uniform to obtain an electrospinning solution; adding a ZIF-8 powder to the electrospinning solution, and ultrasonically dispersing for at least 1 hour to obtain a PCL/ZIF-8 spinning solution; spraying the PCL/ZIF-8 spinning solution onto a PPCL@PDA/TAEG men-blown membrane to obtain the light-driven filtration antibacterial composite membrane.

The invention relates to a method for assembling a bipolar membrane, and bipolar membrane thereof. The method comprises the steps of electrospinning and centrifugal spinning and electrocentrifugal spinning a first cation exchange layer comprising a first water splitting catalyst and a first cation exchange polymer, electrospinning and centrifugal spinning and electrocentrifugal spinning a junction layer. Further, the method comprises electrospinning and centrifugal spinning and electrocentrifugal spinning a first anion exchange layer comprising a second water splitting catalyst and a first anion exchange polymer. A system comprising a bipolar membrane according to the invention is also disclosed.

Disclosed herein are polycationic microfibers comprising a high-aspect-ratio polymeric core, the polymeric core comprising a blend of a first core polymer and a second core polymer, and a polycationic polymer immobilized on the surface of the polymeric core. The polycationic microfibers are capable of sequestering or clearing nucleic acids, proteins, biomolecular complexes, exosomes, or microparticles from solutions and samples and may be formed into filters or integrated into filtration apparatuses. Also disclosed are methods for sequestering or clearing solutes from solutions and fluids, methods for the treatment of diseases or conditions, and methods for the prevention of diseases or conditions.

A fiber membrane prepared based on in-situ growth and an application thereof in toluene adsorption are provided. A method for preparing a fiber membrane based on in-situ growth includes the following steps: (1) adding 2-aminoterephthalic acid and polyacrylonitrile (PAN) powder into a solvent, and mixing uniformly to obtain a spinning solution; (2) performing electrospinning on the spinning solution, and drying to obtain a fiber membrane; (3) placing the fiber membrane in an alcohol solution, adding ethylenediamine, and performing thermal crosslinking; after the thermal crosslinking, cleaning and drying to obtain a crosslinked fiber membrane; and (4) placing the crosslinked fiber membrane in a solvent, adding zirconium oxychloride, 2-aminoterephthalic acid, and benzoic acid, and performing in-situ growth to obtain a fiber membrane prepared based on in-situ growth. The fiber membrane prepared based on in-situ growth of the present disclosure has a large toluene adsorption capacity, which may be recycled and reused.

Described herein is a multilayered article comprising a functionalized porous substrate. Such functionalized porous substrates can be used in the detection of analytes, wherein a reagent matrix comprising: (1) a plurality of first capture components, wherein the first capture component comprises a first analyte capture site and a porous substrate binding site; and (2) a plurality of a second capture component, wherein the second capture component comprises a second analyte capture site; wherein at least one of the first or second capture components comprises a detection medium; is contacted with an analyte and then disposed onto the functionalized porous substrate for analysis. In one embodiment, a novel monomer used to functionalize a substrate is described.

The present invention relates to a method for preparing a filter membrane, comprising the following steps: preparing a first solution by dissolving at least polyamide 6 and polyether block amide into formic acid, wherein the weight ratio of polyamide 6 to polyether block amide being limited by 5:1; preparing a second solution by adding acetic acid to the first solution, wherein the weight ratio of acetic acid to formic acid being limited by 3:1, and the weight ratio of polyamide 6 and polyether block amide in the second solution being limited by 15 wt %; and electrospinning the second solution, whereby fibers comprising polyamide 6 and polyether block amide being deposited over substrate selected from polyethylene terephthalate. The present invention also relates to a filter membrane prepared by the method.

A necklace-type nanofiber hybrid membrane is disclosed. ZIF-67 (Zeolite imidazolate framework-67), a type of metal-organic framework (MOF), is formed surrounding surface of the nanofibers to possess a necklace-type structure. The combination of ZIF-67 and nanofibers enables simultaneous removal of fine dust and sulfides while exhibiting excellent stability.