A fuel reformer module (8005) for initiating catalytic partial oxidation (CPOX) to reform a hydrocarbon fuel oxidant mixture (2025, 3025) to output a syngas reformate (2027) to solid oxide fuel cell stack (2080, 5040). A solid non-porous ceramic catalyzing body (3030) includes a plurality of catalyst coated fuel passages (3085). A thermally conductive element (9005, 10005, 11005, 13005), with a coefficient of thermal conductivity of 50 W/m° K or greater is thermally conductively coupled with the catalyzing body. A first thermal sensor (8030) is thermally conductively coupled with the thermally conductive element. A second thermal sensor is thermally conductively coupled with a surface of the fuel cell stack. A control method independently modulates an oxidant input flow rate, based on first thermal sensor signal values, a hydrocarbon fuel input flow rate, based on second thermal sensor signal values.

A process for the catalytic oxidation of ammonia, comprising: passing an ammonia-containing gas, in the presence of oxygen, over a catalyst contained in a reactor, obtaining a process gas containing nitrogen oxides, and cooling said process gas with a heat exchanger accommodated in the reactor, wherein a portion of said process gas, located in the shell side, bypasses the heat exchanger and forms a hot current which mixes with cooled gas downstream the heat exchanger, and the bypass is regulated on the basis of a target outlet temperature of the mixed process gas.

Fuel tank inerting systems are described. The systems include a fuel tank having an inerting system flow path connected to the fuel tank. A catalytic reactor is arranged along the inerting system flow path configured to receive a reactant mixture of first reactant and a second reactant to generate inert gas. A condenser heat exchanger is arranged between the catalytic reactor and the fuel tank to cool an output from the catalytic reactor. A first ejector is configured to receive the first reactant and the second reactant and output the reactant mixture through an outlet. A second ejector is configured to receive an inert gas and the second reactant to output a mixture of the second reactant and the inert gas.

Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.

Systems and methods are provided for using oxycombustion to provide heat within a reverse flow reactor environment. The oxygen for the oxycombustion can be provided by oxygen stored in an oxygen storage component in the reactor. By using an oxygen storage component to provide the oxygen for combustion during the regeneration step, heat can be added to a reverse flow reactor while reducing or minimizing addition of diluents and while avoiding the need for an air separation unit. As a result, a regeneration flue gas can be formed that is substantially composed of CO.sub.2 and/or H.sub.2O without requiring the additional cost of creating a substantially pure oxygen-containing gas flow.

A new plasma catalyst in the form of a ceramic-matrix nanocomposite is disclosed for application to the plasma-assisted combustion. The new functionality of the nanoceramic plasma catalyst is driven by the synergistic effect of plasma and solids. The plasma catalyst is based on combinations of valve metal oxides, polar transition-metal oxides, rare-earth oxides and phosphides, alkali metal oxides, silicon oxides and nitrides, etc. are disclosed. The advantage of combining a heterogeneous catalytic and plasma catalytic effect allows utility for large area applications and is scalable for large-scale industries.

Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.

A catalyst bed includes a structure defining a plurality of channels configured to receive flow of fluid to be chemically catalyzed. The plurality of channels are oriented at least partially non-parallel to an overall flow direction of the flow from inputs of the plurality of channels to outputs of the plurality of channels. A catalyst is exposed at an exterior of the structure.

Systems and methods are provided for performing hydrocarbon reforming within a reverse flow reactor environment (or another reactor environment with flows in opposing directions) while improving management of CO.sub.2 generated during operation of the reactor. The improved management of CO.sub.2 is achieved by making one or more changes to the operation of the reverse flow reactor. The changes can include using an air separation unit to provide an oxygen source with a reduced or minimized content of nitrogen and/or operating the reactor at elevated pressure during the regeneration stage. By operating the regeneration at elevated pressure, a regeneration flue gas can be generated that is enriched in CO.sub.2 at elevated pressure. The CO.sub.2-enriched stream can include primarily water as a contaminant, which can be removed by cooling while substantially maintaining the pressure of the stream. This can facilitate subsequent recovery and use of the CO.sub.2.

A micro-reactor for a reforming process has a cold side and a hot side opposite the cold side. Inlets are defined in the cold side, the inlets configured for receiving reagents. An outlet is defined in the cold side, the outlet configured for exiting reforming products. A reforming chamber is in the hot side, the reforming chamber having a catalyst, the reforming chamber configured for reforming the reagents into the reforming products, the reforming chamber including channels extending toward an end surface on the hot side of the reforming chamber, and a return plenum. A reagent path is from the inlets to the reforming chamber, the reagent path configured to feed the plurality of channels with reagents. A reforming product path is from the reforming chamber to the outlet, the reforming product path configured to receive products from the return plenum.