Control of humidity in chemical reactors, and associated systems and methods, are generally described. In certain embodiments, the humidity within gas transport conduits and chambers can be controlled to inhibit unwanted condensation within gas transport pathways. By inhibiting condensation within gas transport pathways, clogging of such pathways can be limited (or eliminated) such that transport of gas can be more easily and controllably achieved. In addition, strategies for purging condensed liquid from chemical reactor systems are also described.

Disclosed herein is a method for converting an epoxide to a first C3 product, a second C3 product, and/or a first C4 product within an integrated system. The method includes converting the epoxide to a beta lactone to produce an outlet stream comprising beta lactone. The method includes converting the beta lactone of the outlet stream to a first C3 product in the first C3 reactor to produce an outlet stream comprising the first C3 product; converting the beta lactone to a second C3 product in the second C3 reactor to produce an outlet stream comprising the second C3 product, and/or converting the beta lactone to a first C4 product in the first C4 reactor to produce an outlet stream comprising the first C4 product.

A method for monitoring the production of a material such as graphene in a liquid dispersion in real time, comprises supplying the liquid dispersion to a fluid gap defined between a first layer and an opposed second layer, wherein the first layer is light-transmissive and wherein the second layer has a diffusely reflective surface facing the first layer. The diffusely reflective surface is illuminated with light from a light source and light reflected from the diffusely reflective surface is detected at an associated photodetector. A light path from the light source to the photodetector comprises the light passing through the transmissive layer towards the diffusely reflective surface through the fluid gap, reflecting off the diffusely reflective surface and passing back through the fluid gap towards and onwards through the transmissive layer. The concentration of the material in the liquid dispersion can be determined from the detected reflected light. The fluid gap is typically an integral part of apparatus for producing the material, such as being formed between an inner rotor and an outer casing wall of a liquid exfoliation apparatus.

A method is provided for pretreating cellulosic or lignocellulosic biomass comprising de-esterifying the biomass with an alkali treatment to produce de-esterified biomass; and pretreating the de-esterified biomass with ammonia to produce de-esterified ammonia pretreated biomass. In various embodiments, the de-esterified ammonia pretreated biomass has an amide concentration ranging from about 0.04 to about 25 mg/g biomass. In other embodiments, the amide concentration is no more than 0.04 mg/g biomass. Various ammonia pretreatment processes may be used, including liquid or gaseous ammonia pretreatments, including, but not limited to, liquid ammonium hydroxide pretreatments, various AFEX pretreatments, with or without biomass densification, and various cellulosic conversion pretreatments including “COBRA” pretreatments. Products (e.g., animal feed) and systems are also disclosed.

This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO.sub.2). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO.sub.2.

Methods and systems for on-site, continuous generation of peracid chemistry, namely peroxycarboxylic acids and peroxycarboxylic acid forming compositions, are disclosed. In particular, an adjustable biocide formulator or generator system is designed for on-site generation of peroxycarboxylic acids and peroxycarboxylic acid forming compositions from sugar esters. Methods of using the in situ generated peroxycarboxylic acids and peroxycarboxylic acid forming compositions are also disclosed.

Methods and systems for temperature-controlled, on-site generation of peracids, namely peroxycarboxylic acids and peroxycarboxylic acid forming compositions are disclosed. In particular, methods for using an adjustable biocide formulator or generator system overcome the limitations of temperature on the kinetics of the peracid generation and/or peracid decomposition inside an adjustable biocide formulator or generator system. The methods include the controlling of the temperature of at least one raw starting material, namely water, to improve upon methods of on-site generation of peracids. The methods allow for the generation of user-selected chemistry without regard to the ambient temperatures of the raw starting materials and/or the biocide formulator or generator system.

A reactor system and a process for carrying out the ammonia cracking reaction of a feed gas comprising ammonia to hydrogen are provided, where the heat for the endothermic ammonia cracking reaction is provided by resistance heating.

Provided is a method for manufacturing a terephthalate-based composition, the method comprising: a step (S1) of flowing in a dialkyl terephthalate in which alkyl has 7 to 10 carbon atoms and a primary alcohol with a low boiling point having 4 or 5 carbon atoms into a reactor and performing transesterification of the dialkyl terephthalate and the primary alcohol with a low boiling point; and a step (S2) of extracting in a reduced pressure an unreacted material and a by-product from the reactor after finishing the transesterification, wherein the step S1 comprises a pressure-applying step in which the pressure of the reactor is 1.5 to 2.5 bar.

A processing system and method of producing a particulate material from a liquid mixture are provided. The processing system generally includes a system inlet connected to one or more gas lines to deliver one or more gases into the processing system, one or more power jet modules adapted to jet a liquid mixture into one or more streams of droplets and to force the one or more streams of droplets into the processing system, and a reaction chamber adapted to deliver the one or more streams of droplets in the presence of the one or more gases and process the one or more streams of droplets into the particulate material. The method includes delivering one or more gases into a processing system, jetting the liquid mixture into one or more first droplets streams using one or more power jet modules of the processing system and into the processing system, and reacting the one or more first droplets streams delivered from the processing chamber inside a reaction chamber of the processing system in the presence of the one or more gases into the particulate material at a first temperature.