Patent classifications
B01J19/02
Fluidized bed reactor and a process using same to produce high purity granular polysilicon
The present invention relates to a fluidized bed reactor, comprising a reaction tube, a distributor and a heating device, the reaction tube and the distributor at the bottom of the reaction tube composing a closed space, the distributor comprising a gas inlet and a product outlet, and the reaction tube comprising a tail gas outlet and a seed inlet at the top or upper part respectively, characterized in that the reaction tube comprises a reaction inner tube and a reaction outer tube, and the heating device is an induction heating device placed within a hollow cavity formed between the external wall of the reaction inner tube and the internal wall of the reaction outer tube, wherein the hollow cavity is filled with hydrogen, nitrogen or inert gas for protection, and is able to maintain a pressure of about 0.01 to about 5 MPa; and also to a process of producing high purity granular polysilicon using the reactor. The fluidized bed reactor according to the present invention uses induction heating to heat directly the silicon particles inside the reaction chamber, such that the temperature of the reaction tube is lower than that inside the reaction chamber, which accordingly avoids deposition on the tube wall and results in more uniform heating, and thus is useful for large diameter fluidized bed reactors with much increased output for a single reactor.
Fluidized bed reactor and a process using same to produce high purity granular polysilicon
The present invention relates to a fluidized bed reactor, comprising a reaction tube, a distributor and a heating device, the reaction tube and the distributor at the bottom of the reaction tube composing a closed space, the distributor comprising a gas inlet and a product outlet, and the reaction tube comprising a tail gas outlet and a seed inlet at the top or upper part respectively, characterized in that the reaction tube comprises a reaction inner tube and a reaction outer tube, and the heating device is an induction heating device placed within a hollow cavity formed between the external wall of the reaction inner tube and the internal wall of the reaction outer tube, wherein the hollow cavity is filled with hydrogen, nitrogen or inert gas for protection, and is able to maintain a pressure of about 0.01 to about 5 MPa; and also to a process of producing high purity granular polysilicon using the reactor. The fluidized bed reactor according to the present invention uses induction heating to heat directly the silicon particles inside the reaction chamber, such that the temperature of the reaction tube is lower than that inside the reaction chamber, which accordingly avoids deposition on the tube wall and results in more uniform heating, and thus is useful for large diameter fluidized bed reactors with much increased output for a single reactor.
Element for Anchoring an Anti-Erosion Coating to an Inner Wall of a Chamber of an FCC Unit
The invention relates to a metal element (12) for anchoring an anti-erosion coating that is intended to be fastened alone in an isolated manner to a metal wall or assembled with other identical anchoring elements. The anchoring element (12) has an edge (12a) for fastening to said metal wall and an anchoring body firmly attached to the fastening edge (12a) and having an upper edge (12b) that is away from the fastening edge and intended to be covered by a composite material of concrete type. A section of this upper edge (12b), which is not intended to be juxtaposed and assembled with an upper edge of an identical anchoring element, is provided with a delimiting tab (16) in order to delimit a height of composite material that must cover the upper edge (12b) of said anchoring element, said delimiting tab (16) having a delimiting edge (18) that is a predetermined distance away from a plane defined by the upper edge (12b) of the anchoring element.
Intermediate medium heat exchanging device for supercritical water oxidation system
An intermediate medium heat exchanging device for a supercritical water oxidation system includes a material main loop, an intermediate medium loop and a replenishment branch. A material pump, a preheater, a spray type desuperheater, a reactor and a regenerator are connected in sequence to form the material main loop; a buffer tank, a circulating pump, the regenerator, the preheater and a water cooler form the intermediate medium loop. A back pressure valve is located above the buffer tank. The replenishment branch includes a cooling water pump, an outlet of the cooling water pump is divided into two sub-branches, one sub-branch is connected with the spray type desuperheater, and another sub-branch is connected with the buffer tank. The intermediate medium heat exchanging device is reasonable in structural design, and is able to maximally reduce the investment cost and ensure the stable operation of the system.
SULFUR-INFUSED CARBON FOR SECONDARY BATTERY MATERIALS
In one aspect, a method of producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including providing a carbonaceous material; mixing elemental sulfur with the carbonaceous material; and heating the mixed sulfur and the carbonaceous material at a temperature from about 445° C. to about 1000° C. for a period of time and under a pressure greater than 1 atm to generate a sulfur vapor to infuse the carbonaceous material to result in a sulfur-infused carbonaceous material. In another aspect, a reactor for producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including a reactor body capable of withstanding a pressure from about 1 atm to about 150 atm; and an inner sulfur-resistant layer at the inner surface of the reactor, wherein the inner layer is inert to sulfur vapor at a temperature from about 450° C. to about 1000° C.
PROCESS FOR MAKING A LITHIATED TRANSITION METAL OXIDE
Process for manufacturing a lithiated transition metal oxide, said process comprising the steps of (a) mixing at least one lithium salt and a precursor selected from transition metal oxides, transition metal oxyhydroxides, transition metal hydroxides, and transition metal carbonates, (b) pre-calcining the mixture obtained in step (a) at a temperature in the range of from 300 to 700° C., and (c) calcining the pre-calcined mixture according to step (b) in a multi-stage fluidized bed reactor at a temperature in the range of from 550° C. to 950° C., wherein the temperatures in step (b) and (c) are selected in a way that step (c) is being performed at a temperature higher than that of step (b).
PROCESS FOR MAKING A LITHIATED TRANSITION METAL OXIDE
Process for manufacturing a lithiated transition metal oxide, said process comprising the steps of (a) mixing at least one lithium salt and a precursor selected from transition metal oxides, transition metal oxyhydroxides, transition metal hydroxides, and transition metal carbonates, (b) pre-calcining the mixture obtained in step (a) at a temperature in the range of from 300 to 700° C., and (c) calcining the pre-calcined mixture according to step (b) in a multi-stage fluidized bed reactor at a temperature in the range of from 550° C. to 950° C., wherein the temperatures in step (b) and (c) are selected in a way that step (c) is being performed at a temperature higher than that of step (b).
Method for producing 2-chloro-3,3,3-trifluoropropene and facility for implementing same
The present invention relates to a process for producing 2-chloro-3,3,3-trifluoropropene, comprising the steps: i) providing a stream A comprising at least one chlorinated compound selected from the group consisting of 2,3-dichloro-1,1,1-trifluoropropane, 1,1,1,2,3-pentachloropropane, 1,1,2,3-tetrachloropropene and 2,3,3,3-tetrachloropropene; and ii) in an adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing said stream A into contact, in the presence or absence of a catalyst, with HF in order to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene, characterized in that the temperature at the inlet of the fixed bed of said adiabatic reactor is between 300° C. and 400° C. and the longitudinal temperature difference between the inlet of the fixed bed and the outlet of the fixed bed of said reactor is less than 20° C.
Method for producing 2-chloro-3,3,3-trifluoropropene and facility for implementing same
The present invention relates to a process for producing 2-chloro-3,3,3-trifluoropropene, comprising the steps: i) providing a stream A comprising at least one chlorinated compound selected from the group consisting of 2,3-dichloro-1,1,1-trifluoropropane, 1,1,1,2,3-pentachloropropane, 1,1,2,3-tetrachloropropene and 2,3,3,3-tetrachloropropene; and ii) in an adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing said stream A into contact, in the presence or absence of a catalyst, with HF in order to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene, characterized in that the temperature at the inlet of the fixed bed of said adiabatic reactor is between 300° C. and 400° C. and the longitudinal temperature difference between the inlet of the fixed bed and the outlet of the fixed bed of said reactor is less than 20° C.
Processes and apparatuses for toluene and benzene methylation in an aromatics complex
This present disclosure relates to processes and apparatuses for toluene and benzene methylation in an aromatics complex for producing paraxylene. More specifically, the present disclosure relates to processes and apparatuses for toluene and benzene methylation within an aromatics complex for producing paraxylene wherein an embodiment uses a reactor having a refractory comprising a low iron content refractory.