Provided are methods for storing a gas. An example method comprises providing a vessel containing a manifold system and an adsorbent, the manifold system comprising: a gas tubing, a filter disposed over openings in the gas tubing, a pressure relief valve, and an inlet coupled to the gas tubing and the vessel. The method further comprises introducing the gas into the manifold system via the inlet; circulating the gas in the gas tubing; flowing the gas through the openings in the gas tubing; and adsorbing the gas onto the adsorbent.

Disclosed are daucus-based oxygen scavenging compositions and materials, particularly of the carrot species, and their methods of use in containers and packaging of oxygen sensitive products. Further disclosed are daucus-based oxygen scavenging materials used in combination with tea-based oxygen scavenging compositions. Such compositions, materials and containers are of use for preserving the shelf-life of a myriad of products such as foods, pharmaceuticals, cosmetics, tobacco and cannabis.

A storage system for reversibly storing and releasing a gas such as hydrogen includes storage elements each having a storage volume with a storage material such as a metal-organic framework (MOF) for reversibly adsorbing or physiosorbing the gas, a gastight housing surrounding the storage volume and having a gas inlet/outlet which is in fluid-conducting communication with the storage volume, and at least one non-fluid activating element or activating layer configured to, when in an activation state, release the gas stored in the MOF and/or increases the rate of release relative to an unactivated state. The activating element or layer may surround and/or penetrate the storage material. The activating element may be controlled by an associated control to enter the activation state.

Embodiments describe a method of depositing an MOF, including depositing a metal solution onto a substrate, spinning the substrate sufficient to spread the metal solution, depositing an organic ligand solution onto the substrate and spinning the substrate sufficient to spread the organic ligand solution and form a MOF layer.

A method of forming one or more composite structures is provided wherein one or more carbon structures is formed from a carbon source via a hydrothermal process. Said carbon source is a biomass material including glucose and glucosamine hydrochloride. In particular, the method further comprises introducing a seeding additive of potassium or phosphate salt, preferably monopotassium phosphate to the carbon source. The method includes introducing iron onto the carbon structures to form the one or more composite structures including carbon and iron.

A method of forming one or more composite structures is provided wherein one or more carbon structures is formed from a carbon source via a hydrothermal process. Said carbon source is a biomass material including glucose and glucosamine hydrochloride. In particular, the method further comprises introducing a seeding additive of potassium or phosphate salt, preferably monopotassium phosphate to the carbon source. The method includes introducing iron onto the carbon structures to form the one or more composite structures including carbon and iron.

Provided is an process for the automated synthesis of at least one chemical compound including providing at least one substrate in at least one solvent in the at least one reaction container; automatically passing the at least one substrate through at least one first compartment of the at least one cartridge once or several times and collecting a formed substrate-reagent intermediate product in the at least one reaction container prior to passing the substrate-reagent intermediate product into a subsequent compartment; automatically passing the substrate-reagent intermediate product through at least one second compartment once or several times and collecting a formed reaction product prior to passing the reaction product into a subsequent compartment; automatically passing the reaction product through at least one third compartment for purifying the product once or several times and collecting a purified product in the at least one reaction container.

Provided is an process for the automated synthesis of at least one chemical compound including providing at least one substrate in at least one solvent in the at least one reaction container; automatically passing the at least one substrate through at least one first compartment of the at least one cartridge once or several times and collecting a formed substrate-reagent intermediate product in the at least one reaction container prior to passing the substrate-reagent intermediate product into a subsequent compartment; automatically passing the substrate-reagent intermediate product through at least one second compartment once or several times and collecting a formed reaction product prior to passing the reaction product into a subsequent compartment; automatically passing the reaction product through at least one third compartment for purifying the product once or several times and collecting a purified product in the at least one reaction container.

A preparation method for covalent organic framework 5 (COF-5) includes: adding 2,3,6,7,10,11-hexahydroxytriphenylene and 1,4-phenylenebisboronic acid to a mixed solution of 1,3,5-trimethylbenzene and 1,4-dioxane to form a mixture in the anhydrous and oxygen-free environment; and the addition ratio of 2,3,6,7,10,11-hexahydroxytriphenylene:1,4-phenylenebisboronic acid:1,3,5-trimethylbenzene:1,4-dioxane is 0.02-0.8 mmol:0.08-1.4 mmol:10-15 mL:10-15 mL; sealing the mixture in an airtight container; and obtaining a uniform dispersion solution after shaking the container for wholly mixing the components; heating the dispersion solution to a temperature ranging from 80-100° C.; reacting for a period of time ranging from 72-120 h; and obtaining a precipitate after the reaction; and washing the precipitate, drying the precipitate in vacuum, and heating the precipitate at a temperature ranging from 200-300° C. for a period of time ranging from 1-3 h with a protective atmosphere to obtain COF-5 crystal.

The present disclosure provides methods for controlling swelling of a clay when in contact with an aqueous medium. The methods may include contacting clay with a content of an ionic liquid sufficient to modify one or more transport properties of water through the clay. In particular, in some embodiments, the present disclosure provides clay-based animal litter compositions having controlled flow and clump shape, and a related method. The animal litter can include a clay-based liquid absorbing material and at least one ionic liquid.