The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The preparation of the inorganic/organic hybrid materials of the invention wherein a surrounding material is condensed on a superficially porous hybrid core material will allow for families of different hybrid packing materials to be prepared from a single core hybrid material. Differences in hydrophobicity, ion-exchange capacity, chemical stability, surface charge or silanol activity of the surrounding material may be used for unique chromatographic separations of small molecules, carbohydrates, antibodies, whole proteins, peptides, and/or DNA.

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The preparation of the inorganic/organic hybrid materials of the invention wherein a surrounding material is condensed on a superficially porous hybrid core material will allow for families of different hybrid packing materials to be prepared from a single core hybrid material. Differences in hydrophobicity, ion-exchange capacity, chemical stability, surface charge or silanol activity of the surrounding material may be used for unique chromatographic separations of small molecules, carbohydrates, antibodies, whole proteins, peptides, and/or DNA.

The present invention relates to an activated carbon sheet, and particularly relates to an activated carbon sheet for air purification comprising activated carbon, which is suitable for removing volatile organic compounds in the passenger compartment of an automobile or the like. An object of the present invention is to provide a sheet that is excellent in toluene adsorption capacity and flame retardancy. An activated carbon sheet for air purification comprising an activated carbon fiber, granular or powdered activated carbon, and a fibrillated fiber, wherein a mass (g/m.sup.2) of the activated carbon fiber is 5 g/m.sup.2 or more, a pressure loss as measured by a method set forth below is 150 Pa or less, and a burn distance as measured by the FMVSS 302 burning test is 51 mm or less: <pressure loss test method> the method is conducted in accordance with JIS B 9927:1999 “Appendix (Standard) Cleanroom—Air filters—Test methods”, 3.2 “Pressure Loss Test” as follows: a piece of the activated carbon sheet cut in the form of a circle with a diameter of 110 mm is used as a measurement sample; air is sucked though the measurement sample at a linear velocity of 0.1 m/s, and a difference in static pressure between an upstream side and a downstream side of the activated carbon sheet is measured with a differential pressure gauge; and figures up to the one's place of the measured value are used as significant figures.

This invention relates to a method of using MOF adsorbents to remove elemental impurities from feed streams comprising active pharmaceutical ingredients (API). The process involves contacting the feed stream comprising API and elemental impurities with the MOF at purification conditions to obtain a purified stream with provides an API which has a concentration of the elemental impurity below its permitted daily exposure. The process can be carried in a batch mode where the MOF and feed stream are admixed in a vessel for a given amount of time or continuously by flowing the feed stream through a column or adsorbent bed containing the MOF adsorbent.

Provided are methods of removing perchlorate from water. The methods include contacting water suspected of containing perchlorate with a cationic material. The cationic material includes one or more cationic metal atoms connected by an atom or molecule into an extended structure, and a charge balancing anion. The contacting removes perchlorate (e.g., selectively), if present, from the water. Water treatment vessels, systems and facilities that find use in practicing the methods of the present disclosure are also provided.

Provided are MOF-fabric composites having a crystalline MOF adhered directly to fibers of the fabric and methods of making MOF-fabric composites. A solution is adsorbed onto a fabric. The solution can include a metal salt, a linker, and a solvent. The solution is adsorbed onto the fabric and the fabric suspended over a heated vapor. The vapor releases onto the fabric, causing the metal salt, the linker, and the solvent to diffuse out of the polymer fibers. The linker links metal from the metal salts to form crystals attached to the fabric, and the vapor aids crystallization.

The present disclosure relates to a porous liquid or a porous liquid enzyme system that includes a high surface area solid and a liquid film substantially covering the high surface area solid. The porous liquid or porous liquid enzyme may be contacted with a fluid that is immiscible with the liquid film such that a liquid-fluid interface is formed. The liquid film may facilitate mass transfer of a substance or substrate across the liquid-fluid interface. The present disclosure also provides methods of performing liquid-based extractions and enzymatic reactions utilizing the porous liquid or porous liquid enzyme of the present disclosure. The present disclosure also provides methods for selecting the components of the porous liquid or a porous liquid enzyme system and methods of self-replenishing the used liquid coating.

The present disclosure relates to a porous liquid or a porous liquid enzyme system that includes a high surface area solid and a liquid film substantially covering the high surface area solid. The porous liquid or porous liquid enzyme may be contacted with a fluid that is immiscible with the liquid film such that a liquid-fluid interface is formed. The liquid film may facilitate mass transfer of a substance or substrate across the liquid-fluid interface. The present disclosure also provides methods of performing liquid-based extractions and enzymatic reactions utilizing the porous liquid or porous liquid enzyme of the present disclosure. The present disclosure also provides methods for selecting the components of the porous liquid or a porous liquid enzyme system and methods of self-replenishing the used liquid coating.

An air intake system for an internal combustion engine is described, and includes a vapor capture element disposed in an interior portion of an air intake system. The vapor capture element includes a flexible Metal Organic Framework (MOF) material, wherein the flexible MOF material is reversibly controllable to a first state and to a second state in response to a control stimulus. The flexible MOF material is configured to adsorb hydrocarbon vapor when controlled to the first state and configured to desorb the hydrocarbon vapor when controlled to the second state.

A humidity controlling material includes: a first particle; and a second particle. The first particle includes: a first humidity controlling liquid containing a hygroscopic substance; and a first holding portion holding the first humidity controlling liquid. The second particle includes: a second humidity controlling liquid containing the hygroscopic substance; and a second holding portion holding the second humidity controlling liquid. The first holding portion and the second holding portion are formed of a polymeric material. The first humidity controlling liquid includes a first indicator a color of which changes according to an amount of moisture contained in the first humidity controlling liquid. The second humidity controlling liquid includes a second indicator a color of which changes, in a transition range different from a transition range of the first indicator, according to an amount of moisture contained in the second humidity controlling liquid.