A stacked sorbent assembly for use in sorbent dialysis. The stacked sorbent assembly contains two or more interchangeable sorbent pouches that allow for fluid to freely pass into and through the sorbent materials, while keeping the sorbent materials inside the sorbent pouches. Any of the pouches in the sorbent cartridge can be reused and/or recharged.

Use of an alkyltrichlorosilane of the following formula I: R—SiCl.sub.3, wherein: R represents an alkyl group, Si represents a silicon atom and Cl represents a chlorine atom, and/or of a silsesquioxane of the following formula II: [RSiO.sub.3/2].sub.n, wherein: R represents an alkyl group, Si represents a silicon atom, O represents an oxygen atom and n represents an integer, for the removal of microplastic particles from water and/or for the treatment of water. Further, a method for the removal of microplastic particles from water and/or for the purification of water is provided, as well as an inclusion and/or intercalation compound, a kit for the removal of microplastic particles from water and/or for the purification of water as well as a water treatment system.

Use of an alkyltrichlorosilane of the following formula I: R—SiCl.sub.3, wherein: R represents an alkyl group, Si represents a silicon atom and Cl represents a chlorine atom, and/or of a silsesquioxane of the following formula II: [RSiO.sub.3/2].sub.n, wherein: R represents an alkyl group, Si represents a silicon atom, O represents an oxygen atom and n represents an integer, for the removal of microplastic particles from water and/or for the treatment of water. Further, a method for the removal of microplastic particles from water and/or for the purification of water is provided, as well as an inclusion and/or intercalation compound, a kit for the removal of microplastic particles from water and/or for the purification of water as well as a water treatment system.

Compositions and methods for adsorption of a species (e.g., ammonia, water, a halogen) comprising metal organic frameworks (MOFs) are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core.

The present invention provides compositions for removal of arsenic or heavy metal contaminants in the process of fluid filtration comprising an organically modified inorganic adsorbent, wherein the composition is produced by reaction with 1,3-dipolar compounds prior to filtration. Also provided are systems for fluid filtration, comprising compositions as provided herein, in a column or column-like format, wherein a fluid is provided to the column such that the fluid flows through the organically modified inorganic adsorbent, and wherein contaminants present in the fluid are bound to the composition. Additionally provided are methods for fluid filtration, comprising contacting a fluid sample with the composition of claim 1 and collecting the filtered fluid sample after filtration.

The present invention provides compositions for removal of arsenic or heavy metal contaminants in the process of fluid filtration comprising an organically modified inorganic adsorbent, wherein the composition is produced by reaction with 1,3-dipolar compounds prior to filtration. Also provided are systems for fluid filtration, comprising compositions as provided herein, in a column or column-like format, wherein a fluid is provided to the column such that the fluid flows through the organically modified inorganic adsorbent, and wherein contaminants present in the fluid are bound to the composition. Additionally provided are methods for fluid filtration, comprising contacting a fluid sample with the composition of claim 1 and collecting the filtered fluid sample after filtration.

Method and systems are disclosed for the removal of metal contaminants from aqueous mediums. In an example, a chamber contains activated sorptive media and a primary ligand and optionally, a secondary ligand that has been loaded onto the activated sorptive media using hydraulic loading. A pre-treatment of the sorptive media, a specific volume of the activated sorptive media within the chamber, specific pH ranges of aqueous mediums, and hydraulic loading of the primary ligand and optionally, a secondary ligand, known as dynamic fluidized loading. Pore pressures of the seeding solution within the media are at least sufficient to overcome the gravitational forces acting on the media within the column. The methods and systems provide a highly uniform and predictable loading of the primary ligand and optionally, the secondary ligand, onto the activated sorptive media throughout the sorptive media for effective sorption and increased capacity for metal removal from aqueous mediums.

Method and systems are disclosed for the removal of metal contaminants from aqueous mediums. In an example, a chamber contains activated sorptive media and a primary ligand and optionally, a secondary ligand that has been loaded onto the activated sorptive media using hydraulic loading. A pre-treatment of the sorptive media, a specific volume of the activated sorptive media within the chamber, specific pH ranges of aqueous mediums, and hydraulic loading of the primary ligand and optionally, a secondary ligand, known as dynamic fluidized loading. Pore pressures of the seeding solution within the media are at least sufficient to overcome the gravitational forces acting on the media within the column. The methods and systems provide a highly uniform and predictable loading of the primary ligand and optionally, the secondary ligand, onto the activated sorptive media throughout the sorptive media for effective sorption and increased capacity for metal removal from aqueous mediums.

A metal-organic framework (MOF) and uses thereof are provided herein, including an MOF comprising a repeat unit of the formula [Zn.sub.2(H.sub.2O)L.0.5H.sub.2O].sub.n, wherein L is a ligand of the formula:

##STR00001##

The MOFs provided herein may be used in the separation of two or more gaseous molecules from each other. In some embodiments, the gaseous molecules are carbon dioxide and acetylene.

Provided is a method for manufacturing a porous body by which a porous body having a plurality of layers different from each other in pore diameter can be manufactured more easily than before. The method includes heating a raw material solution including a metal ion and an organic ligand to synthesize an interpenetrated metal-organic framework layer; and after synthesizing the interpenetrated metal-organic framework layer, synthesizing a non-interpenetrated metal-organic framework layer under conditions in which concentrations of the metal ion and the organic ligand in the raw material solution and/or a heat temperature are lower than that in synthesizing the interpenetrated metal-organic framework, to obtain a porous body including the interpenetrated metal-organic framework layer and the non-interpenetrated metal-organic framework layer stacked together.