Adsorbent materials are disclosed, along with filter elements containing the adsorbent materials methods of using adsorbents to remove siloxane contaminants from a gas stream. The method includes providing an adsorbent material that has been washed with an acid and passing a gas through the adsorbent material so as to reduce siloxane levels in the gas. A filter element for reducing siloxane levels in a gas includes a first adsorbent material, the first adsorbent material comprising an acid-washed adsorbent; and a second adsorbent material, the second adsorbent material comprising an acid-impregnated adsorbent.

The present invention is based on the use of surface adsorption to capture CO.sub.2 molecules from air, without requiring the need for bulk absorption within the bulk of the sorbent. Since surface adsorption is a much faster process than bulk absorption, the present invention offers a greatly increased CO.sub.2 capture rate, as well as a greatly improved energy efficiency, over conventional systems. The invention involves the use of a molecular monolayer of CO.sub.2 sorbent, a process and a system for capturing CO.sub.2 from air employing such a molecular monolayer of CO.sub.2 sorbent.

The present invention is based on the use of surface adsorption to capture CO.sub.2 molecules from air, without requiring the need for bulk absorption within the bulk of the sorbent. Since surface adsorption is a much faster process than bulk absorption, the present invention offers a greatly increased CO.sub.2 capture rate, as well as a greatly improved energy efficiency, over conventional systems. The invention involves the use of a molecular monolayer of CO.sub.2 sorbent, a process and a system for capturing CO.sub.2 from air employing such a molecular monolayer of CO.sub.2 sorbent.

Described are storage and dispensing vessels and related systems and methods, for dispensing reagent gas from a vessel in which the reagent gas is held in sorptive relationship to a solid adsorbent medium, the reagent gas being contained at super-atmospheric pressure and the solid adsorbent medium comprising a metal-organic framework.

An apparatus for collecting a gaseous pollutant from air within a poultry or other concentrated animal feeding enclosure may comprise multiple vertical panel-beds each containing a solid sorbent; a fan to pass the air within the poultry enclosure through the multiple vertical panel-beds and over the solid sorbent; an outlet gate configured to release the solid sorbent from the multiple vertical panel-beds after the fan passes the air over the solid sorbent; a regeneration vessel configured to regenerate the released solid sorbent by recovering the gaseous pollutant from the released solid sorbent; and a conveyor configured to return the regenerated solid sorbent to the multiple vertical panel-beds.

A compound represented by Formula (1): each of L.sup.1 and L.sup.2 independently represents an alkyl group having from 1 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, NH.sub.2, NHR.sup.3, NR.sup.3R.sup.4, an ester group, a carboxy group, an amide group, a cyano group, a nitro group, a halogen atom, an acyl group, CF.sub.3, O(CH.sub.2).sub.1OCH.sub.3, a carbamate group, or an aryl group. 1 represents 1 or 2. Each of R.sup.1 and R.sup.2 independently represents a divalent hydrocarbon group having from 1 to 10 carbon atoms, at least one hydrogen atom of the divalent hydrocarbon group is optionally substituted with an alkyl group, an aryl group, an ester group, a carboxy group, an amide group, a cyano group, a nitro group, a halogen atom, an acyl group, CF.sub.3, O(CH.sub.2).sub.1OCH.sub.3, a carbamate group, or an alkoxy group, each of R.sup.3 and R.sup.4 independently represents an alkyl group, an aryl group, an acyl group, an ester group, an alkylsulfonyl group, or an arylsulfonyl group, each of R.sup.5 and R.sup.6 independently represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms, or an aryl group, and n+m≥1.

A process for making modified diethylenetriaminepentaacetic acid (DTPA)-associated media for use in solid-liquid extraction of rare earth elements is disclosed. The process includes functionalizing DTPA with hydrophobic groups to form modified DTPA; dissolving the modified DTPA into a methanol solution; loading the modified DTPA solution to a solid support; rotating the modified DTPA-loaded solid support to allow for association; and removing the methanol to obtain the modified-DTPA-associated media.

A process for making modified diethylenetriaminepentaacetic acid (DTPA)-associated media for use in solid-liquid extraction of rare earth elements is disclosed. The process includes functionalizing DTPA with hydrophobic groups to form modified DTPA; dissolving the modified DTPA into a methanol solution; loading the modified DTPA solution to a solid support; rotating the modified DTPA-loaded solid support to allow for association; and removing the methanol to obtain the modified-DTPA-associated media.

A particulate material for removing an acid gas and/or mercury contaminant from a hydrocarbon gas is disclosed. The particulate material comprises a superabsorbent hydrogel comprising a cross-linked hydrophilic polymer network having from 0.1 mol % to 50 mol % cross-linking agent. The superabsorbent hydrogel has one or more compounds capable of binding the acid gas and/or mercury contaminant incorporated into the hydrophilic polymer network by absorbing said one or more compounds as a liquid phase or an aqueous solution. Methods for preparing the particulate material and using the particulate material to remove one or more acid gas and/or mercury contaminants from a hydrocarbon gas, dehydrating the hydrocarbon gas, and mitigating corrosion in gas flowlines are also disclosed.

A particulate material for removing an acid gas and/or mercury contaminant from a hydrocarbon gas is disclosed. The particulate material comprises a superabsorbent hydrogel comprising a cross-linked hydrophilic polymer network having from 0.1 mol % to 50 mol % cross-linking agent. The superabsorbent hydrogel has one or more compounds capable of binding the acid gas and/or mercury contaminant incorporated into the hydrophilic polymer network by absorbing said one or more compounds as a liquid phase or an aqueous solution. Methods for preparing the particulate material and using the particulate material to remove one or more acid gas and/or mercury contaminants from a hydrocarbon gas, dehydrating the hydrocarbon gas, and mitigating corrosion in gas flowlines are also disclosed.