The present disclosure is directed to metal organic framework materials and uses for such metal organic framework materials. According to one embodiment, a metal organic framework material may include zinc ions, one or more triazoles, and one or more imidazoles. At least a portion of the zinc ions may be coordinated by the triazoles and the imidazoles such that at least a portion of the metal organic framework material forms a crystalline structure belonging to a monoclinic crystal system.

A filter-drier unit for a refrigerant includes an exterior housing formed of a hard material, and a desiccant material supported within the exterior housing and being formed of a metal-organic framework material having inorganic metal ions and bridging ligands that link the metal ions. The metal-organic framework has a three-dimensional permanently porous structure that has at least one chemically tunable characteristic, such as pore size, pore volume, and surface area.

It is provided that an electret having excellent filtering performance and a filter using the electret even in a case where polyolefin resin and magnesium element are contained. An electret comprising a polyolefin resin and a nitrogen-containing compound, wherein 0.1 to 5 parts by mass of the nitrogen-containing compound is contained to 100 parts by mass of the polyolefin resin, a proportion of a magnesium element contained in the electret is 5 to 100 ppm, and a QF value represented by the following formula is not less than 1.00 mmAq.sup.−1 when particles having particle diameters of 0.3 to 0.5 μm are to be collected.

QF [mmAq.sup.−1]=— [1n (particle penetration (%)/100)]/[ventilation resistance (mmAq)]

This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO.sub.2). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO.sub.2.

Embodiments of the present disclosure provide for metal-organic materials (MOMs), systems that exhibit permanent porosity and using hydrophobic MOMs to separate components in a gas, methods of separating CO.sub.2 from a gas, and the like.

Provided herein are electret-MOF filter embedded with particles derived from metal-organic frameworks (MOF) and their methods of manufacturing. The methods of manufacturing the electret-MOF filter can include suspending MOF particles in a solvent to form a MOF particle mixture, contacting a charged polymeric fibrous web with the MOF particle mixture, and coating the charged polymeric fibrous web with the MOF particles by flowing the MOF particle mixture through an inverse side of the polymeric fibrous web. The disclosed coating method can deposit MOF particles uniformly, without formation of films at interstitial spaces between fibers. The electret-MOF filter can simultaneously remove fine particulate matters (PMs) and hazardous gaseous pollutants (including volatile organic compounds (VOCs)) with high particle holding and gas adsorption capacities, and with very low air resistance.

The present invention provides for the use of a metal-organic framework (MOF) in removing particular chemical species or compounds, in particular oxy-anions of iodate, from a liquid or liquid stream. In some embodiments, the MOF is a Zr-based MOF, such as NU-1000 or MOF-808. The Zr-based MOF, including NU-1000 or MOF-808 can be used to remove these oxy-anions from various liquid streams or liquids in industrial processes such as a nuclear and fossil fuel power plants.

Provided are methods of removing perchlorate from water. The methods include contacting water suspected of containing perchlorate with a cationic material. The cationic material includes one or more cationic metal atoms connected by an atom or molecule into an extended structure, and a charge balancing anion. The contacting removes perchlorate (e.g., selectively), if present, from the water. Water treatment vessels, systems and facilities that find use in practicing the methods of the present disclosure are also provided.

The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.

The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.