A zirconium metal-organic framework, which is a coordination product formed between zirconium ion clusters and a linker that links together adjacent zirconium ion clusters, wherein the linker is of formula (I)

##STR00001##

wherein R.sup.1 is hydrogen or an optionally substituted alkyl, and R.sup.2 to R.sup.4 are independently hydrogen, an optionally substituted alkyl, an optionally substituted aryl, or an optionally substituted arylalkyl. A method of capturing CO.sub.2 from a gas mixture with the zirconium metal-organic framework.

A filter composition effective in reacting with airborne or gaseous organic impurities, such as formaldehyde. The filter composition is formed from a filter substrate, such as for example, a fibrous web or extruded carbon block, treated with tris-(hydroxymethyl) aminomethane. The unexpected result of this combination is a longer lasting filter capable of adsorbing organic airborne impurities for a much longer period of time than an untreated filter media of the same type. The removal of formaldehyde is presented as an illustrious example.

A filter composition effective in reacting with airborne or gaseous organic impurities, such as formaldehyde. The filter composition is formed from a filter substrate, such as for example, a fibrous web or extruded carbon block, treated with tris-(hydroxymethyl) aminomethane. The unexpected result of this combination is a longer lasting filter capable of adsorbing organic airborne impurities for a much longer period of time than an untreated filter media of the same type. The removal of formaldehyde is presented as an illustrious example.

Provided is a carbon dioxide absorbent including an ionic liquid including an imidazole-based anion and an aliphatic alcohol. Since an alcohol solvent included in the carbon dioxide absorbent according to one embodiment has low toxicity and a very high boiling point, the carbon dioxide absorbent has no problem of release into the atmosphere and consequent environmental pollution, and is chemically stable to significantly lower the possibility of release of decomposition products into the atmosphere. In addition, the carbon dioxide absorbent is also effective, since it may absorb carbon dioxide with a higher equivalent than an absorbent input equivalent, and has low regeneration energy so that carbon dioxide is easily desorbed.

Provided is a carbon dioxide absorbent including an ionic liquid including an imidazole-based anion and an aliphatic alcohol. Since an alcohol solvent included in the carbon dioxide absorbent according to one embodiment has low toxicity and a very high boiling point, the carbon dioxide absorbent has no problem of release into the atmosphere and consequent environmental pollution, and is chemically stable to significantly lower the possibility of release of decomposition products into the atmosphere. In addition, the carbon dioxide absorbent is also effective, since it may absorb carbon dioxide with a higher equivalent than an absorbent input equivalent, and has low regeneration energy so that carbon dioxide is easily desorbed.

A m-xylene adsorbent contains 94 to 99.9 wt % of a Y molecular sieve and 0.1 to 6 wt % of a matrix. The Y molecular sieve consists of a non-crystal-transformed Y molecular sieve and a Y molecular sieve produced by a crystal transformation. The non-crystal-transformed Y molecular sieve is a mesoporous nano Y molecular sieve, which has a crystalline grain size of 20 to 450 nanometers, contains two types of mesoporous pores, and respectively has most probable pore diameters of 5 to 20 nanometers and 25 to 50 nanometers. The adsorbent is used for adsorptive separation of m-xylene from mixed C8 aromatic hydrocarbons.

A m-xylene adsorbent contains 94 to 99.9 wt % of a Y molecular sieve and 0.1 to 6 wt % of a matrix. The Y molecular sieve consists of a non-crystal-transformed Y molecular sieve and a Y molecular sieve produced by a crystal transformation. The non-crystal-transformed Y molecular sieve is a mesoporous nano Y molecular sieve, which has a crystalline grain size of 20 to 450 nanometers, contains two types of mesoporous pores, and respectively has most probable pore diameters of 5 to 20 nanometers and 25 to 50 nanometers. The adsorbent is used for adsorptive separation of m-xylene from mixed C8 aromatic hydrocarbons.

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.