Primary, secondary (1,2) alkylethylenediamine- and alkylpropylenediamine-appended variants of metal-organic framework are provided for CO.sub.2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption/desorption profiles are overcome by minimizing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg.sub.2(dotpdc) (dotpdc.sup.4=4,4-dioxido-[1,1:4,1-terphenyl]-3,3-dicarboxylate), yields diamine-appended adsorbents displaying a single CO.sub.2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg.sub.2(pc-dobpdc) (pc-dobpdc.sup.4=3,3-dioxidobiphenyl-4,4-dicarboxylate, pc=para-carboxylate) also leads to a single CO.sub.2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO.sub.2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg.sub.2(dotpdc) and Mg.sub.2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

The invention relates to a porous carrier system for reducing the emission of formaldehyde in a wood-based material, which comprises a formaldehyde-binding substance A and a hydroxide-releasing substance B. The invention further relates to a method for producing the porous carrier system, the use of the porous carrier system to reduce the emission of formaldehyde in a wood-based material, a wood-based material comprising the porous carrier system, and a method for producing said wood-based material.

The invention relates to a porous carrier system for reducing the emission of formaldehyde in a wood-based material, which comprises a formaldehyde-binding substance A and a hydroxide-releasing substance B. The invention further relates to a method for producing the porous carrier system, the use of the porous carrier system to reduce the emission of formaldehyde in a wood-based material, a wood-based material comprising the porous carrier system, and a method for producing said wood-based material.

There is provided a deodorizing material having particularly high deodorization capabilities for ammonia, acetaldehyde, and toluene. The deodorizing material of the present invention comprises fibrous activated carbon; and (A) an aromatic amine and a sulfate of the aromatic amine or (B) an aromatic amine, a sulfate of the aromatic amine, and sulfuric acid, supported on the fibrous activated carbon, wherein a total substance amount of the aromatic amine and the sulfate of the aromatic amine supported per gram of the fibrous activated carbon is 0.85 to 1.35 mmol, and a ratio of the total substance amount (mmol) of the aromatic amine and the sulfate of the aromatic amine supported per gram of the fibrous activated carbon relative to a total substance amount (mmol) of the sulfate of the aromatic amine and the sulfuric acid supported per gram of the fibrous activated carbon ([total substance amount of the aromatic amine and the sulfate of the aromatic amine][total substance amount of the sulfate of the aromatic amine and the sulfuric acid]) is 5.0 to 7.5.

There is provided a deodorizing material having particularly high deodorization capabilities for ammonia, acetaldehyde, and toluene. The deodorizing material of the present invention comprises fibrous activated carbon; and (A) an aromatic amine and a sulfate of the aromatic amine or (B) an aromatic amine, a sulfate of the aromatic amine, and sulfuric acid, supported on the fibrous activated carbon, wherein a total substance amount of the aromatic amine and the sulfate of the aromatic amine supported per gram of the fibrous activated carbon is 0.85 to 1.35 mmol, and a ratio of the total substance amount (mmol) of the aromatic amine and the sulfate of the aromatic amine supported per gram of the fibrous activated carbon relative to a total substance amount (mmol) of the sulfate of the aromatic amine and the sulfuric acid supported per gram of the fibrous activated carbon ([total substance amount of the aromatic amine and the sulfate of the aromatic amine][total substance amount of the sulfate of the aromatic amine and the sulfuric acid]) is 5.0 to 7.5.

A method for making a metal organic framework suspension is described herein. The method includes providing a hybrid material comprising a nano-crystalline metal organic framework comprising micropores and a mesoporous polymeric material comprising mesopores, wherein the nano-crystalline metal organic framework is homogeneously dispersed and substantially present only within the mesopores or void spaces of the mesoporous polymeric material; and wherein the hybrid material has a weight percentage of the metal organic framework in the range of 5-50% relative to the total weight of the hybrid material. The method includes contacting the hybrid material with a solvent in which the mesoporous polymeric material is soluble, thereby forming a polymeric solution in which the nano-crystalline metal organic framework is substantially homogeneously dispersed and suspended.

An energy efficient and durable thermal swing type carbon dioxide recovery and concentration device can be made smaller and use low-temperature heat waste of 100 C. or less. A honeycomb rotor carries adsorption particles having a sorption capacity for carbon dioxide. The rotor is rotated in a sealed casing divided into at least an sorption zone and a desorption zone and is brought into contact with material gas that contains carbon dioxide in a state wherein the honeycombs in the sorption zone are moist so as to adsorb the carbon dioxide while carrying out evaporative cooling of water. Then, the honeycombs that have adsorbed the carbon dioxide are moved to the desorption zone and brought into contact with low pressure vapor so as to desorb high concentration carbon dioxide. Thus, it is possible to continuously recover carbon dioxide at a high recovery rate and high concentration.

A method of adsorbing a highly reactive gas onto an adsorbent material comprising adsorbing the highly reactive gas to the adsorbent material. The adsorbent material comprises at least one Lewis basic functional group, or pores of a size to hold a single molecule of the highly reactive gas, or inert moieties which are provided to the adsorbent material at the same time at the same time as the highly reactive gas, prior to adsorbing the highly reactive gas or after adsorbing the highly reactive gas, or the highly reactive gas reacts with moieties of the adsorbent material resulting in passivation of the adsorbent material. A rate of decomposition of the adsorbed highly reactive gas is lower than a rate of decomposition for the neat gas at equal volumetric loadings and equal temperatures for both the adsorbed highly reactive gas and the neat gas.

A CO.sub.2 concentration device has an adsorbent body formed from sheet material. Solid adsorbent particles are adhered onto at least a single surface of the sheet material and then the sheet material is wound onto itself or laminated in layers. The adsorbent body is divided into at least into a processing zone and a regeneration zone. CO.sub.2 is adsorbed in the processing zone when the processing zone is wet with water and a CO.sub.2 containing gas is passed through. The regeneration zone desorbs CO.sub.2 when saturated steam is passed through. Condensation heat from the steam condensing causes CO.sub.2 desorption. The solid adsorbent particles may be aligned in a linear or a staggered arrangement when the solid adsorbent particles are adhered to the sheet material to follow a gas flow and form gas introduction paths between adjacent layers of the sheet material.

A CO.sub.2 concentration device has an adsorbent body formed from sheet material. Solid adsorbent particles are adhered onto at least a single surface of the sheet material and then the sheet material is wound onto itself or laminated in layers. The adsorbent body is divided into at least into a processing zone and a regeneration zone. CO.sub.2 is adsorbed in the processing zone when the processing zone is wet with water and a CO.sub.2 containing gas is passed through. The regeneration zone desorbs CO.sub.2 when saturated steam is passed through. Condensation heat from the steam condensing causes CO.sub.2 desorption. The solid adsorbent particles may be aligned in a linear or a staggered arrangement when the solid adsorbent particles are adhered to the sheet material to follow a gas flow and form gas introduction paths between adjacent layers of the sheet material.