Patent classifications
B01J21/005
Ferrite catalyst for oxidative dehydrogenation, method of preparing ferrite catalyst, and method of preparing butadiene using ferrite catalyst
A ferrite catalyst for oxidative dehydrogenation and a method of preparing the same. The ferrite catalyst is prepared using an epoxide-based sol-gel method, wherein a step of burning includes a first burning step, in which burning is performed at a temperature of 70 to 200 C.; and a second burning step, in which burning is performed after the temperature is raised from a temperature in the range of greater than 200 C. to 250 C. to a temperature in the range of 600 to 900 C.
BIFUNCTIONAL CATALYST COMPRISING PHOSPHOROUS
A bifunctional catalyst for example for conversion of oxygenates, said bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl.sub.2O.sub.4.
FISCHER-TROPSCH SYNTHESIS PROCESS COMPRISING A CATALYST PREPARED BY ADDITION OF AN ORGANIC COMPOUND IN GAS PHASE
A Fischer-Tropsch process for synthesizing hydrocarbons, by bringing a catalyst comprising a support and an active phase comprising a Group VIII metal into contact with a feedstock comprising synthesis gas, said catalyst being prepared according to the following steps: a) a porous support is provided; b) an organic compound containing oxygen and/or nitrogen is added to the porous support; c) a step of bringing said porous support into contact with a solution containing a salt of a precursor of the phase comprising a Group VIII metal is carried out; d) the porous support obtained at the end of step c) is dried;
characterized in that step b) is carried out by bringing together said porous support and said organic compound under conditions of temperature, pressure and duration such that a fraction of said organic compound is transferred in the gaseous state to the porous support.
Method for preparing supported catalyst for heterogeneous catalytic ozonation
A method for preparing a catalyst, including: 1) uniformly mixing attapulgite, lithium-manganese spinel (LiMn spinel), manganese dioxide powders to form mixed raw material; adding water to the mixed raw material; stirring and mixing the mixed raw material and the water for between 5 and 15 min to yield a reaction mixture; 2) feeding the reaction mixture in 1) to a pelletizer to prepare spherical particles or hollow cylindrical particles; drying the spherical particles or the hollow cylindrical particles to yield a precursor; 3) heating the precursor in a muffle furnace, and calcining the precursor to yield a crude catalyst; 4) mixing the crude catalyst with an acid solution; alternating between ultrasound and microwave to wash the crude catalyst; and 5) washing the crude catalyst in 4) with water; and drying the catalyst for 12 hrs in air at 105 C.
Catalyst and method for synthesis of aromatic hydrocarbons through direct conversion of synthesis gas
Synthesis of aromatic hydrocarbons from synthesis gas in a fixed bed or a moving bed reactor loaded with a composite catalyst comprising Catalyst Component A and Catalyst Component B mixed via a mechanical mixing mode, wherein the active ingredient of the Catalyst Component A is active metal oxides; and the Catalyst Component B is one or both of ZSM-5 zeolite and metal modified ZSM-5; the pressure of the synthesis gas is 0.1-6 MPa; the reaction temperature is 300-600 C.; and the space velocity is 500-8000 h.sup.1. The reaction process has a high product yield and selectivity, with the selectivity of aromatics reaching 50-85%, while the selectivity of the methane byproduct is less than 15%.
Exhaust system with a modified lean NOx trap
An exhaust system for treating an exhaust gas from an internal combustion engine is disclosed. The system comprises a modified lean NO.sub.x trap (LNT), a urea injection system, and an ammonia-selective catalytic reduction catalyst. The modified LNT comprises a first layer and a second layer. The first layer comprises a NO.sub.x adsorbent component and one or more platinum group metals. The second layer comprises a diesel oxidation catalyst zone and an NO oxidation zone. The diesel oxidation catalyst zone comprises a platinum group metal, a zeolite, and optionally an alkaline earth metal. The NO oxidation zone comprises a platinum group metal and a carrier. The modified LNT stores NO.sub.x at temperatures below about 200 C. and releases at temperatures above about 200 C. The modified LNT and a method of using the modified LNT are also disclosed.
Catalyst material and method of manufacturing the same
A method of manufacturing a catalyst material includes the steps of: providing a body having an open-porous foam structure and comprising at least a first metal or alloy; providing particles, each of which particles comprising at least a second metal or alloy; distributing the particles on the body; forming a structural connection between each of at least a subset of the particles and the body; and forming an oxide film on at least the subset of the particles and the body, wherein the oxide film has a catalytically active surface.
CO2 hydrogenation catalysts for the commercial production of syngas
The present invention is generally directed to the production of low-carbon syngas from captured CO.sub.2 and renewable H.sub.2. The H.sub.2 is generated from water using an electrolyzer powered by renewable electricity, or from any other method of low-carbon H.sub.2 production. The improved catalysts use low-cost metals, they can be produced economically in commercial quantities, and they are chemically and physically stable up to 2,100 F. CO.sub.2 conversion is between 80% and 100% with CO selectivity of greater than 99%. The catalysts don't sinter or form coke when converting H.sub.2:CO.sub.2 mixtures to syngas in the operating ranges of 1,300-1,800 F., pressures of 75-450 psi, and space velocities of 2,000-100,000 hr.sup.1. The catalysts are stable, exhibiting between 0 and 1% CO.sub.2 conversion decline per 1,000 hrs. The syngas can be used for the synthesis of low-carbon fuels and chemicals, or for the production of purified H.sub.2. The H.sub.2 can be used at the production site for the synthesis of low-carbon chemical products or compressed for transportation use.
One-step process for the production of hydrocarbons from carbon dioxide
The present invention are new and improved processes and catalysts that can efficiently facilitate the direct carbon dioxide conversion reaction with hydrogen to hydrocarbons in a single reactor at temperatures less than 450 C. and more preferably at temperatures from 250 C. to 325 C. Carbon dioxide is utilized from stationary sources or from direct air capture. Hydrogen is produced by the electrolysis of water using renewable or low carbon electricity.
Catalytic hydrogenation method for carbon nine resin
The present invention discloses a catalytic hydrogenation method for carbon nine resin, comprising the following steps: 1) adding a PtWY/?-Al.sub.2O.sub.3 catalyst in the first half of a fixed bed, adding a PdZrNd/?-Al.sub.2O.sub.3 catalyst in the second half of the fixed bed, and feeding hydrogen for reduction; and 2) catalytic hydrogenating the pretreated carbon nine resin in the fixed bed. In the present invention, different catalysts capable of reacting under the same catalytic conditions are added in the first and second halves of the fixed bed, and the two different catalysts play different roles, and can be active and complementary to each other under the same conditions. The synergistic effect of the two catalysts plays a good catalytic role. Moreover, the production process is simplified, and the production cost is saved.