The present invention relates to catalysts, catalyst systems, and processes for the production of valuable light olefins, such as C.sub.2-C.sub.4 olefins (ethylene, propylene, and/or butenes) from paraffinic hydrocarbons, such as propane, through dehydrogenation and metathesis. Some particular aspects relate to the discovery of non-precious metal catalysts and catalyst systems utilizing such catalysts, for example in the case of being in an admixture with a metathesis catalyst, which advantageously exhibit high performance in terms of activity, selectivity, and stability. Other advantages can include a reduced production of byproducts (e.g., methane and ethane) that result from undesired side reactions, in addition to benefits that may be attained through the addition of a sulfur-bearing compound (e.g., H.sub.2S).

A method of forming a fuel cell catalyst system, the method includes providing an anticorrosive, conductive catalyst support material having oxygen vacancies and a formula (I):
MgTi.sub.2O.sub.5-δ  (I),
where .sub.δ is any number between 0 and 3 optionally including a fractional part denoting the oxygen vacancies, coating the catalyst support material with a polymeric film, attaching a catalyst material onto the polymeric film, removing the polymeric film, and providing additional material onto the support material to increase physical, electrical, and/or mechanical contact between the catalyst material and the catalyst support material.

A method of forming a fuel cell catalyst system, the method includes providing an anticorrosive, conductive catalyst support material having oxygen vacancies and a formula (I):
MgTi.sub.2O.sub.5-δ  (I),
where .sub.δ is any number between 0 and 3 optionally including a fractional part denoting the oxygen vacancies, coating the catalyst support material with a polymeric film, attaching a catalyst material onto the polymeric film, removing the polymeric film, and providing additional material onto the support material to increase physical, electrical, and/or mechanical contact between the catalyst material and the catalyst support material.

Processes for upgrading a hydrocarbon. The process can include (I) contacting a hydrocarbon-containing feed with a catalyst that can include a Group 8-10 element or a compound thereof disposed on a support to effect conversion of the hydrocarbon-containing feed to produce a coked catalyst and an effluent. The process can also include (II) contacting the coked catalyst with an oxidant to effect combustion the coke to produce a regenerated catalyst. The process can also include (IIa) contacting the regenerated catalyst with a reducing gas to produce a regenerated and reduced catalyst. The process can also include (III) contacting an additional quantity of the hydrocarbon-containing feed with the regenerated and reduced catalyst. A cycle time from the contacting the hydrocarbon-containing feed with the catalyst in step (I) to the contacting the additional hydrocarbon-containing feed with the regenerated and reduced catalyst in step (III) can be ≤1 hours.

Processes for upgrading a hydrocarbon. The process can include contacting a hydrocarbon-containing feed with fluidized catalyst particles that can include a Group 8-10 element or a compound thereof disposed on a support to effect one or more of dehydrogenation, dehydroaromatization, and dehydrocyclization of at least a portion of the hydrocarbon-containing feed to produce coked catalyst particles and an effluent. The process can also include contacting at least a portion of the coked catalyst particles with an oxidant to effect combustion of at least a portion of the coke to produce regenerated catalyst particles. The process can also include contacting at least a portion of the regenerated catalyst particles with a reducing gas to produce regenerated and reduced catalyst particles. The process can also include contacting an additional quantity of the hydrocarbon-containing feed with fluidized regenerated and reduced catalyst particles to produce additional effluent and re-coked catalyst particles.

Processes for upgrading a hydrocarbon. The process can include contacting a hydrocarbon-containing feed with fluidized catalyst particles that can include a Group 8-10 element or a compound thereof disposed on a support to effect one or more of dehydrogenation, dehydroaromatization, and dehydrocyclization of at least a portion of the hydrocarbon-containing feed to produce coked catalyst particles and an effluent. The process can also include contacting at least a portion of the coked catalyst particles with an oxidant to effect combustion of at least a portion of the coke to produce regenerated catalyst particles. The process can also include contacting at least a portion of the regenerated catalyst particles with a reducing gas to produce regenerated and reduced catalyst particles. The process can also include contacting an additional quantity of the hydrocarbon-containing feed with fluidized regenerated and reduced catalyst particles to produce additional effluent and re-coked catalyst particles.

A method for producing chemicals from crude oil by double-tube parallel multi-zone catalytic conversion is provided. The method may include the following steps: feeding the crude oil directly or separating the crude oil into light and heavy components by flash evaporation or distillation after desalination and dehydration; strengthening the contact and reaction between oil gas and catalyst by using two parallel reaction tubes with novel structure, controlling the reaction by zones, carrying out optimal combination on feeding modes according to different properties of reaction materials, controlling suitable reaction conditions for different materials, and increasing the production of light olefins and aromatics.

Polymerization process control methods for making polyethylene are provided. The process control methods include performing a polymerization reaction in a polymerization reactor to produce the polyethylene, where ethylene, and optionally one or more comonomers, in the polymerization reaction is catalyzed by an electron donor-free Ziegler-Natta catalyst and an alkyl aluminum co-catalyst. A melt flow ratio (I.sub.21/I.sub.2) of the polyethylene removed from the polymerization reactor is measured and an amount of long chain branching (LCB) of the polyethylene from the polymerization reactor is controlled by adjusting a weight concentration of the alkyl aluminum co-catalyst present in the polymerization reactor. In addition, an electron donor-free Ziegler-Natta catalyst productivity of the polyethylene being produced in the polymerization reactor is measured from which the amount of LCB of the polyethylene from the polymerization reactor is determined using the measured electron donor-free Ziegler-Natta catalyst productivity and a predetermined relationship between the electron donor-free Ziegler-Natta catalyst productivity and the LCB.

Polymerization process control methods for making polyethylene are provided. The process control methods include performing a polymerization reaction in a polymerization reactor to produce the polyethylene, where ethylene, and optionally one or more comonomers, in the polymerization reaction is catalyzed by an electron donor-free Ziegler-Natta catalyst and an alkyl aluminum co-catalyst. A melt flow ratio (I.sub.21/I.sub.2) of the polyethylene removed from the polymerization reactor is measured and an amount of long chain branching (LCB) of the polyethylene from the polymerization reactor is controlled by adjusting a weight concentration of the alkyl aluminum co-catalyst present in the polymerization reactor. In addition, an electron donor-free Ziegler-Natta catalyst productivity of the polyethylene being produced in the polymerization reactor is measured from which the amount of LCB of the polyethylene from the polymerization reactor is determined using the measured electron donor-free Ziegler-Natta catalyst productivity and a predetermined relationship between the electron donor-free Ziegler-Natta catalyst productivity and the LCB.

This invention relates to a catalyst system comprising (a) at least one layer of a first catalyst comprising a dehydrogenation active metal on a solid support; (b) at least one layer of a second catalyst comprising a metal oxide; and (c) at least one layer of a third catalyst comprising a transition metal on an inorganic support; wherein the at least one layer of a second catalyst is sandwiched between the at least one layer of a first catalyst and the at least one layer of a third catalyst; and a process comprising contacting a hydrocarbon feed with the catalyst system.