To provide a method for producing propionaldehyde directly from glycerol with high yield, gasified glycerol is brought into contact with a silica-type regular mesoporous body. More specifically, gasified glycerol is supplied to a catalyst layer containing a regular mesoporous body while heating the catalyst layer at a temperature ranging from 200 to 800 C. in such a manner that a W/F value can fall within the range from 0.001 to 1000 g.Math.min/ml inclusive wherein W represents an amount (g) of a catalyst and F represents a supply rate (ml/min) of supplied glycerol.

According to this invention, a NiMoW trimetallic catalyst supported on porous alumina is obtained that shows very high activity for hydrotreating (HDT) of gasoils, particularly deep hydrodesulfurization (HDS) and hydrodesnitrogenation (HDN) of straight run gasoil in conditions of moderate pressure.

When the catalyst is applied to HDT of diesel, the NiMoW catalyst exhibits high catalytic activity. The content of sulfur and nitrogen in the resulting diesel can be reduced from 13,200 to 10 ppm and nitrogen from 360 ppm to less than 1 ppm, under moderate pressure, temperature and space-velocity (LHSV) similar to those of an industrial unit.

The catalytic composition, of trimetallic type, is prepared from an alumina support of high surface area to which a solution containing a metal precursor of an element of group VIB is added, followed by other solution that contains one of the precursors of the active metallic phase, a solution containing another of the precursors of the active metallic phase from group VIB, a metal promoter of group VIII and an additive promoter of acidity from group VB, and finally another solution containing a metal of group VIB, a metal of Group VIII and an organic compound, the used route promotes the preferential formation of well dispersed structures of the used metals on the support of porous alumina, less refractory to sulfidation, with high stacking and short lengths of metal sulfides formed in the resulting hydrodesulfurization catalyst. In the formulation, at least a percentage, but not all the Mo is replaced by W, in a Mo/W molar ratio of 0.6 to 2.0.

A catalyst carrier may have a cross-sectional shape that may include a plurality of surface channels having a first channel width and a second channel width, where the first channel width may be closer to a periphery of the cross-sectional shape than the second channel width and the first channel width may be less than the second channel width. The cross-sectional shape may further include a plurality of surface features where at least one surface feature is located between at least one pair of surface channels. The cross-sectional shape may further include a ratio L.sub.OC/L.sub.SCP of at least about 1.7, where L.sub.OC is a length of a total contour of the cross-sectional shape and L.sub.SCP is a length of an outer simple convex perimeter of the cross-sectional shape.

Methods for forming an interconnected network of solid material and pores, with metal residing only at the air/solid interface of the interconnected network structure are described. In certain embodiments, nanoparticle decorated sacrificial particles can be used as sacrificial templates for the formation of a porous structure having an interconnected network of solid material and interconnected network of pores. The nanoparticles reside predominantly at the air/solid interface and allow further growth and accessibility of the nanoparticles at defined positions of the interconnected structure. SEM and TEM measurements reveal the formation of 3D interconnected porous structures with nanoparticles residing predominantly at the air/solid interface of the interconnected structure.

In one embodiment, the present application discloses a catalyst composition comprising: a) a reaction solvent or a reaction medium; b) organometallic nanoparticles comprising: i) a nanoparticle (NP) catalyst, prepared by a reduction of an iron salt in an organic solvent, wherein the catalyst comprises at least one other metal selected from the group consisting of Pd, Pt, Au, Ni, Co, Cu, Mn, Rh, Ir, Ru and Os or mixtures thereof; c) a ligand; and d) a surfactant; wherein the metal or mixtures thereof is present in less than or equal to 50,000 ppm relative to the iron salt.

A catalyst for oxidising ammonia comprises a selective catalytic reduction (SCR) catalyst and a composite heterogeneous extruded honeycomb having longitudinally extending parallel channels, which channels being defined in part by channel walls having a total longitudinal length, wherein the channel walls comprise a pore structure including a periodic arrangement of porous cells embedded in an inorganic matrix component, at least some of which porous cells are defined at least in part by an active interface layer of a catalytically active material comprising a precious metal supported on particles of a support material.

Systems and methods are provided for modifying the composition of the conversion catalyst in a reactor for oxygenate conversion during conversion of an oxygenate feed to allow for adjustment of the slate of conversion products. The modification of the conversion catalyst can be performed by introducing a substantial portion (relative to the amount of catalyst inventory in the reaction system) of make-up catalyst having a distinct composition relative to the conversion catalyst in the reaction system. Introducing the distinct composition of make-up catalyst can modify the composition of the conversion catalyst in the reactor to allow for changes in the resulting product slate. By introducing the distinct catalyst composition, the conversion catalyst in the reactor can correspond to a different composition of catalyst than the overall average catalyst composition within the catalyst inventory in the reaction system.

Provided are a carbon powder which can provide a catalyst exhibiting high performance and a catalyst. A carbon powder for fuel cell comprising carbon as a main component, which has a ratio (B/A) of an area B of peak 1 to an area A of peak 0 of more than 0 and 0.15 or less, wherein the area A represents an area of peak 0 at a position of 2=22.5 to 25 as observed by XRD analysis when the carbon powder for fuel cell is subjected to heat treatment at 1800 C. for 1 hour in an inert atmosphere, and the area B represents an area of peak 1 at a position of 2=26 as observed by XRD analysis when the carbon powder for fuel cell is subjected to heat treatment at 1800 C. for 1 hour in an inert atmosphere.

A honeycomb structural body 20 comprises a porous partition portion 22 which forms a plurality of cells each functioning as a flow path of a fluid, and in the partition portion 22, the average pore diameter is 10 to 20 m, and a wet area rate R (=S/V) which is the rate of a wet area S of pores to a volume V of the partition portion 22 is 0.000239 m.sup.1 or more.

In the present disclosure, a heterogeneous nickel-based oligomerization catalyst in which nickel in the form of single atom is loaded on an Al-mesoporous silicate support by ion exchange and a method for producing the same, and a method for oligomerizing light olefins, specifically C4 olefins using the catalyst are described.