Patent classifications
B01J35/60
METHOD FOR PRODUCING METHYLENEMALONIC ACID ESTER
A method for producing a compound represented by the following Formula (II), the method comprising a step of subjecting a compound represented by the following Formula (I) to heat treatment in the presence of an organic sulfonic acid and an inorganic oxide solid to obtain the compound represented by the following Formula (II), wherein a Hammett acidity function of the inorganic oxide solid is more than ?12.0:
##STR00001##
wherein R each independently represents an alkyl group, an alkenyl group, or an aryl group,
##STR00002##
wherein R has the same meaning as R in Formula (I).
CATALYST AND METHOD FOR SULFUR-TOLERANT SHIFT CATALYTIC REACTION
A sulfur-tolerant catalyst can be used in the sulfur-tolerant shift catalytic reaction. The catalyst has a carrier and a molybdenum oxide, a cobalt oxide and a cobalt-molybdenum-based perovskite composite oxide carried thereon. The cobalt-molybdenum-based perovskite composite oxide contains a molybdenum element, a cobalt element, an A element, and an oxygen element. The A element is one or more selected from a group consisting of a rare-earth metal element, an alkali metal element and an alkaline earth metal element.
METHOD FOR PRODUCING MESOPOROUS TRANSITION-METAL CARBIDE LAYERS WITH DEFINED NANOSTRUCTURING, AND USE OF SAID TRANSITION-METAL CARBIDE LAYERS IN ELECTROCATALYSIS
The invention relates to a method for producing mesoporous metal carbide layer with defined nano-structuring, wherein during a first method step a mesoporous metal oxide layer is made available and in a second step, the metal oxide layer is brought in contact in a reducing atmosphere with a carbon source in the atmosphere, wherein the temperature is at least 650? C. and the heat-up rate ranges from 0.5 to 2 kelvin per minute.
METHOD FOR MANUFACTURING AMMONIA SYNTHESIS CATALYST, AND METHOD FOR MANUFACTURING AMMONIA
Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO.Math.7Al.sub.2O.sub.3 having a specific surface area of 5 m.sup.2/g or above; a second step for supporting a ruthenium compound on the 12CaO.Math.7Al.sub.2O.sub.3; and a third step for performing a reduction process on the 12CaO.Math.7Al.sub.2O.sub.3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.
METHOD FOR MANUFACTURING AMMONIA SYNTHESIS CATALYST, AND METHOD FOR MANUFACTURING AMMONIA
Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO.Math.7Al.sub.2O.sub.3 having a specific surface area of 5 m.sup.2/g or above; a second step for supporting a ruthenium compound on the 12CaO.Math.7Al.sub.2O.sub.3; and a third step for performing a reduction process on the 12CaO.Math.7Al.sub.2O.sub.3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.
LAYER STRUCTURED MULTIFUNCTIONAL MONOLITH CATALYST FOR ENERGY-EFFICIENT CONVERSION OF CO2 TO DIMETHYL ETHER
A layered-structure, multifunctional monolith catalyst is provided. The multifunctional monolith catalyst includes a monolithic substrate. A first layer is coated on a surface of the substrate. The first layer includes a first catalyst. A second layer is formed on top of the first layer. The second layer includes a second catalyst, and the second layer is porous. Layering of the first and second catalysts reduces degradation of one or both of the first and second catalysts, and increases a yield of the reaction catalyzed by the second catalyst. A method of converting carbon dioxide to dimethyl ether using the multifunctional monolith catalyst is also provided.
PROCESS FOR PRODUCING ORGANIC ACID ESTER-TYPE LIQUID, AND PROCESS FOR PRODUCING SOLVENT OF RESIST FOR PRODUCING ELECTRONIC PART OR RINSING LIQUID FOR PRODUCING ELECTRONIC PARTS
A process for producing an organic acid ester-type liquid is disclosed which is a process for removing an organic peroxide contained in an organic acid ester-type liquid which is a solvent of a resist for producing electronic parts or an organic acid ester-type liquid which is a rinsing liquid for producing electronic parts, which comprises contacting the organic acid ester-type liquid with a platinum group metal catalyst to remove the organic peroxide in the organic acid ester-type liquid, and a resist solvent for producing electronic parts or a rinsing liquid for producing electronic parts which comprises an organic acid ester-type liquid in which an organic peroxide contained therein has been removed by using the producing process and a peroxide value (POV) thereof is 2 mmoL/kg or less.
METHOD OF MAKING A COPPER OXIDE-TITANIUM VDIOXIDE NANOCATALYST
A method of making a copper oxide-titanium dioxide nanocatalyst for performing the catalytic oxidation of carbon monoxide is provided. The copper oxide-titanium dioxide nanocatalyst is in the form of copper oxide (CuO) nanoparticles supported on mesoporous titanium dioxide (TiO.sub.2) nanotubes. The copper oxide-titanium dioxide nanocatalyst is prepared by adding an aqueous solution of Cu(NO.sub.3).sub.23H.sub.2O to an aqueous suspension of titanium dioxide nanotubes. Deposition precipitation at constant alkaline pH is used to form the copper oxide nanoparticles supported on mesoporous titanium dioxide nanotubes. Aqueous sodium carbonate is used to adjust the pH. The solid matter (copper oxide deposited on titanium dioxide nanotubes) is separated from the suspension, washed, dried and calcined, yielding the copper oxide-titanium dioxide nanocatalyst. Carbon monoxide may then flow over a fixed-bed reactor loaded with the copper oxide-titanium dioxide nanocatalyst at a temperature between 80 C. and 200 C.
Pore opened zeolite nanosheets and their suspensions and methods and uses related thereto
Methods for forming two-dimensional (2D) zeolite nanosheets include exposing a multi-lamellar (ML) zeolite material including an organic structure directing agent (OSDA) to a mixture including sulfuric acid and hydrogen peroxide under conditions sufficient to remove substantially all of the OSDA from the ML zeolite material; and after exposing the ML zeolite material, treating a solution containing the ML zeolite material to sonication and/or mixing under conditions sufficient to substantially exfoliate layers of the ML zeolite to obtain porous two-dimensional zeolite nanosheets that are substantially free of the OSDA. In some cases, without further treatment such as secondary growth of the zeolite coating layer, a deposit of the OSDA-free nanosheets on polymer support exhibits hydrocarbon isomer selectivity.
METHOD FOR PRODUCING ALCOHOL
A method for producing an alcohol having 8 or more and 22 or less carbon atoms includes the following steps: step 1: forming a porous layer on a surface of a porous material having a pore size mode of 30 nm or more and 200 nm or less to obtain a bimodal carrier; step 2: supporting cobalt on the bimodal carrier obtained in step 1 to obtain a catalyst having peaks of pore distribution in a range of 1 nm or more and 25 nm or less and a range of 30 nm or more and 200 nm or less, respectively; and step 3: reacting carbon monoxide with hydrogen at a gauge pressure of 2 MPa or more and 100 MPa or less in the presence of the catalyst obtained in step 2.