The present disclosure provides a preparation method of a monometallic or bimetallic nanoparticle-supported catalyst. The synthesis of metal nanoparticles with different shapes, sizes, and atomic structures is affected by nucleation and growth rates. In the present disclosure, by changing a ratio of strong and weak reducing agents, a suitable double reducing agent is provided for metal nanoparticles with different reduction potentials, where the strong reducing agent is used for rapid nucleation and the weak reducing agent is used for the growth of metal nanoparticles. Accordingly, modulation and control of the nucleation and growth rates can be realized during the synthesis of nanoparticles. In addition, through multiple actions of a combination of reducing agents with different reduction intensities, monometallic/bimetallic nanoparticles of different sizes, shapes, and atomic structures are controllably prepared, which are then supported with a carrier to obtain the monometallic or bimetallic nanoparticle-supported catalyst.

The present invention provides a process for the hydrogenation of polyunsaturated hydrocarbon compounds, in particular di-olefins and alkynes, more particularly di-olefins, said process comprising contacting a feed comprising one or more polyunsaturated hydrocarbon compounds with a catalyst comprising copper and carbon in the presence of hydrogen, preferably wherein the catalyst is a copper catalyst on a carbon-containing support. The present invention also provides a process for producing a copper catalyst on a carbon-containing support and the use of a copper catalyst on a carbon-containing support to increase the selectivity towards di-olefin hydrogenation over mono-olefin hydrogenation in a process for hydrogenation of one or more di-olefins.

The present invention provides a process for the hydrogenation of polyunsaturated hydrocarbon compounds, in particular di-olefins and alkynes, more particularly di-olefins, said process comprising contacting a feed comprising one or more polyunsaturated hydrocarbon compounds with a catalyst comprising copper and carbon in the presence of hydrogen, preferably wherein the catalyst is a copper catalyst on a carbon-containing support. The present invention also provides a process for producing a copper catalyst on a carbon-containing support and the use of a copper catalyst on a carbon-containing support to increase the selectivity towards di-olefin hydrogenation over mono-olefin hydrogenation in a process for hydrogenation of one or more di-olefins.

The supported catalyst synthesis device according to the present disclosure includes a first source for a liquid containing a reducing agent; a second source for a liquid containing elements to constitute single-metal fine particles or solid solution fine particles to be supported; a third source for a liquid containing support particles; a reaction unit that joins flows of these liquids; a liquid feed route connecting between the first source and the reaction unit; a liquid feed route connecting between the second source and the reaction unit; a liquid feed route connecting between the third source and the reaction unit; and a collection unit, connected to the reaction unit via a pipe, to collect a produced reaction product, and further includes a pressure adjustment mechanism connected to the collection unit.

The supported catalyst synthesis device according to the present disclosure includes a first source for a liquid containing a reducing agent; a second source for a liquid containing elements to constitute single-metal fine particles or solid solution fine particles to be supported; a third source for a liquid containing support particles; a reaction unit that joins flows of these liquids; a liquid feed route connecting between the first source and the reaction unit; a liquid feed route connecting between the second source and the reaction unit; a liquid feed route connecting between the third source and the reaction unit; and a collection unit, connected to the reaction unit via a pipe, to collect a produced reaction product, and further includes a pressure adjustment mechanism connected to the collection unit.

Methods for fabricating thermally stable reducible metal oxide catalyst support structures on a base material using a multi-step incipient wetness impregnation (IWI) process are disclosed. For example, reducible metal oxide catalyst support structures having high surface area and high thermal stability may be formed using a multi-step IWI process, where the support structure is generated through high-temperature calcination between IWI steps. The metal or metal oxide catalysts fabricated using the methods are also disclosed. The generation of engineered surface defects on reducible metal oxides using a gas reduction process to serve as anchoring sites for metal or metal oxide catalysts is also disclosed. Generating engineered defects through a gas reduction process may be a relatively low-cost and scalable process suitable for fabricating efficient catalysts using a wide range of materials.

Methods for fabricating thermally stable reducible metal oxide catalyst support structures on a base material using a multi-step incipient wetness impregnation (IWI) process are disclosed. For example, reducible metal oxide catalyst support structures having high surface area and high thermal stability may be formed using a multi-step IWI process, where the support structure is generated through high-temperature calcination between IWI steps. The metal or metal oxide catalysts fabricated using the methods are also disclosed. The generation of engineered surface defects on reducible metal oxides using a gas reduction process to serve as anchoring sites for metal or metal oxide catalysts is also disclosed. Generating engineered defects through a gas reduction process may be a relatively low-cost and scalable process suitable for fabricating efficient catalysts using a wide range of materials.

In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.

In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.

In the present disclosure, a composite oxide catalyst capable of effectively suppressing side reactions at the time of dehydrogenation of C4 hydrocarbons having single bonds or one double bond and a process for preparing butadiene, in particular 1,3-butadiene, with a high selectivity and a high yield using the same are described.