B01J41/02

Calcium silicate hydrate anion exchange membrane useful for water electrolysis and fuel cells and a process for the preparation thereof

The present invention relates to a process for the preparation of Calcium Silicate Hydrate anion exchange membrane (cement paste) with an ionic conductivity of the order of 10.sup.3 S/cm. The membrane can be formulated by mixing Ordinary Portland Cement (OPC) and water with the cement to water ratio of 1:0.45. After initial setting time, the membrane undergoes curing in 7% calcium chloride solution and the Cl.sup. ions in the membrane is converted to OH.sup. form by immersing into saturated Ca(OH).sub.2 solution with pH 14 and it has been washed to remove the excess alkali. This membrane has high mechanical strength (Ultimate Tensile Strength: 6.3 MPa) and does not deteriorate even at high temperature (up to 450 C.) and alkaline atmosphere (pH 11.5-14). Also disclosed is a method of producing in-situ formation of membrane electrode assembly. This invention encompasses a process for producing and using the membrane in water electrolysis and fuel cell.

Calcium silicate hydrate anion exchange membrane useful for water electrolysis and fuel cells and a process for the preparation thereof

The present invention relates to a process for the preparation of Calcium Silicate Hydrate anion exchange membrane (cement paste) with an ionic conductivity of the order of 10.sup.3 S/cm. The membrane can be formulated by mixing Ordinary Portland Cement (OPC) and water with the cement to water ratio of 1:0.45. After initial setting time, the membrane undergoes curing in 7% calcium chloride solution and the Cl.sup. ions in the membrane is converted to OH.sup. form by immersing into saturated Ca(OH).sub.2 solution with pH 14 and it has been washed to remove the excess alkali. This membrane has high mechanical strength (Ultimate Tensile Strength: 6.3 MPa) and does not deteriorate even at high temperature (up to 450 C.) and alkaline atmosphere (pH 11.5-14). Also disclosed is a method of producing in-situ formation of membrane electrode assembly. This invention encompasses a process for producing and using the membrane in water electrolysis and fuel cell.

Ammonia sequestering system

The present invention is an ammonia sequestering system including a system controller connected to a plurality of flow control valves, a feed stream extending through a system inlet, and a system outlet. The feed stream is a liquid contaminated with ammonia. At least one exchange column is located between the system inlet and the system outlet. The ion column includes an ion exchange material, a column inlet connected to one of the flow control valves, and a column outlet connected to another of the flow control valves. The system also includes a regenerant stream of an aqueous solution of sodium cations, as well as an ammonia brine stream made up of the regenerant stream and ammonia.

Ammonia sequestering system

The present invention is an ammonia sequestering system including a system controller connected to a plurality of flow control valves, a feed stream extending through a system inlet, and a system outlet. The feed stream is a liquid contaminated with ammonia. At least one exchange column is located between the system inlet and the system outlet. The ion column includes an ion exchange material, a column inlet connected to one of the flow control valves, and a column outlet connected to another of the flow control valves. The system also includes a regenerant stream of an aqueous solution of sodium cations, as well as an ammonia brine stream made up of the regenerant stream and ammonia.

METHOD FOR TRANSPORTING NITRIDE IONS IN AN ELECTROCHEMICAL CELL

A method for transporting nitride (N.sup.3) ions in an electrochemical cell includes providing nitrogen to a first side of a solid electrolyte membrane to form nitride ions and transporting the nitride ions across the solid electrolyte membrane. The solid electrolyte membrane includes a metal nitride. The method may be used for ionically-mediated separation and/or compression of nitrogen or to form ammonia.

METHOD FOR TRANSPORTING NITRIDE IONS IN AN ELECTROCHEMICAL CELL

A method for transporting nitride (N.sup.3) ions in an electrochemical cell includes providing nitrogen to a first side of a solid electrolyte membrane to form nitride ions and transporting the nitride ions across the solid electrolyte membrane. The solid electrolyte membrane includes a metal nitride. The method may be used for ionically-mediated separation and/or compression of nitrogen or to form ammonia.

Zirconium phosphate and zirconium oxide recharger control logic and operational process algorithms

Control logic and processes for monitoring and controlling sorbent rechargers are presented. The control logic and processes use control systems to monitor the rechargers for performance problems and to control the recharging process. Various sensors in communication with the control systems are provided to ensure proper operation.

Zirconium phosphate and zirconium oxide recharger control logic and operational process algorithms

Control logic and processes for monitoring and controlling sorbent rechargers are presented. The control logic and processes use control systems to monitor the rechargers for performance problems and to control the recharging process. Various sensors in communication with the control systems are provided to ensure proper operation.

Cartridges Useful In Cleaning Dialysis Solutions

Cartridges useful in regenerating or purifying dialysis solutions are described as well as methods to regenerate or purify spent dialysis solutions. Dialysis methods using the sorbent cartridges of the present invention are further described.

Cartridges Useful In Cleaning Dialysis Solutions

Cartridges useful in regenerating or purifying dialysis solutions are described as well as methods to regenerate or purify spent dialysis solutions. Dialysis methods using the sorbent cartridges of the present invention are further described.