A coating liquid for preparing a needle-shaped cylinder liner, comprising the following components: 0.05-0.4 parts of an anionic surfactant; 0.05-0.5 parts of tannic acid; 0.15-0.7 parts of caustic soda; 22-38 parts of diatomite; 3-10 parts of montmorillonite; and 62-75 parts of water. A method for preparing a needle-shaped cylinder liner comprises spraying a coating liquid for preparing the needle-shaped cylinder liner onto the inner wall of a hollow cylindrical mould, and drying the coating liquid to obtain a mould with a coating attached to the surface of the inner wall; adding an inoculated iron liquid into the rotary mould, and cooling and demoulding to obtain a cylinder liner blank; and subjecting the blank to outer surface cleaning and forming machining to obtain the needle-shaped cylinder liner.

A composite roll for rolling comprising an outer layer and an inner layer integrally fused to each other; the outer layer being made of an Fe-based alloy comprising by mass 1-3% of C, 0.3-3% of Si, 0.1-3% of Mn, 0.1-5% of Ni, 1-7% of Cr, 1-8% of Mo, 4-7% of V, 0.005-0.15% of N, and 0.05-0.2% of B; the inner layer being made of graphite cast iron comprising by mass 2.4-3.6% of C, 1.5-3.5% of Si, 0.1-2% of Mn, 0.1-2% of Ni, less than 0.7% of Cr, less than 0.7% of Mo, 0.05-1% of V, and 0.01-0.1% of Mg; the inner layer comprising a core portion fused to the outer layer, and shaft portions integrally extending from both ends of the core portion; at least one of the shaft portions containing 200/cm.sup.2 or more of hard MC carbides having circle-equivalent diameters of 5 μm or more.

A composite roll for rolling comprising an outer layer and an inner layer integrally fused to each other; the outer layer being made of an Fe-based alloy comprising by mass 1-3% of C, 0.3-3% of Si, 0.1-3% of Mn, 0.1-5% of Ni, 1-7% of Cr, 1-8% of Mo, 4-7% of V, 0.005-0.15% of N, and 0.05-0.2% of B; the inner layer being made of graphite cast iron comprising by mass 2.4-3.6% of C, 1.5-3.5% of Si, 0.1-2% of Mn, 0.1-2% of Ni, less than 0.7% of Cr, less than 0.7% of Mo, 0.05-1% of V, and 0.01-0.1% of Mg; the inner layer comprising a core portion fused to the outer layer, and shaft portions integrally extending from both ends of the core portion; at least one of the shaft portions containing 200/cm.sup.2 or more of hard MC carbides having circle-equivalent diameters of 5 μm or more.

There is provided a centrifugally cast composite roll for rolling having excellent wear resistance and surface deterioration resistance at levels of a high-speed steel cast iron roll and having rolling incident resistance at a level of a high alloy grain cast iron roll. A centrifugally cast composite roll for rolling having an outer layer and an inner layer, the outer layer including chemical components by mass ratio: C: 1.0 to 3.0%; Si: 0.3 to 3.0%; Mn: 0.1 to 3.0%; Ni: 0.1 to 6.0%; Cr: 0.5 to 6.0%; Mo: 0.5 to 6.0%; V: 3.0 to 7.0%; Nb: 0.1 to 3.0%; B: 0.001 to 0.1%; N: 0.005 to 0.070%; and the balance being Fe and inevitable impurities, wherein: the chemical composition of the outer layer satisfies following Formula (1), has a crystallization and precipitation amount of graphite suppressed to less than 0.3% by area ratio, and has 1 to 15% of MC carbide by area ratio; and the centrifugally cast composite roll for rolling does not have a cast defect having a diameter of ϕ4 mm or more at a boundary between the outer layer and the inner layer,

50×N+V<9.0  (1).

There is provided a centrifugally cast composite roll for rolling having excellent wear resistance and surface deterioration resistance at levels of a high-speed steel cast iron roll and having rolling incident resistance at a level of a high alloy grain cast iron roll. A centrifugally cast composite roll for rolling having an outer layer and an inner layer, the outer layer including chemical components by mass ratio: C: 1.0 to 3.0%; Si: 0.3 to 3.0%; Mn: 0.1 to 3.0%; Ni: 0.1 to 6.0%; Cr: 0.5 to 6.0%; Mo: 0.5 to 6.0%; V: 3.0 to 7.0%; Nb: 0.1 to 3.0%; B: 0.001 to 0.1%; N: 0.005 to 0.070%; and the balance being Fe and inevitable impurities, wherein: the chemical composition of the outer layer satisfies following Formula (1), has a crystallization and precipitation amount of graphite suppressed to less than 0.3% by area ratio, and has 1 to 15% of MC carbide by area ratio; and the centrifugally cast composite roll for rolling does not have a cast defect having a diameter of ϕ4 mm or more at a boundary between the outer layer and the inner layer,

50×N+V<9.0  (1).

There is provided a centrifugally cast composite roll for rolling having excellent wear resistance and surface deterioration resistance at levels of a high-speed steel cast iron roll and having rolling incident resistance at a level of a high alloy grain cast iron roll. Its outer layer includes chemical components by mass ratio: C: 1.5 to 3.5%; Si: 0.3 to 3.0%; Mn: 0.1 to 3.0%; Ni: 1.0 to 6.0%; Cr: 1.5 to 6.0%; Mo: 0.1 to 2.5%; V: 2.0 to 6.0%; Nb: 0.1 to 3.0%; B: 0.001 to 0.2%; N: 0.005 to 0.070%; and the balance being Fe and inevitable impurities, wherein: a chemical composition of the outer layer satisfies Formula (1) and has 5 to 30% of M.sub.3C carbide by area ratio; an outer layer Shore hardness (A) of a roll surface satisfies Formula (2); and a residual stress (B) of the roll surface satisfies Formula (3),

2×Ni+0.5×Cr+Mo>10.0  (1)

Hs 75≤A≤Hs 85  (2)

100 MPa≤B≤350 MPa  (3).

A composite roll for rolling having a structure comprising centrifugally cast outer and intermediate layers of an Fe-based alloy integrally fused to an inner layer of ductile cast iron; the outer layer having a composition comprising by mass 1-3% of C, 0.3-3% of Si, 0.1-3% of Mn, 0.5-5% of Ni, 1-7% of Cr, 2.2-8% of Mo, 4-7% of V, 0.005-0.15% of N, and 0.05-0.2% of B, the balance being Fe and inevitable impurities; the intermediate layer containing 0.025-0.15% by mass of B; the B content in the intermediate layer being 40-80% of that in the outer layer; and the total amount of Cr, Mo, V, Nb and W in the intermediate layer being 40-90% of that in the outer layer.

A composite roll for rolling having a structure comprising centrifugally cast outer and intermediate layers of an Fe-based alloy integrally fused to an inner layer of ductile cast iron; the outer layer having a composition comprising by mass 1-3% of C, 0.3-3% of Si, 0.1-3% of Mn, 0.5-5% of Ni, 1-7% of Cr, 2.2-8% of Mo, 4-7% of V, 0.005-0.15% of N, and 0.05-0.2% of B, the balance being Fe and inevitable impurities; the intermediate layer containing 0.025-0.15% by mass of B; the B content in the intermediate layer being 40-80% of that in the outer layer; and the total amount of Cr, Mo, V, Nb and W in the intermediate layer being 40-90% of that in the outer layer.

A method to manufacture a tubular element for transferring abrasive materials such as concrete, inert materials or suchlike, wherein the tubular element comprises an internal tubular component made of chromium carbide or other wear-resistant material, and an internal tubular component in contact with and coaxial to the internal tubular component and made of composite material.

A method to manufacture a tubular element for transferring abrasive materials such as concrete, inert materials or suchlike, wherein the tubular element comprises an internal tubular component made of chromium carbide or other wear-resistant material, and an internal tubular component in contact with and coaxial to the internal tubular component and made of composite material.