The present disclosure provides for a heat-shrinkable, biaxially stretched, multilayer thermoplastic film that includes at least a puncture resistant layer. The puncture resistant layer is formed with a polyethylene based plastomer having a density of 0.890 g/cm.sup.3to 0.910 g/cm.sup.3 as measured in accordance with ASTM D-792, and a melt index (MI) as measured by ASTM D-1238 at 190° C./2.16 kg from 0.20 g/10 minutes to 1.5 g/10 minutes. The polyethylene based plastomer has a log M.sub.25% of an upper 25% of a GPC quadrant having a value of 5.1 to 5.7, an intermediate molecular weight distribution (Mw/Mn) of 2.5 to 3, a Mz/Mw value of 2 to 2.5, a Comonomer Distribution Constant value from 60 to 400 and a single SCBD peak between 40-85° C. with a mass fraction of less than 3% above 85° C. as determined by CEF, and a ZSVR value from 1.0 to 5.5. The multilayer thermoplastic film is biaxially stretched at a temperature of 60° C. to 120° C. with a blow-up ratio from 2:1 to 10:1.

The present disclosure provides for a heat-shrinkable, biaxially stretched, multilayer thermoplastic film that includes at least a puncture resistant layer. The puncture resistant layer is formed with a polyethylene based plastomer having a density of 0.890 g/cm.sup.3to 0.910 g/cm.sup.3 as measured in accordance with ASTM D-792, and a melt index (MI) as measured by ASTM D-1238 at 190° C./2.16 kg from 0.20 g/10 minutes to 1.5 g/10 minutes. The polyethylene based plastomer has a log M.sub.25% of an upper 25% of a GPC quadrant having a value of 5.1 to 5.7, an intermediate molecular weight distribution (Mw/Mn) of 2.5 to 3, a Mz/Mw value of 2 to 2.5, a Comonomer Distribution Constant value from 60 to 400 and a single SCBD peak between 40-85° C. with a mass fraction of less than 3% above 85° C. as determined by CEF, and a ZSVR value from 1.0 to 5.5. The multilayer thermoplastic film is biaxially stretched at a temperature of 60° C. to 120° C. with a blow-up ratio from 2:1 to 10:1.

The present invention relates to an external cooling system for a molten film tube produced by a blown film tubular extrusion process, comprised of one or more enclosures with one or more respective cavities that directly receive a portion of cooling gas emanating from one or more associated cooling elements. Each enclosure includes a port containing a variable exhaust device and optional flow buffer, acting to maintain a pressure differential between the cavity and an adjacent inside volume of the molten film tube, adjustable to optimize molten film tube stability cooling element efficiency and spaced apart dimension between cooling elements. Significant increases in production speeds are achieved with improved film quality over an increased range of tubular film sizes, down to a minimum size which occurs when operating at zero internal to molten film tube pressure.

The present invention relates to an external cooling system for a molten film tube produced by a blown film tubular extrusion process, comprised of one or more enclosures with one or more respective cavities that directly receive a portion of cooling gas emanating from one or more associated cooling elements. Each enclosure includes a port containing a variable exhaust device and optional flow buffer, acting to maintain a pressure differential between the cavity and an adjacent inside volume of the molten film tube, adjustable to optimize molten film tube stability cooling element efficiency and spaced apart dimension between cooling elements. Significant increases in production speeds are achieved with improved film quality over an increased range of tubular film sizes, down to a minimum size which occurs when operating at zero internal to molten film tube pressure.

Disclosed is a composition that comprises or is produced from a first ethylene α-olefin copolymer, a modified first ethylene α-olefin copolymer, and a second ethylene α-olefin copolymer or propylene α-olefin copolymer. Also disclosed is a multilayer film or sheet structure containing at least one barrier layer; at least one predominantly propylene-based layer, at least one predominantly ethylene-based layer, or both; and at least one adhesive layer produced from the composition. Further disclosed is a produced for producing a multilayer structure using the composition as adhesive layer.

Disclosed is a composition that comprises or is produced from a first ethylene α-olefin copolymer, a modified first ethylene α-olefin copolymer, and a second ethylene α-olefin copolymer or propylene α-olefin copolymer. Also disclosed is a multilayer film or sheet structure containing at least one barrier layer; at least one predominantly propylene-based layer, at least one predominantly ethylene-based layer, or both; and at least one adhesive layer produced from the composition. Further disclosed is a produced for producing a multilayer structure using the composition as adhesive layer.

Provided are oriented biodegradable thermoplastic polyurethane films. The films may be prepared by extruding and drawing biodegradable polyurethane films. The polyurethanes may be prepared from biodegradable polyols and/or biodegradable chain extenders. The films possess high tensile strength yet are degradable under biological conditions. The films may be utilized in the fabrication of devices, particularly implantable medical devices.

A method of making a 3D tube and the 3D tube made thereby. The method comprises: inserting a deflated pre-formed bladder into the 3D tube; and inflating the pre-formed bladder to deform the 3D tube and make the 3D tube have a substantially similar shape as that of the pre-formed bladder inflated.

The invention relates to an apparatus for producing tubular films stretched in-line by blow molding with an extruder, a film blowing line, a lay-flat unit, an oscillating haul-off unit, and a stretching line for monoaxially stretching the film laid flat in machine direction. According to the invention, the stretching line is arranged above the extruder between the lay-flat unit and the oscillating haul-off unit.

A device and method for blowing and stretching a plastic film are provided. A first blow-expanding mechanism subjects a primitive plastic film made of PVC, PLA, or PET to extrusion at a temperature of 140° C.-180° C. and primary blow-expansion to form a volume in which the primitive plastic film has a lateral opening ratio of 1:1. Front-stage press rollers and middle-stage press rollers then subject the primitive plastic film to primary longitudinal press-flattening and pull-stretching, followed by heating and blow-expanding by the second blow-expansion mechanism at a temperature of 160° C.-220° C. and a pressure of 1.1-1.6 atm to achieve a volume in which the primitive plastic film has lateral opening ratio of at least 2:1, further followed by reduction of temperature to a temperature of 10° C.-20° C. for shape fixing to form a shaped plastic film. Finally, rear-stage press rollers subject the shaped plastic film to secondary longitudinal press-flattening and pull-stretching.