Rupturable, dual reagent mono-capsules are disclosed that have a core composition, which includes a carboxylic acid, encapsulated within a phenolic resin-containing polymer wall that ruptures upon exposure to alkaline conditions over a period of time, and a shell connected to an exterior surface of the polymer wall by a surfactant. The shell is made from a mineral containing a metal that is chemically bonded to the surfactant by a chemical electrostatic interaction. Upon rupture of the polymer wall of the mono-capsule, the carboxylic acid and the mineral containing the metal chemically react with one another to form a reaction product that seals a rupture in the capsule and/or seals a feature of a surface upon which the capsules are disposed.

A joining method for joining a first member having a hole that is opened on at least one surface, to a second member including a material of which a melting temperature is lower than that of a constituent material of the first member, includes: laminating the second member on the first member so as to cover an opening of the hole; and introducing that material of the second member which is softened or melted into the hole through the opening and curing the material of the second member.

A joining method for joining a first member having a hole that is opened on at least one surface, to a second member including a material of which a melting temperature is lower than that of a constituent material of the first member, includes: laminating the second member on the first member so as to cover an opening of the hole; and introducing that material of the second member which is softened or melted into the hole through the opening and curing the material of the second member.

Making a carbon aerogel involves 3-D printing an ink to make a printed part, removing the solvent from the printed part, and carbonizing the printed part (with the solvent removed) to make the aerogel. The ink is based on a solution of a resorcinol-formaldehyde resin (RF resin), water, and an organic thickener. Advantageously, the RF resin contains an acid catalyst, which tends to produce carbon aerogels with higher surface areas upon activation than those produced from methods involving an ink composition containing a base catalyzed resin.

A system for fabricating an ablative, 3D fiber-woven thermal protection material, with porosity 0.5-15 percent, reduced thermal conductivity, very low thermal recession, high glass transition temperature, high frontface-backface temperature difference, relatively high mass density, and significant compression strength and tensile strength.

A ultrasonic welding method of joining dissimilar-material workpieces, such as sheet materials, and the joined components formed thereby. The method includes applying ultrasonic energy to a thermoplastic piece to fill a hole of a dissimilar piece to form a weld point that is made up with polymer from the thermoplastic piece. In general, the geometry of the thermoplastic piece is not altered during the process. The dissimilar piece generally has a higher melting temperate and can be metal, thermoset polymers, or other thermoplastic material. The welded pieces can be arranged in a lap, laminate, or double lap configuration. In some embodiments, the hole of the dissimilar sheet material includes undercut features that improve the mechanical interlock between the dissimilar pieces. In some embodiments, the weld point has a mushroom cap to improve mechanical interlock.

A ultrasonic welding method of joining dissimilar-material workpieces, such as sheet materials, and the joined components formed thereby. The method includes applying ultrasonic energy to a thermoplastic piece to fill a hole of a dissimilar piece to form a weld point that is made up with polymer from the thermoplastic piece. In general, the geometry of the thermoplastic piece is not altered during the process. The dissimilar piece generally has a higher melting temperate and can be metal, thermoset polymers, or other thermoplastic material. The welded pieces can be arranged in a lap, laminate, or double lap configuration. In some embodiments, the hole of the dissimilar sheet material includes undercut features that improve the mechanical interlock between the dissimilar pieces. In some embodiments, the weld point has a mushroom cap to improve mechanical interlock.

This invention relates to the production of cured polymeric skin materials. In particular, the invention relates to methods and substrates for the production of skin materials, for example, for use in building, furniture, and as architectural components for example in roofing materials such as roofing tiles, or for brick wall effect materials.

An ablative material comprises a phenolic resin, a polymeric phosphorylated amide, and a number of fillers. The polymeric phosphorylated amide is in the ratio of between 1 and 10 parts of the polymeric phosphorylated amide per 100 parts of phenolic resin or resin solids, by weight.

Making a carbon aerogel involves 3-D printing an ink to make a printed part, removing the solvent from the printed part, and carbonizing the printed part (with the solvent removed) to make the aerogel. The ink is based on a solution of a resorcinol-formaldehyde resin (RF resin), water, and an organic thickener. Advantageously, the RF resin contains an acid catalyst, which tends to produce carbon aerogels with higher surface areas upon activation than those produced from methods involving an ink composition containing a base catalyzed resin.