In various aspects, reinforced composite filaments, methods of making reinforced composite filaments, and methods of producing reinforced composite filament are all provided herein. The reinforced composite filaments can include a thermoplastic polymer matrix having dispersed therein reinforcing fibers composed of a thermotropic liquid crystalline polymer. In some aspects, the thermoplastic polymer matrix is chosen such that a processing temperature for the thermoplastic polymer matrix is below a melting temperature of the thermotropic liquid crystalline polymer. In some aspects, the thermotropic liquid crystalline polymer is chosen such that a solidification temperature of the thermotropic liquid crystalline polymer is below an upper processing temperature of the thermoplastic polymer matrix. The filaments can be used for fused deposition manufacturing of a variety of parts, especially for the automotive and other industries.

The present invention relates to a pellet mixture including a pellet of a liquid crystal polyester resin composition which contains a liquid crystal polyester resin and an inorganic filler, and a fine powder formed of an organic material, in which a volume average particle diameter of the fine powder is in a range of 10 μm to 200 μm, and an amount of the fine powder is in a range of 10 ppm to 2000 ppm with respect to the total mass of the pellet mixture.

A method of manufacturing a composite member including an aluminum member and a fiber-reinforced resin member bonded to each other, the method including: performing blasting on a surface of the aluminum member; modifying the surface of the aluminum member into aluminum hydroxide, the modifying including causing the surface of the aluminum member having undergone blasting to react with water by using at least one of heat and plasma; and directly bonding the fiber-reinforced resin member to the surface of the aluminum member modified to the aluminum hydroxide.

A product includes a three-dimensional structure having a plurality of sequentially-formed layers comprised of liquid crystal elastomers. The liquid crystal elastomers in a portion of a first of the layers are substantially aligned in a predefined first orientation and the liquid crystal elastomers in a portion of a second of the layers are substantially aligned in a predefined second orientation that is different than the first orientation. Each of the portions of the three-dimensional structure is characterized as exhibiting a shape change in response to a stimulus, wherein the shape change is reversible. The product includes a contiguous region of aligned liquid crystal elastomers in one of the portions having a maximum dimension of less than 60 microns.

The present invention discloses an LCP film production apparatus and method. The apparatus includes: a rack; a screw extrusion device; a T-shaped material port; a squeezing assembly, where the squeezing assembly includes a first roller wheel, a second roller wheel, and a third roller wheel, the first roller wheel and the second roller wheel are fixedly mounted directly below the T-shaped material port side by side, and the third roller wheel is fixedly mounted next to the second roller wheel side by side; and an electromagnetic field generator, fixedly connected to the T-shaped material port and mounted around the T-shaped material port in a circle by means of bolts, where the screw extrusion device is fixedly mounted at the top of the rack, and the T-shaped material port is fixedly mounted on one end of the screw extrusion device. According to the present invention, a field generated by the electromagnetic field generator can disrupt the ordered arrangement of LCP molecules, thereby alleviating or even eliminating the anisotropic problem of transverse and longitudinal tensile strength thereof.

A method for producing molded foam articles that molds molded foam articles continuously, the method comprising continuously repeating the following step 1, step 2, step 3 and step 4 in this order; wherein step 1 comprises melting a resin composition that includes a liquid crystal polyester; step 2 comprises introducing, with an introduction device, a supercritical fluid that is unreactive, in a supercritical state, with the liquid crystal polyester, and is a gas at normal temperature and normal pressure, into the resin composition in an amount of at least 0.1 parts by mass but not more than 0.3 parts by mass per 100 parts by mass of the liquid crystal polyester, and then melt-kneading the resultant mixture; step 3 comprises injecting the melt-kneaded resin composition containing the supercritical fluid into a mold; and step 4 comprises conducting foaming by lowering at least one of the pressure and the temperature of the supercritical fluid contained in the resin composition to a value below the critical point of the supercritical fluid, thereby producing a molded foam article. This liquid crystal polyester has a melt tension at a temperature 20 C. higher than the flow start temperature of at least 5 mN but not more than 100 mN.

A process for the production of a polymeric article directed to (a)forming apply having successive layers, namely, (i) a first layer made up of strands of an oriented polymer material; (ii)a second layer of a polymeric material; (iii)a third layer made up of strands of an oriented polymeric material, wherein the second layer has a lower peak melting temperature that of the first and third layers; (b)subjecting the ply to conditions of time, temperature, and pressure sufficient to melt a proportion of the firsts layer to melt the second layer entirely, and to melt a proportion of the third layer, and to compact the ply; and (c)cooling the compacted ply. The resultant articles have good mechanical properties yet may be made at a lower compaction temperature than articles not employing the second layer, leading to a more controllable manufacturing process.

A liquid crystal polymer film, and a composite film of liquid crystal polymer and polyimide and a manufacturing method thereof are provided. The liquid crystal polymer film includes 63 wt % to 74 wt % of p-hydroxybenzoic acid, 21 wt % to 26 wt % of 6-hydroxy-2-naphthoic acid, and 5 wt % to 11 wt % of p-hydroxycinnamic acid. The composite film is manufactured by thermocompressing a single layer or multi layers of liquid crystal polymer film and polyimide film so that the composite film can have high flatness and the surface roughness Sa of the composite film is ranging from 0.1 m to 10 m. In the production process of the composite film, the composite film is rolled up and attached to a copper foil to form a high frequency substrate with good processability. After peeling the polyimide film, the liquid crystal polymer film can be thermocompressed to form a four-layered, six-layered, eight-layered or eight-layered high frequency substrate.

An electrical wire includes a conductor and an insulating layer that covers the conductor and that is cross-linked. The insulating layer is a cross-linked product of a resin composition including (a) a base polymer containing polyolefin and a compatibilizer, (b) a photoradical generator of 0.5 parts by mass or more and 3 parts by mass or less relative to the 100 parts by mass of the base polymer, and (c) a reactive monomer of 1 part by mass or more and 5 parts by mass or less relative to the 100 parts by mass of the base polymer. A relative dielectric constant of the insulating layer is less than 2.5.

A process for the production of a polymeric article directed to (a) forming a ply having successive layers, namely, (i) a first layer made up of strands of an oriented polymer material; (ii) a second layer of a polymeric material; (iii) a third layer made up of strands of an oriented polymeric material, wherein the second layer has a lower peak melting temperature that of the first and third layers; (b) subjecting the ply to conditions of time, temperature, and pressure sufficient to melt a proportion of the firsts layer to melt the second layer entirely, and to melt a proportion of the third layer, and to compact the ply; and (c) cooling the compacted ply. The resultant articles have good mechanical properties yet may be made at a lower compaction temperature than articles not employing the second layer, leading to a more controllable manufacturing process.