The invention relates to fluoropolymer filament for use in 3-D printing, and 3-D printed fluoropolymer articles having low warpage, excellent chemical resistance, excellent water resistance, flame resistance, and good mechanical integrity. Additionally, the articles of the invention have good shelf life without the need for special packaging. In particular, the invention relates to filament, 3-D printed polyvinylidene fluoride (PVDF) articles, and in particular material extrusion 3-D printing. The articles may be formed from PVDF homopolymers, copolymers, such as KYNAR resins from Arkema, as well as polymer blends with appropriately defined low shear melt viscosity. The PVDF may optionally be a filled PVDF formulation. The physical properties of the 3-D printed articles can be maximized and warpage minimized by optimizing processing parameters.

A composite material may be used as a building material to provide desirable visible aesthetics, such as in a roof or facade. The composite material may include two or more materials, wherein a first material provides desirable qualities for appearance and a second material provides desirable qualities for strength or other characteristics desirable of a building material. Each of the first material and the second material may be transparent, such that the composite material is also transparent. The first material may be Ethylene tetrafluoroethylene (ETFE) and the second material may be Polyethylene terephthalate (PET).

A filter medium includes: a porous substrate; a nanofiber web laminated on both surfaces of the porous substrate, the nanofiber web being formed of accumulated nanofibers made of a polymer material and having a number of fine pores; and a fuse reinforcement material interposed between the nanofiber web and the porous substrate for adhesion with the nanofiber web and the porous substrate integrally. The porous substrate is surrounded by the nanofiber web except for an upper edge of the porous substrate, the upper edge of the porous substrate protrudes with respect to the nanofiber web to form a protruding portion, and the protruding portion is configured to be connected with a discharge hole through which purified water via the porous substrate is discharged.

Methods and apparatus to couple a decorative composite having a reinforcing layer to a panel are disclosed. An example apparatus includes a decorative layer to couple to a panel. The decorative layer including a first tile, a second tile, and an adhesive liner positioned between the first tile and the second tile to couple respective edges of first and second tiles.

A laminate has a substrate layer, an intermediate layer, and a fluorine-based resin layer in this order, and has a total film thickness of 400 m or less, in which a thickness of the fluorine-based resin layer is 20 m or more and 150 m or less and a water vapor permeability of the laminate is 0.5 g/m.sup.2/24 hours or less.

A laminate including a metal substrate having a chemically etched surface and a fluoroelastomer layer laminated in contact with the chemically etched surface or laminated in contact with a surface of a fluororesin layer laminated in contact with the chemically etched surface, and a gate valve including the laminate, are provided.

A filter medium according to one embodiment of the present invention comprises: a first support having a plurality of pores; a nanofiber web comprising nanofibers disposed on upper and lower portions of the first support and forming a three-dimensional network structure, and a hydrophilic coating layer formed on at least a part of an outer surface of the nanofibers, wherein the hydrophilic coating layer is formed of a hydrophilic coating composition comprising a hydrophilic polymer compound having at least one functional group selected from a hydroxyl group and a carboxyl group and a crosslinking agent comprising at least one sulfone group; and a second support having a plurality of pores interposed between the first support and the nanofiber web.

A protective coating layer, an electronic device including such a protective coating layer, and the methods of making the same are provided. The electronic device includes a substrate, a thin film circuit layer disposed over the substrate, and a protective coating layer disposed over the thin film circuit layer. The protective coating layer includes a first coating and a second coating disposed over the first coating. Each coating has a cross-plane thermal conductivity in a direction normal to a respective coating surface equal to or higher than 0.5 W/(m*K). The first coating and the second coating have different crystal structures, or different crystalline orientations, or different compositions, or a combination thereof to provide different nanoindentation hardness. The first coating has a hardness lower than that of the second coating.

A filter apparatus includes: a housing having an inlet for supplying sewage or waste water into the housing, and an outlet for discharging purified water from the housing; and filter media arranged inside the housing. Each of the filter media includes: a porous substrate; a nanofiber web laminated on both surfaces of the porous substrate; and a fuse reinforcement material interposed between the nanofiber web and the porous substrate. The porous substrate is surrounded by the nanofiber web except for an upper edge of the porous substrate to form a protruding portion. The apparatus further includes: a discharge pipe connected to the outlet and including a fixing portion fixed to the protruding portion of the porous substrate and a connection tube connected to the fixing portion and connected to the outlet; and a pump connected to the outlet for pumping the purified water out of the housing.

Methods and apparatus to couple a decorative composite having a reinforcing layer to a panel are disclosed. An example apparatus includes a decorative layer and a first reinforcing layer coupled to the decorative layer. The example apparatus includes a coil reduction layer that is to apply a force to the first reinforcing layer to reduce coiling of the first reinforcing layer. The example apparatus includes an adhesive layer applied to the coil reduction layer that is coupled to the first reinforcing layer to enable the decorative layer to be coupled to a panel. A rigidity of the first reinforcing layer is to enable the first reinforcing layer to distribute a force exerted by at least one of gas or vapor disposed between the first reinforcing layer and the decorative layer to impede separation of a portion of the decorative layer from the panel.