A plurality of carbonation plots are positioned in communication with atmospheric carbon dioxide to facilitate sequestration thereof via ambient weathering. The carbonation plots include a composition rich in metal oxides, which are positioned within the environment, such as on non-arable land, and exposed to the environment to react with carbon dioxide in the air and form metal carbonates. After about one year of exposure, the composition is recollected and calcined to produce a carbon dioxide stream and replenish the metal oxides, which can be redistributed in the carbonation plots to sequester additional carbon dioxide. The systems and methods of the present disclosure enable capture and redistribution of carbon dioxide for industrial-scale uses for very abundant quarry minerals and enable large-scale low-cost carbon capture projects for municipalities or corporations. CO.sub.2 removal from air via these methods and systems have a similar or lower cost than CO.sub.2 removal using DAC with synthetic sorbents or solvents.

A plurality of carbonation plots are positioned in communication with atmospheric carbon dioxide to facilitate sequestration thereof via ambient weathering. The carbonation plots include a composition rich in metal oxides, which are positioned within the environment, such as on non-arable land, and exposed to the environment to react with carbon dioxide in the air and form metal carbonates. After about one year of exposure, the composition is recollected and calcined to produce a carbon dioxide stream and replenish the metal oxides, which can be redistributed in the carbonation plots to sequester additional carbon dioxide. The systems and methods of the present disclosure enable capture and redistribution of carbon dioxide for industrial-scale uses for very abundant quarry minerals and enable large-scale low-cost carbon capture projects for municipalities or corporations. CO.sub.2 removal from air via these methods and systems have a similar or lower cost than CO.sub.2 removal using DAC with synthetic sorbents or solvents.

Method and installation for calcining cement raw meal in a calciner whereby fuel and a calciner oxidant having an oxygen content of at least 30% vol are introduced into the calciner so as to generate either an oxidant-lean zone or a fuel-lean zone in the calciner located between the lowermost fuel inlet level and the lowermost oxidant inlet level of the calciner, between 50% and 100% by weight of the raw meal being supplied to the calciner upstream of and/or within the oxidant-lean, respectively the fuel-lean zone.

Method and installation for calcining cement raw meal in a calciner whereby fuel and a calciner oxidant having an oxygen content of at least 30% vol are introduced into the calciner so as to generate either an oxidant-lean zone or a fuel-lean zone in the calciner located between the lowermost fuel inlet level and the lowermost oxidant inlet level of the calciner, between 50% and 100% by weight of the raw meal being supplied to the calciner upstream of and/or within the oxidant-lean, respectively the fuel-lean zone.

The invention provides a process for regenerating a liquid absorbent, including: contacting the liquid absorbent with a hydrophobic medium, wherein the liquid absorbent includes at least one amine of Formula (I) ##STR00001##
and degradation product thereof including at least one imine of Formula (II), ##STR00002##
wherein each Ar is independently an aromatic group and each R is independently selected from hydrogen, an organyl group and NH2; and selectively extracting the degradation product into or through the hydrophobic medium.

The invention provides a process for regenerating a liquid absorbent, including: contacting the liquid absorbent with a hydrophobic medium, wherein the liquid absorbent includes at least one amine of Formula (I) ##STR00001##
and degradation product thereof including at least one imine of Formula (II), ##STR00002##
wherein each Ar is independently an aromatic group and each R is independently selected from hydrogen, an organyl group and NH2; and selectively extracting the degradation product into or through the hydrophobic medium.

This present invention describes methods and systems for integrating liquid-phase, electrochemical and chemical processes into power generation, petrochemical, metal, cement and other industrial process plants, in such a manner as to capture and recycle all input carbon into cost-competitive hydrogen, oxygen and hydrocarbons. These integrated systems will recover internally generated losses in chemical potential (AG Gibbs Free or Available Energy) as well as waste heat (ΔH—Enthalpy), and sometimes electricity, to assist in driving these electrochemical and chemical processes, which will increase the total useful output of the process plants, thereby increasing thermal, carbon and economic efficiency.

This present invention describes methods and systems for integrating liquid-phase, electrochemical and chemical processes into power generation, petrochemical, metal, cement and other industrial process plants, in such a manner as to capture and recycle all input carbon into cost-competitive hydrogen, oxygen and hydrocarbons. These integrated systems will recover internally generated losses in chemical potential (AG Gibbs Free or Available Energy) as well as waste heat (ΔH—Enthalpy), and sometimes electricity, to assist in driving these electrochemical and chemical processes, which will increase the total useful output of the process plants, thereby increasing thermal, carbon and economic efficiency.

A thermochemical energy storage system and method of storing thermal energy are described. The energy storing system described herein comprises a reactor comprising: a) a reactor with a CO.sub.2 sorbent including MgO; and b) a supercritical CO.sub.2 source with supercritical CO.sub.2 and H.sub.2O, wherein the supercritical CO.sub.2 source is in fluid communication with the reactor and the CO.sub.2 sorbent including MgO to allow flow of the supercritical CO.sub.2 and H.sub.2O between the supercritical CO.sub.2 source and the reactor, thereby allowing contact of CO.sub.2 with the CO.sub.2 sorbent comprising MgO.

A thermochemical energy storage system and method of storing thermal energy are described. The energy storing system described herein comprises a reactor comprising: a) a reactor with a CO.sub.2 sorbent including MgO; and b) a supercritical CO.sub.2 source with supercritical CO.sub.2 and H.sub.2O, wherein the supercritical CO.sub.2 source is in fluid communication with the reactor and the CO.sub.2 sorbent including MgO to allow flow of the supercritical CO.sub.2 and H.sub.2O between the supercritical CO.sub.2 source and the reactor, thereby allowing contact of CO.sub.2 with the CO.sub.2 sorbent comprising MgO.