Perforated graphene sheets can be used in forming separation membranes. Separation membranes of the present disclosure, which can be used in gas separation processes in some embodiments, can include one or more polymer layers and one or more layers of perforated graphene. Methods for separating a gas mixture can include contacting a gas mixture with the separation membranes, and transiting one or more of the gases through the perforated graphene so as to affect separation.

The present disclosure provides a rigid self-supporting MXene separation membrane and a preparation method and use thereof, belonging to the technical field of membranes. In the present disclosure, a MXene material is mixed with an aluminum salt powder to conduct one-step membrane formation by hot-pressing. The pressure forms the powder into a membrane and imparts rigidity, enabling a self-supporting structure; the heating breaks an ionic bond of an inorganic metal salt to reach a molten ionic state, and free metal cations react with active oxygen-containing functional groups on the surface of the MXene to form new chemical bonds (such as an Al—O bond); such a chemical bond has higher energy, achieving a desirable anti-swelling effect to improve the membrane stability. The separation membrane further has excellent conductivity and hydrophilicity.

The invention relates to a porous separation article having a fluoropolymer or polyamide binder interconnecting one or more types of interactive powdery materials or fibers. The interconnectivity is such that the binder connects the powdery materials or fibers in discrete spots rather than as a complete coating, allowing the materials or fibers to be in direct contact with, and interact with a fluid. The resulting article is a formed multicomponent, interconnected web, with porosity. The separation article is useful in water purification, as well as in the separation of dissolved or suspended materials in both aqueous and non-aqueous systems in industrial uses. The separation article can function at ambient temperature, as well as at elevated temperatures.

Synthesis, fabrication, and application of nanocomposite polymers in different form (as membrane/filter coatings, as beads, or as porous sponges) for the removal of microorganisms, heavy metals, organic, and inorganic chemicals from different contaminated water sources.

To provide a filter medium, a process for producing filter medium, a filtration device, a method for operating the filtration device, and a filtration system, which are capable of promptly regenerating the adsorption power by backwashing and realizing efficient operation of a filtration device. The filter medium of the present invention contains a carbon-based material in which a cumulative pore volume of pores having a pore radius of 2 nm or less is 25% or less with respect to a cumulative pore volume of pores having a pore radius of 50 nm or less.

A high-oxidation and NOx-free synthesis of graphene oxide (GO) from natural graphite using the modified Hummers' method is described. The amine-functionalized GO using dodecylamine (DDA) is used as a filler for membranes for the first time. Antifouling and antibacterial properties of UF membranes are achieved using amine functionalization of GO. A process of incorporating raw GO and dodecylamine-functionalized GO (GO-DDA) in polysulfone (PSF) via phase inversion technique is disclosed.

The present invention relates to a composite separation membrane that is applicable to carbon dioxide separation and recovery processes. The composite separation membrane includes a coating layer composed of graphene oxide and a bile acid or its salt on a porous polymer support. The composite separation membrane of the present invention, which includes a coating layer composed of graphene oxide and a bile acid or its salt, has both high carbon dioxide permeability and high selectivity for carbon dioxide over nitrogen, hydrogen or methane gas, is free of surface defects, and maintains a stable structure without deterioration of its performance even after long-term use. Due to these advantages, the composite separation membrane of the present invention can be applied to industrial fields involving carbon dioxide separation and recovery processes. The present invention also relates to a method for manufacturing the composite separation membrane.

Membranes comprising graphene oxide sheets and associated filter media and methods are provided. In some embodiments, a membrane may comprise graphene oxide sheets that have undergone one or more chemical treatments. The chemical treatment(s) may impart beneficial properties to the membrane, such as a relatively small d-spacing, compatibility with a broad range of environments, physical stability, and charge neutrality. For example, the graphene oxide sheets may undergo one or more chemical treatments that form chemical linkages between at least a portion of the graphene oxide sheets in the membrane. Such chemical linkages may impart a small d-spacing, broad compatibility, and/or allow relatively thick membranes to be formed. In certain embodiments, the graphene oxide sheets may undergo one or more chemical treatment that imparts relative charge neutrality to the membrane by altering the ionizability of certain functional groups. Graphene oxide membranes, described herein, can be used for a wide range applications.

New carbon nanomaterials, preferably titanium carbide-derived carbon (CDC) nanoparticles, were embedded into a polyamide film to give CDC/polyamide mixed matrix membranes by the interfacial polymerization reaction of an aliphatic diamine, e.g., piperazine, and an activated aromatic dicarboxylate, e.g., isophthaloyl chloride, supported on a sulfone-containing polymer, e.g., polysulfone (PSF), layer, which is preferably previously prepared by dry/wet phase inversion. The inventive membranes can separate CO.sub.2 (or other gases) from mixtures of CO.sub.2 and further gases, esp. CH.sub.4, based upon the generally selective nanocomposite layer(s) of CDC/polyamide.

Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time.