Patent classifications
B01D71/58
Separation membrane
A separation membrane (10) of the present disclosure includes: a separation functional layer (30) composed of a polyamide containing, as a monomer unit, at least one selected from the group consisting of piperazine and a piperazine derivative; and a coating (40) covering the separation functional layer (30) and containing a polymer having a repeating unit represented by the following formula (1). In the formula (1), N.sup.+ is a nitrogen atom constituting a quaternary ammonium cation, and R.sup.1 and R.sup.2 are each independently a substituent containing a carbon atom bonded to the nitrogen atom. ##STR00001##
Separation membrane
A separation membrane (10) of the present disclosure includes: a separation functional layer (30) composed of a polyamide containing, as a monomer unit, at least one selected from the group consisting of piperazine and a piperazine derivative; and a coating (40) covering the separation functional layer (30) and containing a polymer having a repeating unit represented by the following formula (1). In the formula (1), N.sup.+ is a nitrogen atom constituting a quaternary ammonium cation, and R.sup.1 and R.sup.2 are each independently a substituent containing a carbon atom bonded to the nitrogen atom. ##STR00001##
Isomer separation with highly fluorinated polymer membranes
Separation of linear and branched alkane isomers via selective permeation through a composite membrane is disclosed. The separation layer in the composite membrane is fabricated from a blend of at least two different fluoropolymer compositions, A and B, in which composition A has a normal-alkane isomer permeability that is greater than composition B. Composition B has a normal alkane to branched-alkane isomer selectivity that is equal or greater than composition A. The separation layer in the composite membrane has a normal-alkane permeability that is greater than composition B and a normal-alkane to branched alkane isomer selectivity that is greater than composition A.
Isomer separation with highly fluorinated polymer membranes
Separation of linear and branched alkane isomers via selective permeation through a composite membrane is disclosed. The separation layer in the composite membrane is fabricated from a blend of at least two different fluoropolymer compositions, A and B, in which composition A has a normal-alkane isomer permeability that is greater than composition B. Composition B has a normal alkane to branched-alkane isomer selectivity that is equal or greater than composition A. The separation layer in the composite membrane has a normal-alkane permeability that is greater than composition B and a normal-alkane to branched alkane isomer selectivity that is greater than composition A.
METHOD OF PREPARATION OF CONDUCTIVE POLYMER/CARBON NANOTUBE COMPOSITE NANOFILTRATION MEMBRANE AND THE USE THEREOF
A method for preparation of conductive polymer/carbon nanotube (CNT) composite nanofiltration (NF) membrane and the use thereof. This conductive polymer/CNT composite NF membrane is obtained by polymerizing conductive polymer into a CNT membrane and then in-situ cross-linking with glutaraldehyde under acidic condition. The synthetic method for the conductive polymer/CNT composite NF membrane is simple and has no need of expensive equipment. The prepared membrane has controllable membrane structure and possesses superior electrical conductivity and electrochemical stability. The membrane can couple with electrochemistry for electrically assisted filtration. With the electrical assistance, the membrane can achieve improved ion rejection performance while retaining high permeability by enhancement of membrane surface charge density, which alleviates the permeability-selectivity trade-off. Furthermore, the electrically assisted NF membrane filtration can also enhance the removal for small molecular organic pollutants.
Ionic polyamide and polyamide-imide materials and methods of use
Disclosed are compositions and methods of preparing ionic polyamides. Also disclosed are compositions and methods of preparing ionic polyamide-imides. Additionally, disclosed herein are compositions comprising the ionic polyamides or polyamide-imides. The compositions comprising the ionic polyamides or polyamide-imides can include an ionic liquid. The disclosed polyamides and polyamide-imides can be utilized for three-dimensional printing or to capture gases.
Crosslinked polyphosphazene blends for gas separation membranes
The disclosed invention relates to a composition comprising a crosslinked blend of polyphosphazene polymers. The composition comprises a first polyphosphazene and a second polyphosphazene, where the first polyphosphazene and the second polyphosphazene being bound by a thiol bearing crosslinking agent. Such compositions are useful as a membrane material for the separation of gasses in a gaseous mixture.
Crosslinked polyphosphazene blends for gas separation membranes
The disclosed invention relates to a composition comprising a crosslinked blend of polyphosphazene polymers. The composition comprises a first polyphosphazene and a second polyphosphazene, where the first polyphosphazene and the second polyphosphazene being bound by a thiol bearing crosslinking agent. Such compositions are useful as a membrane material for the separation of gasses in a gaseous mixture.
Gel including condensation product of organic silicon compound
The present invention provides a gel containing a crosslinked polymer having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, and a condensate of a compound represented by the following formula (I): Si{R.sup.1N(R.sup.2)(R.sup.3)}(OR.sup.4)(OR.sup.5)(R.sup.6) (wherein each group is as defined in the DESCRIPTION).
PROCESS FOR MAKING MEMBRANES
The invention provides a filtration membrane which comprises a porous support and, covalently bonded to a surface thereof, a layer comprising a plurality of vesicles having transmembrane proteins incorporated therein, said vesicles being formed from an amphiphilic block copolymer; characterised in that within said layer, vesicles are covalently linked together to form a coherent mass. The membrane may be prepared by a process which comprises providing an aqueous suspension of vesicles having transmembrane proteins incorporated therein, said vesicles being formed from an amphiphilic block copolymer having reactive end groups; depositing said suspension of vesicles on a surface of a porous support; and providing reaction conditions such that covalent bonds are formed between different vesicles and between vesicles and said surface.