A method for capturing CO.sub.2 comprising dissolving at least one pure amino acid (AA) in water without the use of a catalyst for establishing protonation of an amino group of the amino acid, adding at least one base solution to the amino acid and water solution to deprotonate the protonated amino group of the amino acid and forming an amino acid-XOH—H.sub.2O wherein X is sodium or potassium, and subjecting CO.sub.2 to the amino acid-XOH—H.sub.2O to form new nanomaterials is provided. A regenerable nanofiber is disclosed comprising a NaHCO.sub.3 nanofiber, a KHCO.sub.3 nanofiber, or an amino acid nanofiber made from subjecting a CO.sub.2 gas to an amino acid aqueous solvent. Preferably, the amino acid aqueous solvent is one or more of a Gly-NaOH—H.sub.2O, an Ala-NaOH—H.sub.2O, a Phe-NaOH—H.sub.2O, a Gly-KOH—H.sub.2O, an Ala-KOH—H.sub.2O, and a Phe-KOH—H.sub.2O.

Novel methods for pretreating a rare-gas-containing stream exiting an etch chamber followed by recovering the rare gas from the pre-treated, rare-gas containing stream are disclosed. More particularly, the invention relates to the pretreatment and recovery of a rare gas, such as xenon or krypton, from a nitrogen-based exhaust stream with specific gaseous impurities generated during an etch process that is performed as part of a semiconductor fabrication process.

A system for capturing CO.sub.2 gas comprising: a gaseous feed stream having an initial concentration of the CO.sub.2 gas; wherein the gaseous feed stream is provided to a first reactor as a gaseous reaction stream; the first reactor comprising a sorbent composition and the gaseous reaction stream flowing therein, the gaseous reaction stream being in contact with the sorbent composition; and a first gaseous output stream having a concentration of CO.sub.2 being less than the initial concentration of CO.sub.2; wherein: the gaseous reaction stream comprises the CO.sub.2 gas and is characterized by a relative humidity of at least 5%; the sorbent composition comprises a metal carbonate material that reacts with the CO.sub.2 gas of the gaseous reaction stream thereby reducing CO.sub.2 gas concentration; and the first reactor comprises 35 wt. % or less of liquid water by weight of sorbent and liquid water.

A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.

Methods and systems for bioremediation of heavy metal contaminants in waste materials (e.g., sludge and combustion wastes from a coal-fixed power plant). The systems described in the present application include at least one waste treatment unit (e.g., a flue gas cleaner or a waste lagoon) that includes one or more selected bacterial strains disposed therein consume and/or reclaim at least a portion of the heavy metal in the combustion wastes. Methods include inoculating a waste treatment unit with one or more selected bacteria that consume and/or reclaim at least a portion of the heavy metal in the combustion wastes. Methods may include periodic reinoculation of the waste treatment unit with fresh bacteria and period recovery of the bacteria from the waste treatment unit.

The mixing nozzle has a throat section, a diffuser section, a gas nozzle section, a first liquid suction port, a liquid nozzle section, a second liquid suction port, a baffle plate, and a jetting port. The first liquid suction port liquidly absorbs the solution in the water storage pool from a side of the gas nozzle section toward the gas nozzle tip. The liquid nozzle section extends to the downstream side of the gas nozzle section with intervening the first liquid suction port. The second liquid suction port liquidly absorbs the solution in the water storage pool from a side of the liquid nozzle section toward the liquid nozzle tip. The baffle plate is provided such that the mixed flow mixed in the diffuser section collides in front of a downstream end of the diffuser section, and divides and reverses the mixed flow.

A catalyst for decomposing perfluorinated compounds includes an alumina carrier, at least one metal carried on the alumina carrier and selected from the group consisting of Zn, Ni, W, Zr, Ti, Ga, Nb, Co, Mo, V, Cr, Mn, Fe, and Cu, S carried on the alumina carrier, and rare-earth metals carried on the alumina carrier.

A gas purification agent includes an electronegative film-forming agent and a foaming agent. The electronegative film-forming agent accounts for 20-80 wt % of the gas purification agent, while the foaming agent accounts for 20-80 wt % of the gas purification agent. The gas purification agent of such a composition can be used as a haze removing agent to effectively remove fine dust particles such as PM10 and PM2.5 from the air. The gas purification agent includes 2.5-25 wt % of the electronegative film-forming agent, 2.5-25 wt % of the foaming agent, and 50-95 wt % of a desulfurizing agent. The gas purification agent of such a composition can be used as a desulfurizing agent to remove sulfur-containing compounds from industrial exhaust gases. A method for using the gas purification agent is also provided.

A system and a method for industrial plant or utility plant flue gas desulfurization, with zero waste water liquid discharge from a wet flue gas desulfurization system utilized therein, are disclosed herein. The wet flue gas desulfurization system is supplied an absorption liquid for contact with a flue gas to absorb flue gas acid gases. Waste water from the wet flue gas desulfurization system is heated under pressure in a heat exchanger to produce heated waste water, which is supplied to a flash vessel to produce steam. The produced steam is supplied to the flue gas upstream of a particulate collection system and the wet flue gas desulfurization system, supplied to the flue gas upstream of the wet flue gas desulfurization system, or supplied to absorption liquid circulated to the wet flue gas desulfurization system.

A method for removing a halogen fluoride in a mixed gas by reacting the mixed gas containing a halogen fluoride including bromine or iodine with a removing agent, wherein the removing agent is a chloride, bromide or iodide of potassium, sodium, magnesium, calcium and barium. Also disclosed is a quantitative analysis method as well as a quantitative analyzer for a gas component contained in a hydrogen fluoride mixed gas, the method characterized by reacting a mixed gas containing a halogen fluoride and another gas component with a removing agent, thereby removing the halogen fluoride in the mixed gas, further removing produced by-products, and quantitatively analyzing a residual gas by a gas chromatograph.