Disclosed herein is a system for purifying air; for the capture of solid residues (soot), and the transformation of CO.sub.x and NO.sub.x (and even methane) present in contaminated air generated by industrial combustion.

The purifying air system comprises an air entrance (c); a first module (A), made up of mechanical filters; a second module (B), downwards from the first module (A), and it corresponds to a series of small reactors with molecular converters (nucleophile chemical agents) to capture and transform carbon oxides (CO.sub.x) and nitrogen oxides (NO.sub.x); and an exit for decontaminated air (D).

A method and composition of matter for detecting and decontaminating hazardous chemicals, the composition of matter including: a magnetic material for any of chemisorbing, molecularly dissociating, or decomposing a hazardous chemical, wherein the magnetic material changes its magnetic moment upon any of chemisorption, decomposition, and molecular dissociation of the hazardous chemical and the change in magnetic moment is used to detect the presence of the hazardous chemical, and wherein the hazardous chemical includes any of toxic industrial chemicals, chemical warfare agents, and chemical warfare agent related compounds.

The application provides an oxide layer material capable of adsorbing and degrading methane gas, which is obtained by a method comprising the steps of: 1) subjecting a cracked household refuse to aerobic biological pretreatment; 2) subjecting the material which has been subjected to the aerobic biological pretreatment to biological stabilizing treatment; and 3) adding copper chloride, potassium sulfate, magnesium oxide, and a composite bacterial agent for oxidizing methane gas to the material which has been subjected to the biological stabilizing treatment to obtain the oxide layer material capable of adsorbing and degrading methane gas. This disclosure further discloses a method for preparing the oxide layer material capable of adsorbing and degrading methane gas described above.

Industrial waste derived adsorbents were obtained by pyrolysis of sewage sludge, metal sludge, waste oil sludge and tobacco waste in some combination. The materials were used as media to remove hydrogen sulfide at room temperature in the presence of moisture. The initial and exhausted adsorbents after the breakthrough tests were characterized using sorption of nitrogen, thermal analysis, XRD, ICP, and surface pH measurements. Mixing tobacco and sludges result in a strong synergy enhancing the catalytic properties of adsorbents. During pyrolysis new mineral phases are formed as a result of solid state reaction between the components of the sludges. High temperature of pyrolysis is beneficial for the adsorbents due to the enhanced activation of carbonaceous phase and chemical stabilization of inorganic phase. Samples obtained at low temperature are sensitive to water, which deactivates their catalytic centers.

Disclosed are processes for removing H.sub.2S from gas streams containing H.sub.2S, the processes comprise contacting gas streams with a mixed metal oxy-hydroxide media comprising two or more metals selected from the group consisting of magnesium, chromium, manganese, iron, cobalt, zinc and copper. Also disclosed are processes for removing H.sub.2S from gas streams containing H.sub.2S, the processes comprise contacting the gas streams with a mixed metal oxy-hydroxide media comprising one or more metals selected from the group listed above plus one or more metals selected from the group consisting of aluminum, silicon, titanium and zirconium.

A filtration device including a fluid-impermeable housing having a gas inlet and outlet, and containing within the housing first filter media particles of an extended surface area substrate and containing at least one metal impregnant, and second filter media particles of an extended surface area zirconium hydroxide substrate and containing zinc (hydr)oxide. The first or second filter media particles also contain an amine-functional material. The device may be used in atmospheres containing various harmful gases, and may provide particularly useful improvements in breakthrough times for nitrogen dioxide, hydrogen sulfide, ammonia and formaldehyde compared to a device containing only the first filter media particles or only the second filter media particles.

An ammonia chemical species desorption process desorbs ammonia chemical species adsorbed onto a Prussian blue derivative more simply at lower cost under milder conditions as compared with using an aqueous solution of a salt or strong acid, and only water. This ammonia chemical species desorption process includes an ammonia chemical desorption step of bringing carbon dioxide and water into contact with a Prussian blue derivative represented by the following general formula (1), thereby desorbing an ammonia chemical species.

A.sub.xM[M′(CN).sub.6].sub.y.zH.sub.2O  (1)

where x is 0 to 3, y is 0.1 to 1.5, z is 0 to 6, A is at least one cation of hydrogen, ammonium, an alkaline metal, and an alkaline earth metal, and M and M′ are each independently at least one cation of at least one of atoms having atomic numbers 3 to 83 except for ammonium, an alkali metal, and an alkaline earth metal.

This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.

Sealed LED lighting fixtures operated under certain conditions (e.g., outdoors, in cold ambient environments, at high operating current, and/or in non-hermetic environments) will oftentimes exhibit condensation on an inner surface of the emitting face of the fixture. When occurring, said condensation impairs the ability to produce useful light—namely, light harnessed and directed in a manner so to provide lighting for a task (or otherwise desired)—by diffusing light emitted from the lighting fixture. Envisioned are apparatus, methods, and systems to reduce moisture in sealed LED lighting fixtures so to reduce or eliminate condensation, and in a manner that addresses both fixtures already in the field and those being assembled.

The disclosure relates to the field of heavy metal adsorbents, and a heterogeneous agglomeration adsorbent for heavy metal adsorption, a method for preparing the same, and applications are provided. The heterogeneous agglomeration adsorbent includes the following components according to percentage by weight: 0.005% to 0.01% of polyacrylamide, 0.0005% to 0.001% of calcium chloride, 0.001% to 0.01% of coconut oil fatty acid diethanolamide, and a balance is water.