The invention relates to dispersions of porous solids in liquids selected from deep eutectic solvents, liquid oligomers, bulky liquids, liquid polymers, silicone oils, halogenated oils, paraffin oils or triglyceride oils, as well as to their methods of preparation. In embodiments of the invention, the porous solids are metal organic framework materials (MOFs), zeolites, covalent organic frameworks (COFs), porous inorganic materials, Mobil Compositions of Matter (MCMs) or a porous carbon. The invention also relates to the use of porous materials to form dispersions, and to assemblages of such dispersions with a gas or gases. The dispersions can exhibit high gas capacities and selectivities.

A gas-permeable element configured to close a receptacle base containing an active material, wherein the receptacle includes the receptacle base and the gas-permeable element. The gas-permeable element includes a body, having a base wall, including at least one opening. For each opening of the base wall, the body includes a tubular projection projecting from a periphery of the opening. The tubular projection includes a first end, connected to the periphery of the opening, a second end, defining a distal edge surface transverse to a longitudinal axis of the tubular projection. A porous membrane portion extends across the second end of the tubular projection while attached to the distal edge surface at its periphery.

Systems and methods are provided for separation of CO.sub.2 from dilute source streams. The systems and methods for the separation can include use of contactors that correspond radial flow adsorbent modules that can allow for efficient contact of CO.sub.2-containing gas with adsorbent beds while also facilitating use of heat transfer fluids in the vicinity of the adsorbent beds to reduce or minimize temperature variations. In particular, the radial flow adsorbent beds can be alternated with regions of axial flow heat transfer conduits to provide thermal management. The radial flow structure for the adsorbent beds combined with axial flow conduits for heat transfer fluids can allow for sufficient temperature control to either a) reduce or minimize temperature variations within the adsorbent beds or b) facilitate performing the separation using temperature as a swing variable for controlling the working capacity of the adsorbent.

Described herein is a an adsorbent and/or absorbent composition, a method of preparing the adsorbent and/or absorbent composition, and method of treating a fluid stream with the adsorbent and/or absorbent composition. Alumina and carbon are combined with polyacrylamide (PAM) powder and water in preferred proportions and impregnates such as Group 1A metal hydroxides. Group 7A salts of Group 1A metals optionally can be added.

The present disclosure relates to a solid adsorbent for capturing carbon dioxide (CO.sub.2) from a gas stream comprising CO.sub.2, the solid adsorbent comprising an amine covalently bonded to a polymer resin (e.g., a polystyrene resin), wherein the solid adsorbent has a CO.sub.2 uptake capacity of greater than about 7 wt. % at a temperature of about 40° C., and wherein the solid adsorbent has a CO.sub.2 uptake capacity of less than about 1.5 wt. % at a temperature of about 100° C., as measured when the gas stream further comprises a concentration of the CO.sub.2 of about 4 vol. %, by volume of the gas stream.

An ink for three dimensional printing a ceramic material includes metal oxide nanoparticles and a polymer resin, where a concentration of the metal oxide nanoparticles is at least about 50 wt % of a total mass of the ink. A method of forming a porous ceramic material includes obtaining an ink, where the ink comprises a mixture of metal oxide nanoparticles and a polymer, forming a body from the ink, curing the formed body, heating the formed body for removing the polymer and for forming a porous ceramic material from the metal oxide nanoparticles. The forming the body includes an additive manufacturing process with the ink.

Porous solid amine adsorbents are prepared by bringing into contact a first (e.g., dope) solution, including a water insoluble polymer and a water-soluble amine polymer, with an aqueous solution containing a multifunctional chemical agent. The first solution can be obtained by dissolving the water insoluble polymer and the water-soluble amine polymer in a polar solvent. The adsorbents can be in the form of beads, sheets, fibers, hollow fibers, etc. and can be used in the removal of acid gases, CO.sub.2, for instance, from fluid streams.

Coating compositions and methods for using the same are disclosed. The coating compositions can include an aminosilica adsorbent. The coating compositions can adsorb CO.sub.2.

Sorbent materials comprising a nanofiber composite including a polymeric material defining a continuous phase and at least one metal organic framework (MOF) material defining a discontinuous phase are provided. The at least one MOF material is dispersed throughout the continuous phase of the polymeric material. Fibrous mats comprising the sorbent materials are also provided. Water harvesting devices utilizing the sorbent materials are also provided.

Some embodiments of the disclosure correspond to, for example, a method for controlling a scrubber containing an adsorbent. The scrubber may be configured to cycle between scrubbing at least one pollutant/gas from a stream of gases with the pollutant/gas being adsorbed onto the adsorbent, and regenerating at least some of the adsorbent and thereby purging at least some of the one pollutant and/or first gas from the adsorbent via a regeneration gas flow. The method may include flowing a stream of gases through the scrubber, the scrubber including the adsorbent and adsorbing at least some of the one pollutant/gas from the stream of gases onto the adsorbent during an adsorption phase over a first time period. The method may also include purging at least a portion of the one pollutant/gas from the adsorbent during a regeneration phase over a second time period with a regeneration gas flow, and cycling therebetween.