Patent classifications
B01D2255/92
METHOD FOR PRODUCING CATALYST FIBROUS STRUCTURE
A catalyst fibrous structure having a catalyst metal carried on a fibrous structure, wherein (a) a Log differential micropore volume distribution curve thereof obtained by measurement using a mercury intrusion technique has a peak having a maximum micropore diameter in the range of from 0.1 μm to 100 μm; (b) a Log differential micropore volume at the peak is 0.5 mL/g or more; and (c) an amount of a catalyst metal compound and a binder carried per unit volume is 0.05 g/mL or more. A production method for producing a catalyst fibrous structure having: (1) mixing a catalyst metal compound or a catalyst precursor, and an inorganic binder and a solvent; (2) grinding the mixture to obtain a coating material of the catalyst metal compound or the catalyst precursor having a median particle diameter of 2 μm or less and a viscosity of from 10 mPa.Math.s to 200 mPa.Math.s; (3) impregnating a fibrous structure with the coating material to fill up voids of the fibrous structure with the coating material of the catalyst metal compound or the catalyst precursor; (4) heating and drying the fibrous structure, directly as it is, at a temperature not lower than the boiling point of the solvent; and (5) heating and calcination the dried fibrous structure at a temperature not lower than the dehydration temperature of the inorganic binder to obtain a catalyst fibrous structure.
EXHAUST GAS PURIFICATION CATALYST
An exhaust gas purification catalyst is provided for which a purification performance is excellent and particle growth of a catalyst metal is suppressed. The exhaust gas purification catalyst is provided with a substrate and a catalyst layer formed on the substrate. The catalyst layer contains a catalyst metal that functions as an oxidation and/or reduction catalyst and contains a support that supports the catalyst metal. The support is constituted of a porous ceramic that, in its volumetric pore diameter distribution measured based on a nitrogen gas adsorption method, has a pore diameter P.sub.10 corresponding to a cumulative 10% from a small pore side and a pore diameter P.sub.90 corresponding to a cumulative 90% from the small pore side that are both in a range from 5 to 50 nm.
Carbon capture
The present invention relates to the use of solid metal materials for catalyzing the hydration of carbon dioxide. It also relates to methods of and apparatus for hydrating carbon dioxide and capturing carbon. The solid metal materials may be nickel nanoparticles. The invention finds particular application in the sequestration of carbon dioxide either at the point of release or from the atmosphere.
CATALYST FOR EXHAUST GAS PURIFICATION
When sizes of particles supporting a catalyst metal remain relatively large but sizes of particles not supporting a catalyst metal are minimized among metal oxide particles included in a catalyst coating layer, it is possible to decrease a thickness of the catalyst coating layer while maintaining durability and improve gas diffusibility of the coating layer. Therefore, a thickness of the catalyst coating is decreased without decreasing durability and a catalyst can exhibit high exhaust gas purification performance even under high load conditions.
HIGH METALS CONTENT HYDROLYSIS CATALYST FOR USE IN THE CATALYTIC REDUCTION OF SULFUR CONTAINED IN A GAS STREAM, AND A METHOD OF MAKING AND USING SUCH COMPOSITION
Disclosed is a composition useful in the hydrolysis of sulfur compounds that are contained in a gas stream. The composition comprises a calcined co-mulled mixture of psuedoboehmite, a cobalt compound, and a molybdenum compound such that the composition comprises gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt. The composition is made by forming into an agglomerate a co-mulled mixture pseudoboehmite, a cobalt component, and a molybdenum component followed by drying and calcining the agglomerate to provide a catalyst composition comprising gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt.
Particulate filter
Provided is a particulate filter in which a PM collection rate is stably increased. The particulate filter according to the present invention includes a substrate 10 having a wall flow structure having a porous partition wall 16 that partitions an inlet cell and an outlet cell, and a wash coat layer held on surfaces of internal pores of the partition wall. In addition, average filling rates A, B, and C of the wash coat layer measured for each predetermined pore diameter range in the internal pores satisfy specific relationships. Further, the wash coat layer is formed in a region that occupies 50% or more of a thickness of the partition wall, and an amount of a noble metal catalyst carried by the wash coat layer is 0 g/L or more but 0.2 g/L or less.
CATALYST MODULES AND APPLICATIONS THEREOF
In one aspect, catalyst modules and catalytic reactors are provided which, in some embodiments, mitigate inefficiencies and/or problems associated with fluid stream pressure drop A catalyst module comprises a layer of structural catalyst bodies arranged in a pleated format, the structural catalyst bodies forming pleat inlet faces and pleat outlet faces, wherein fluid flow channels defined by inner partition walls of the structural catalyst bodies extend from the pleat inlet faces to the pleat outlet faces. The pleat inlet faces form an angle (δ) with an inlet face of the module.
HONEYCOMB BODY AND PARTICULATE FILTER COMPRISING A HONEYCOMB
A particulate filter having a porous ceramic honeycomb structure with a first end, a second end, and a plurality of walls having wall surfaces defining a plurality of inner channels. Filtration material deposits are disposed on one or more of the wall surfaces of the honeycomb body. The highly porous deposits provide durable high clean filtration efficiency with small impact on pressure drop through the filter.
Dinuclear rhodium complex-doped platinum/hollow mesoporous silica sphere composite material, and preparation method and application thereof
The invention discloses a dinuclear rhodium complex-doped platinum/hollow mesoporous silica sphere composite material, and a preparation method and an application thereof. The preparation method comprises the following steps: preparing hollow mesoporous silica by a selective etching technology, uniformly distributed a precious metal platinum in the channels of the hollow mesoporous silica by using simple impregnation, and mixing the obtained catalyst with dinuclear rhodium complex adsorbed silica gel to obtain the composite material integrating a chromogenic probe with the catalyst. The preparation method is simple, and the chromogenic performance of the dinuclear rhodium complex material and catalysis performance of the catalyst can achieve simultaneous detection and catalyst of CO; and the dinuclear rhodium complex has obvious response to CO, and has chromogenic change in the presence of 50 ppm CO, and the product prepared through the preparation method has excellent CO detection and treatment properties, and highly facilitates industrial application.
PARTICULATE FILTER
Provided is a particulate filter in which a PM collection rate is stably increased. The particulate filter according to the present invention includes a substrate 10 having a wall flow structure having a porous partition wall 16 that partitions an inlet cell and an outlet cell, and a wash coat layer held on surfaces of internal pores of the partition wall. In addition, average filling rates A, B, and C of the wash coat layer measured for each predetermined pore diameter range in the internal pores satisfy specific relationships. Further, the wash coat layer is formed in a region that occupies 50% or more of a thickness of the partition wall, and an amount of a noble metal catalyst carried by the wash coat layer is 0 g/L or more but 0.2 g/L or less.