A polymer blend membrane includes a polyether-based copolymer and a polyether polymerized in situ and has high permeability and high selectivity for carbon dioxide. In the polymer blend membrane, the free volume of the polyether-based copolymer is greatly increased, and the adsorption capacity for carbon dioxide is enhanced. Thus, it can have excellent mechanical properties and excellent permeability and selectivity for carbon dioxide.

A hybrid crosslinked polymeric membrane and a process for fabricating the same are provided. Specifically, the hybrid crosslinked polymer membrane comprises a glassy polymer and a ladder-structured polysilsesquioxane and has a crosslinked structure. The hybrid crosslinked polymer membrane can have an excellent permeability of carbon dioxide by virtue of an increase in the free volume and enhanced plasticization resistance, chemical resistance, and durability.

A method to dry a gas stream that includes methane and condensable components that have a lower boiling point than methane by: combining the gas stream with a cold liquid stream in a gas mixer to produce a mixed stream that is colder than the gas stream and to condense a first portion of the condensable components; passing the mixed stream through a first separator to remove the condensed first portion and obtain a second gas stream; lowering a pressure and temperature of the second gas stream in an expansion device to obtain a third gas stream and condense a second portion of the condensable components; passing the third gas stream through a second separator to remove the condensed second portion and obtain a dried gas stream; and recirculating at least a portion of the condensed second portion into the in-line gas mixer as the cold liquid stream.

A carbon molecular sieve (CMS) membrane having improved separation characteristics for separating olefins from their corresponding paraffins is comprised of carbon with at most trace amounts of sulfur and a group 13 metal. The CMS membrane may be made by pyrolyzing a precursor polymer devoid of sulfur in which the precursor polymer has had a group 13 metal incorporated into it, wherein the metal is in a reduced state. The pyrolyzing for the precursor having the group 13 metal incorporated into it is performed in a nonoxidizing atmosphere and at a heating rate and temperature such that the metal in a reduced state (e.g., covalently bonded to carbon or nitrogen or in the metal state).

Facility and method for membrane permeation treatment of a feed gas stream containing at least methane and carbon dioxide including first, second, and third membrane separation units each including at least one membrane that is more permeable to carbon dioxide than to methane, wherein a permeate from the first membrane separation unit is fed to the third membrane separation unit and a retentate from the first membrane separation unit is fed to the second membrane separation unit. A compressor B adjusts the third-permeate suctioning pressure as a function of the feed gas stream pressure and the second retentate methane concentration.

A novel adsorbent and contactor material based on polymer functionalized with amidoxime and alkylamines moieties. Methods of making the material are also described. The material can be easily processed into any desired sorbent geometry such as solid fibers, electrospun fibers, hollow fibers, monoliths, etc. The adsorbent exhibits a very high affinity toward acidic gases such CO.sub.2 and can be used in direct air capture, power plant-based CO.sub.2 capture, and industrial CO.sub.2 capture applications. The material can also serve as a contactor that accommodates other adsorbents within its structure.

A natural gas processing system is mounted on a mobile platform that is transported to a natural gas source, such as a well. The system supplies retentate gas to operate multi-fuel engines for wellfield equipment such as pumps, compressors, and drills. A liquid drain discharges contaminants. A separator, first and second coalescing filters, and a particulate filter remove particulate matter and fluid contaminant matter from the natural gas. A dryer removes water vapor from the natural gas. Dual membranes separate the natural gas into a retentate gas and a permeate gas. A first heat exchanger adjusts temperature of the natural gas entering the membranes. A second heat exchanger adjusts temperature of the retentate gas output. A thermoelectric generator powered by the natural gas supplies process electricity. A process control monitors and controls the natural gas processing system, including pressure control valves, temperature control valves, and emergency shutdown systems. An instrument gas supply with an accumulator supplies gas pressure to operate pneumatic valves and instruments.

The invention relates to a process and apparatus for separation of gas mixtures with reduced maintenance costs. The process and the apparatus consist of a feed stream separation stage (1), and a retentate separation stage (2), of which both are membrane separation stages, wherein the first retentate stream (7) is heated to temperature higher than the temperature of the feed stream (5), before it is introduced to the retentate separation stage (2), and the total capacity of the membranes used in the retentate separation stage (2) is higher than the total capacity of the membranes used in the feed stream stage (1).

A method of purifying gaseous mixtures, for example ternary or quaternary gaseous mixtures, using a sorbent media comprising two or more sorbent materials. The method involves obtaining a target gas from a gaseous composition comprising the target gas, a first gas and a second gas, and optionally further gases by contacting the gaseous composition with the sorbent media to remove at least some of the first gas and at least some of the second gas from the gaseous composition. The sorbent media comprises at least a first sorbent material and a second sorbent material; wherein the first sorbent material has a higher adsorption selectivity for the first gas than for the target gas; and wherein the second sorbent material has a higher adsorption selectivity for the second gas than for target gas. The method may be particularly useful for the separation of pure ethylene, methane or propylene from such gaseous mixtures. A sorbent media and an apparatus for obtaining a target gas from such a gaseous composition are also disclosed.

A gas processing system for recovering methane gas from a landfill includes a high pressure main absorber plus a relatively low pressure one. The low pressure absorber receives a gas stream from an equally low pressure flash tank. This low pressure gas stream consists mostly of carbon dioxide and methane. The methane would normally be lost due to the high cost of recompressing the carbon dioxide, but by running this mixture of carbon dioxide and methane through the low pressure absorber with a slip stream of cold absorbent, a large portion of the carbon dioxide can be removed with negligible methane losses. The remaining methane can be recycled through the high pressure main absorber without having to recompress the removed portion of carbon dioxide.