Disclosed is a system and method for cooperatively treating water and gas to reduce pollutants and carbon emission. The system includes a flue gas pre-treatment unit, a wastewater pre-treatment unit, a gas-water cooperative cleaning unit, a remaining water treatment unit, and a circulating cooling evaporation unit.

Methods and systems for recovering sulfur dioxide from a Claus unit process emissions stream are provided. The method comprises the steps of generating a process emissions stream from a thermal oxidizer or other combustion device, introducing the emissions stream to an SO.sub.2 removal system, introducing the SO.sub.2 rich stream from the SO.sub.2 removal system to a CO.sub.2 removal system, and introducing an enriched SO.sub.2 stream back to the Claus unit. The SO.sub.2 removal system can include one or more SO.sub.2 selective membranes. The CO.sub.2 removal system can include one or more CO.sub.2 selective membranes.

Some embodiments of the disclosure correspond to, for example, a method for controlling a scrubber containing an adsorbent. The scrubber may be configured to cycle between scrubbing at least one pollutant/gas from a stream of gases with the pollutant/gas being adsorbed onto the adsorbent, and regenerating at least some of the adsorbent and thereby purging at least some of the one pollutant and/or first gas from the adsorbent via a regeneration gas flow. The method may include flowing a stream of gases through the scrubber, the scrubber including the adsorbent and adsorbing at least some of the one pollutant/gas from the stream of gases onto the adsorbent during an adsorption phase over a first time period. The method may also include purging at least a portion of the one pollutant/gas from the adsorbent during a regeneration phase over a second time period with a regeneration gas flow, and cycling therebetween.

A method for desulfurizing and decarbonizing a flue gas includes: feeding a boiler flue gas after denitrating and dedusting to a water cooler; cooling the boiler flue gas in the water cooler to a temperature near room temperature, and discharging condensed water; feeding a wet flue gas to a washing tower; washing and cooling the wet flue gas with a washing liquid to separate H.sub.2O, SO.sub.2 and CO.sub.2 in a solid form from the flue gas; feeding a solid-liquid mixed slurry from a bottom of the washing tower to a solid-liquid separator to separate solid H.sub.2O, SO.sub.2 and CO.sub.2 from the washing liquid; feeding the solid H.sub.2O, SO.sub.2 and CO.sub.2 to a rectification separation column; separating CO.sub.2 from SO.sub.2 and H.sub.2O by a reboiler at a bottom of the rectification separation column; and discharging CO.sub.2, SO.sub.2 and H.sub.2O.

The present disclosure relates to a spray apparatus for improving the performance of a rectangular-shaped scrubber which may efficiently remove harmful substances in a gas by mounting an injector for spraying a liquid in a rectangular pyramid shape on a scrubber having a rectangular shape. The spray apparatus includes: a scrubber having a rectangular shape; and an injector mounted on the scrubber and including a spray nozzle configured to spray a liquid in a rectangular pyramid shape.

A gas separation apparatus includes a separation membrane module including at least one gas separation membrane element in a housing, a casing for blocking external air, and a heat source unit for adjusting a temperature of a heat medium with which the casing is filled. The casing holds greater than or equal to two separation membrane modules.

The present invention discloses a method for ammonium-enhanced flue gas desulfurization (FGD) by using red mud slurry. The method specifically includes: crushing red mud, sieving the crushed red mud, slurrying the red mud, conducting aeration treatment, adding an ammonium salt and/or ammonia, and conducting natural sedimentation to obtain pretreated red mud slurry and pretreated red mud liquor; adding an ammonium salt and/or ammonia to the slurry, adding water and conducting uniform mixing, conducting pre-FGD, conducting deep desulfurization on treated flue gas by using the pretreated red mud liquor, and directly discharging desulfurized flue gas; and charging the pretreated red mud slurry and the pretreated red mud liquor obtained after the treatment to a replacement tank below, adding lime milk to the replacement tank, conducting stirring and natural sedimentation, conducting soilization on subnatant thick red mud slurry, and refluxing the supernatant to a red mud aeration tank.

Various embodiments disclosed relate to extraction of target materials using a CZTS sorbent. A method of extracting a target material from a medium includes contacting a copper zinc tin sulfur (CZTS) sorbent with the target material in the medium including the target material to form a used CZTS sorbent that includes the target material.

This process comprises quenching and washing with water a gas stream derived from pyrolysis, and separating an aqueous phase from a washed gas stream; compressing, then cooling a washed gas stream; washing the compressed gas stream under pressure; passing the washed gas stream through at least one acid removal unit; drying the acid-depleted gas stream; passing the dry gas stream through at least one impurity removal unit; and feeding the purified gas stream into a cryogenic absorption unit and supplying the cryogenic absorption unit with a hydrocarbon cryogenic solvent to obtain a light gas residue, and a fraction of C.sub.2.sup.+ hydrocarbons.

Apparatus and methods for treating acid gas, which utilizes multi-stage absorption cycle of ammonia desulfurization to treat acid tail gas after pre-treatment of the acid gas, thereby achieving the purpose of efficient and low-cost treatment of acid tail gas. The parameters of the acid tail gas may be adjusted by a regulatory system such that the enthalpy value of the acid tail gas is in the range of 60-850 kJ/kg dry gas, for example, 80-680 kJ/kg dry gas or 100-450 kJ/kg dry gas, to meet the requirements of ammonia desulfurization, and achieve the synergy between the acid gas pre-treatment and ammonia desulfurization. Furthermore, hydrogen sulfide may be converted into sulfur/sulfuric acid plus ammonium sulfate at an adjustable ratio.