The present disclosure provides for collection and separation systems, collection and separation methods, isotope analsis systems, methods of processing samples to analyze .sup.15N, .sup.13C, and S.sup.34, and the like. In an aspect, the present disclosure provides for a system that includes a collection system in gaseous communication with a first device, wherein the collection system is configured to isolate two or more gases of a gaseous sample and configured to introduce each to a second device independently of one another.

Embodiments of the present disclosure include methods and systems of circulating air in an enclosed environment. In such embodiments, the system may comprise an air handling unit (AHU), the AHU including an indoor air inlet to receive an indoor airflow from the enclosed environment and an indoor air outlet to expel the indoor airflow, a conditioning element arranged between the inlet and the outlet configured to at least heat or cool the indoor airflow as it flows thereover, one or more fan units arranged between the inlet and the outlet configured to provide velocity to the indoor airflow, and an air treatment assembly (ATA) arranged within or proximate the AHU, the ATA including an air inlet configured to receive a portion of the indoor airflow received by the AHU indoor air inlet.

A system includes a purification unit configured to process a vapor stream including sulfur dioxide. The purification unit includes an inlet configured to allow the vapor stream to enter the purification unit. The purification unit includes a steam coil configured to circulate steam and provide a source of heat. The purification unit includes a packed bed. The purification unit includes a tray configured to accumulate sulfur. The purification unit includes an absorber section configured to remove at least a portion of the sulfur dioxide from the vapor stream. The purification unit includes an outlet configured to allow an effluent with a lower sulfur dioxide content than the vapor stream to exit the purification unit. The system includes a sulfur tank including a vent line in fluid communication with the inlet. The vent line is configured to allow vapor to flow from the sulfur tank to the purification unit.

This disclosure provides an integrated system and method for producing purified water, hydrogen, and oxygen from contaminated water. The contaminated water may be derived from regolith-based resources on the moon, Mars, near-Earth asteroids, or other destination in outer space. The integrated system and method utilize a cold trap to receive the contaminated water in a vapor phase and selectively freeze out water from one or more volatiles. A heat source increases temperature in the cold trap to vaporize the frozen contaminated water to produce a gas stream of water vapor and volatiles. A chemical scrubber may remove one or more volatiles. The integrated system and method utilize ionomer membrane technology to separate the water vapor from remaining volatiles. The water vapor is delivered for crew use or delivered to an electrolyzer to produce hydrogen and oxygen.

A method for separating a Lewis acid gas from a fluid mixture, comprising contacting the fluid mixture with a reduced electroactive species; a non-aqueous electrolyte; and a stabilizing additive to form an anion adduct between the Lewis acid gas and the reduced electroactive species, wherein the electroactive species comprises an oxidized state, and at least one reduced state that bonds with the Lewis acid gas to form the anion adduct, wherein the stabilizing additive comprises a cationic Lewis acid, a hydrogen-bond donor, or a combination thereof, and the stabilizing additive is present in an effective amount to kinetically favor the forming of the anion adduct from the reduced electroactive species and thermodynamically favor the forming of the anion adduct in the thermodynamic equilibrium between the anion adduct and the reduced electroactive species.

In a process for treating a carbon dioxide-rich gas (1) containing water, the treatment by compression and/or washing and/or drying of the gas produces acidified water (W1, W2, W3, W4, W7) which is sent to a cooling circuit (W8, W10).

In one embodiment, a system includes a purification stage configured to purify an input gas stream prior to delivering the input gas stream to a reaction stage; and a collection stage configured to collect at least some ammonia from the reaction stage. The reaction stage is configured to reduce nitrogen into nitride; and convert at least some of the nitride into ammonia. In another embodiment, a separation membrane includes: an anode; a cathode electrically coupled to the anode; and a porous support material positioned between the anode and the cathode. The separation membrane is configured to reduce nitrogen into nitride; and facilitate hydrogenation of the nitride to form ammonia. In another embodiment, a method includes delivering an input gas stream comprising nitrogen to a separation membrane; reducing at least some of the nitrogen into nitride; and reacting at least some of the nitride with hydrogen-containing compound(s).

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

The present invention relates to a biomimetic-hybrid solvent system for simultaneous capture of H.sub.2S and CO.sub.2 from any gaseous composition. The present invention also relates to a process for upgradation of biogas to bio CNG by removing gaseous contaminants, including microbial removal of H.sub.2S, to obtained purified CO.sub.2. The biomimetic-hybrid solvent system contains three components selected from tertiary amine compounds, a functional colloidal fluid, and an enzyme mimic.

A filter media can include a fiber coated with a barrier coating that is substantially non-reactive to reactive species, and a photocatalytic coating disposed on the barrier coating, wherein the photocatalytic coating generates reactive species in response to illumination with optical radiation.