A process for the removal of hydrogen sulfide and sulfur recovery from a H.sub.2S-containing gas stream by catalytic direct oxidation and Claus reaction through two or more serially connected catalytic reactors, wherein a specific control of the oxygen supplement is operated. The control and improvement of the process is obtained by complementing, in each major step of the process, the H.sub.2S-containing gas stream by a suitable flow of oxygen, namely before the H.sub.2S-containing gas stream enters the Claus furnace, in the first reactor of the process and in the last reactor of the process. Especially in application in a SubDewPoint sulfur recovery process the H.sub.2S/SO.sub.2 ratio is kept constant also during switch-over of the reactors R1 and R by adding the last auxiliary oxygen containing gas directly upstream the last reactor R so that the H.sub.2S/SO.sub.2 ratio can follow the signal of the ADA within a few seconds.

Disclosed is an absorbent containing an amine for absorption of an acid gas in a biogas, and a biogas purification system using the same.

A device and method of generating an enriched gas within a nasal vestibule of a patient includes a housing, a chamber, a chamber inlet, a pump, a molecular sieve bed, a release outlet, and a breath duct. The chamber is configured to be received within the nasal vestibule. The pump is configured to direct an ambient air from an ambient environment into the chamber. The molecular sieve bed is positioned within the chamber and configured to collect a predetermined molecule from the ambient air thereby generating the enriched gas. The release outlet is configured to discharge the enriched gas from the chamber into the nasal vestibule. The breath duct longitudinally extends through the housing such that the breath duct is configured to fluidly communicate a fluid flow through the housing for nasal breathing by the patient while the chamber is positioned within the nasal vestibule.

There is an absorbent mixture usable for the removal of sour gases from gas mixtures. The mixture has at least one organic base having a pK.sub.b (in water) less than or equal to 3.2; at least one alcoholic solvent of general formula R(OH).sub.n having a boiling temperature above or equal to 100° C. at ambient pressure, wherein R is a linear or branched saturated alkyl group having a number of carbon atoms between 2 and 20 and n is a whole number varying between 1 and 20; an aprotic polar solvent having a dielectric constant ε at 25° C. greater than or equal to 30, a viscosity μ at 25° C. less than or equal to 14 cP, preferably less than or equal to 12 cP; and a boiling temperature at normal pressure equal to or above 130° C. There is also a process for the removal of sour gases using the absorbent mixture.

Embodiments provide a method of compound removal from a fluid. The method includes contacting one or more metal organic framework (MOF) compositions with a fluid and sorbing one or more compounds, such as CO.sub.2, H.sub.2S and condensable hydrocarbons. One or more of CO.sub.2, H.sub.2S and condensable hydrocarbons can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF.

A process for operating a reforming system by operating a reforming section containing a plurality of reactors, wherein each of the plurality of reactors containing a reforming catalyst capable of catalyzing the conversion of at least a portion of the hydrocarbons in a treated hydrocarbon stream into a reactor effluent comprising aromatic hydrocarbons, and operating a sulfur guard bed (SGB) to remove sulfur and sulfur-containing hydrocarbons from a hydrocarbon feed to provide the treated hydrocarbon stream, where the SGB contains at least a layer of a SGB catalyst comprising the same catalyst as the reforming catalyst, and where each reactor of the plurality of reactors within the reforming section may be operated at a higher operating temperature than an operating temperature of the SGB. A system for carrying out the process is also provided.

The disclosure provides a method for producing a gas separation article, said gas separation article comprising: a gas separation membrane, optionally a support, and optionally an additional support said method comprising the steps of: a) providing a matrix comprising: a matrix material having a viscosity from 1 cP to 40000 cP, particles, said particles being free from functionalized carbon nanotubes, and optionally a solvent, b) contacting the matrix of step a) with a support comprising at least one side, said at least one side facing said matrix, thereby forming (i) a matrix side in contact with the support and (ii) a matrix side opposite the side in contact with the support, c) optionally contacting the matrix side opposite the side contacting the support with an additional support, d) subjecting said matrix being in contact with said support to one or more electric fields whereby the particles form particle groups in a plurality of substantially parallel planes, said particle groups in each of said plurality of substantially parallel planes being aligned substantially parallel with the one or more electric fields, e) fixating the matrix material so as to fixate the particle groups thereby forming a gas separation membrane, and f) optionally removing the support and/or the additional support.

The disclosure also provides a gas separation membrane obtainable by the aforementioned method as well as use thereof for separation of gases in a gas mixture.

The present disclosure provides a method for producing a gas separation article, said gas separation article comprising: a gas separation membrane, optionally a support, and optionally an additional support, said method comprising the steps of: a) providing a matrix, said matrix having a viscosity from 1 centipoise to 40000 centipoise, said matrix comprising or consisting of one or more monomers, oligomers and/or polymers, and optionally a solvent, b) contacting the matrix of step a) with a support comprising at least one side, said at least one side facing said matrix, thereby forming (i) a matrix side contacting the support and (ii) a matrix side opposite the side contacting the support, c) optionally contacting the matrix side opposite the side contacting the support with an additional support, d) subjecting said matrix contacted with said support to one or more electric fields that is/are substantially parallel to a plane in which the support extends, or substantially perpendicular to a plane in which the support extends e) fixating the one or more monomers, oligomers and/or polymers of the matrix subjected to one or more electric fields in step d) thereby forming a solid gas separation membrane, and f) optionally removing the support and/or the additional support.

The present disclosure also gas separation article obtainable by the aforementioned method as well as use of said gas separation article for separation of gases in a gas mixture.

Described herein are amorphous fluorinated copolymers produced by the polymerization of one or more fluorinated ring monomers and one or more fluorinated comonomers containing multiple ether oxygens. The copolymers are suitable in many high-technology applications, such as optical fibers, anti-reflection coatings, protective coatings, and gas separation membranes. In one aspect, the copolymers are useful is in the field of membrane-based gas separation processes. In one aspect, amorphous copolymer is produced by polymerizing (a) one or more fluorinated ring monomers in the amount of 1 mol % to 99.5 mol %, wherein the fluorinated ring monomer is at least a five membered ring and (b) a comonomer in the amount of from 0.5 mol % to 99 mol %, wherein the comonomer comprises a fluorinated compound with two or more ether oxygens.

Described herein is a an adsorbent and/or absorbent composition, a method of preparing the adsorbent and/or absorbent composition, and method of treating a fluid stream with the adsorbent and/or absorbent composition. Alumina and carbon are combined with polyacrylamide (PAM) powder and water in preferred proportions and impregnates such as Group 1A metal hydroxides. Group 7A salts of Group 1A metals optionally can be added.