An integrated mercaptan extraction and/or sweetening and thermal oxidation and flue gas treatment process for a wide variety of sulfur, naphthenic, phenolic/cresylic contaminated waste streams is described. It provides comprehensive treatment for the safe disposal of sulfidic, naphthenic, phenolic/cresylic spent caustic streams, disulfide streams, spent air streams, spent mixed amine and caustic streams (also known as COS solvent streams) from sulfur treating processes. It allows the use of regenerated spent caustic in the sulfur oxide removal section of the thermal oxidation system reducing the need for fresh NaOH. It may also contain an integrated make-up water system. The integration allows the use of the liquefied petroleum gas or other hydrocarbon feeds to the respective extraction or sweetening process to offset external fuel gas requirements for the thermal oxidation system and for the push/pull system of the spent caustic surge drum and optional hydrocarbon surge drum.

A gas purification device includes: a converter packed with a catalyst for hydrolyzing both carbonyl sulfide and hydrogen cyanide; an upstream heat exchanger for heat exchange between a gas to be introduced into the converter and a cooling fluid for cooling the gas; a reaction-temperature estimation member for estimating a reaction temperature inside the converter; and a flow-rate adjustment member for adjusting a flow rate of the cooling fluid flowing into the upstream heat exchanger based on an estimated value of the reaction-temperature estimation member to control the reaction temperature.

The invention relates to a method for purifying a gaseous, liquid or aerosol composition, containing at least one pollutant consisting of a volatile inorganic compound (VIC), a siloxane and/or a functional volatile organic compound (Pollution Trap Concept or P.T.C. System).

Disclosed is method for removing carbonyl sulphide and/or carbon disulphide from a sour gas stream. The method comprises subjecting the gas stream to simultaneous contact with an absorption liquid, such as an aqueous amine solution, and with a catalyst suitable for hydrolyzing carbonyl sulphide and/or carbon disulphide. To this end, the invention also provides a reactor system wherein both an absorption liquid and a catalyst are present. In a preferred embodiment, the catalyst is a heterogeneous catalyst present on or in an absorption column, either coated on the trays of a column with trays, or contained in the packing of a packed column.

Disclosed herein are acid gas absorbents that afford high acid gas (CO2) absorption amount per unit volume and high absorption speed and can prevent the absorbent. components from diffusing. The acid gas absorbent contains an amine compound of the form is (1) and a cyclic amine compound of the formula (3) or (3):

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Techniques for removing sulfur compounds from a sulfur-containing gas stream can include contacting the gas with an absorption solution comprising a metal cation capable of reacting with the sulfur compound to form a metal sulphide precipitate and/or a metal mercaptide precipitate. In addition, the treatment can include controlling a concentration of the precipitates below a threshold to maintain rheological properties; subjecting the precipitate-enriched solution to vitalization; subjecting the precipitate-enriched solution to regeneration including oxidation; and/or other features to enhance the sulfur removal operations.

Disclosed herein are acid gas absorbents that afford high acid gas (CO2) absorption amount per unit volume and high absorption speed and can prevent the absorbent components from diffusing. Also disclosed herein is a method and device for removing an acid gas, in which the energy required for separating the acid gas and regenerating the absorbent is reduced, are provided.

A process for recovering sulfur and carbon dioxide from a sour gas stream, the process comprising the steps of: providing a sour gas stream to a membrane separation unit, the sour gas stream comprising hydrogen sulfide and carbon dioxide; separating the hydrogen sulfide from the carbon dioxide in the membrane separation unit to obtain a retentate stream and a first permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur; introducing the permeate stream to an amine absorption unit; and processing the permeate stream in the amine absorption unit to produce an enriched carbon dioxide stream.

The embodiments provide an acidic gas absorbent, an acidic gas removal method, and an acidic gas removal apparatus. The absorbent absorbs an acidic gas in a large amount and hardly diffuses in air. The acidic gas absorbent according to the embodiment comprises an amine compound having a sulfonyl group and two or more amino groups.

Plant and process for separation of sulfur-containing components, H.sub.2S, COS and mercaptans from methanol which is used as absorbent within the Rectisol process by hot regeneration of the methanol laden in the absorption and an additional step for separation of the mercaptans from the methanol by stripping.